ChemicalBook > CAS DataBase List > 2-Bromoethyl trifluoromethanesulphonate

2-Bromoethyl trifluoromethanesulphonate

Product Name: 2-Bromoethyl trifluoromethanesulphonate
CAS No.: 103935-47-3
Chemical Name: 2-Bromoethyl trifluoromethanesulphonate
Synonyms: 2-broMoethyl trifluoroMethanesulfonate;2-Bromoethyl triflate;2-Bromoethyl trifluoromethanesulphonate;Trifluoro-methanesulfonic acid 2-bromo-ethyl ester;Methanesulfonic acid, trifluoro-, 2-broMoethyl ester;1,1,1-TrifluoroMethanesulfonic acid 2-broMo-ethyl ester;Methanesulfonic acid, 1,1,1-trifluoro-, 2-bromoethyl ester
CBNumber: CB42526768
Molecular Formula: C3H4BrF3O3S
Formula Weight: 257.03
MOL File: 103935-47-3.mol

Less

2-Bromoethyl trifluoromethanesulphonate Property

Boiling point:: 230 °C
Density: 1.903±0.06 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: liquid
color: clear
InChI: InChI=1S/C3H4BrF3O3S/c4-1-2-10-11(8,9)3(5,6)7/h1-2H2
InChIKey: KENPFZUYYWVXNW-UHFFFAOYSA-N
SMILES: C(F)(F)(F)S(OCCBr)(=O)=O

Less

Safety

HS Code: 2904990090

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P310Immediately call a POISON CENTER or doctor/physician.

Less

N-Bromosuccinimide Price

TRC

Product number: B679558
Product name: 2-BromoethylTrifluoromethanesulfonate
Packaging: 50mg
Price: $45
Updated: 2021/12/16

SynQuest Laboratories

Product number: 6164-B-02
Product name: 2-Bromoethyl trifluoromethanesulfonate
Purity: 98%
Packaging: 1g
Price: $95
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB145510
Product name: 2-Bromoethyl trifluoromethanesulfonate
Packaging: 500mg
Price: $140
Updated: 2021/12/16

Apolloscientific

Product number: PC57000
Product name: 2-Bromoethyltrifluoromethanesulphonate
Purity: 95%
Packaging: 1g
Price: $185
Updated: 2021/12/16

Biosynth Carbosynth

Product number: FB145510
Product name: 2-Bromoethyl trifluoromethanesulfonate
Packaging: 1g
Price: $220
Updated: 2021/12/16

Less

2-Bromoethyl trifluoromethanesulphonate Chemical Properties,Usage,Production

Synthesis

358-23-6

540-51-2

103935-47-3

Pyridine (1.74 kg, 22.01 mol, 1.10 eq.) was dissolved in dichloromethane (20 L) under nitrogen protection and the solution was cooled to -20 °C. Subsequently, trifluoromethanesulfonic anhydride (5.87 kg, 20.81 mol, 1.04 eq.) was added slowly and dropwise. The reaction system was maintained at -20 °C with stirring for 0.5 hours. Then, 2-bromoethanol (2.50 kg, 20.01 mol, 1.0 eq.) was slowly added dropwise and the reaction temperature was ensured to be maintained below 0 °C and stirring was continued for 1.0 hour. The progress of the reaction was monitored by thin layer chromatography (TLC, unfolding agent ratio of petroleum ether: ethyl acetate = 5:1) to confirm the completion of the reaction. After completion of the reaction, the reaction mixture was filtered and the filtrate was concentrated. Petroleum ether (15 L) was added to the concentrate, the precipitated solid was filtered, and the filtrate was concentrated again to obtain the target product (4.80 kg, 93.33% yield) of trifluoromethanesulfonic acid (2-bromoethyl) ester as a dark yellow oil.

References

[1] Patent: CN107955019, 2018, A. Location in patent: Paragraph 0098; 0099; 0100
[2] Tetrahedron, 1999, vol. 55, # 35, p. 10659 - 10672
[3] Patent: WO2009/153554, 2009, A1. Location in patent: Page/Page column 62
[4] Angewandte Chemie - International Edition, 2008, vol. 47, # 20, p. 3784 - 3786
[5] Patent: WO2017/147410, 2017, A1. Location in patent: Page/Page column 180

2-Bromoethyl trifluoromethanesulphonate Preparation Products And Raw materials

Raw materials

Preparation Products

Less

2-Bromoethyl trifluoromethanesulphonate Suppliers

China 52 United Kingdom 2 United States 5 Global 59

Cangzhou Dimai Technology Co., Ltd

Tel: 1351-2466848 13512466848
Fax: QQ:94204388
Email: hbdypharm@163.com
Country: China
ProdList: 244
Advantage: 58

J & K SCIENTIFIC LTD.

Tel: 18210857532; 18210857532
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Beijing Ouhe Technology Co., Ltd

Tel: 010-010-82967028 13522913783
Fax: +86-10-82967029
Email: 2355560935@qq.com
Country: China
ProdList: 12000
Advantage: 60

Hunan Hui Bai Shi Biotechnology Co., Ltd.

Tel: 0731-85526065 13308475853
Email: ivy@hnhbsj.com
Country: China
ProdList: 7247
Advantage: 62

Hangzhou Sage Chemical Co., Ltd.

Tel: +86057186818502 13588463833
Fax: Pls mail us for more information!
Email: info@sagechem.com
Country: China
ProdList: 10266
Advantage: 58

Nanjing Norris-Pharm Technology Co., Ltd

Tel: 18652989687
Fax: +86-25-52131256
Email: sales@norris-pharm.com
Country: China
ProdList: 8878
Advantage: 55

Shanghai Jian Chao Chemical Technology Co., Ltd.

Tel: 150-2103-5486 18017383231
Fax: qq：2817624287
Email: 983544897@qq.com
Country: China
ProdList: 9342
Advantage: 55

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 39966
Advantage: 60

Cool Pharm, Ltd

Tel: 021-60455363 18019463053
Fax: 50966098
Email: sales@coolpharm.com
Country: China
ProdList: 12346
Advantage: 58

Nanjing Huang Tai Pharmaceutical Technology Co. Ltd.

Tel: 025-58803135 18551845925
Fax: 025-58803650
Email: 3569572487@qq.com
Country: China
ProdList: 337
Advantage: 58

JW & Y Pharmlab Co., Ltd.

Tel: 021-64340559 13651849907;
Fax: 021- 64345308
Email: xinyu_shi@jwypharmlab.com.cn
Country: China
ProdList: 12000
Advantage: 58

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 71826
Advantage: 60

Cangzhou Enke Pharma-tech Co., Ltd.

Tel: 0317-5296180 15533709196
Fax: 0317-5106596
Email: sale@enkepharma.com
Country: China
ProdList: 2267
Advantage: 55

Amadis Chemical Company Limited

Tel: 571-89925085
Fax: 0086-571-89925065
Email: sales@amadischem.com
Country: China
ProdList: 131957
Advantage: 58

Shanghai Anmike Chemical Co. Ltd.

Tel: 微信 17321281695 18019252918
Fax: 021-31261685
Email: sale@amkchem.com
Country: China
ProdList: 9405
Advantage: 55

Aikon International Limited

Tel: 025-66061636 18013972705
Fax: (3)02557626880
Email: qqyang@aikonchem.com
Country: China
ProdList: 15814
Advantage: 58

Shanghai ruichang pharmaceutical technology co., LTD

Tel: 18621054990
Email: maychemicals@sina.com
Country: China
ProdList: 673
Advantage: 58

Henan Alpha Chemical Co., Ltd.

Tel: 0371-55055611 18137792234
Fax: QQ：3002694073
Email: 3002694073@qq.com
Country: China
ProdList: 9987
Advantage: 58

Suzhou XiBoli Biotechnology Co., Ltd.

Tel: 17326194005
Email: 1873444526@qq.com
Country: China
ProdList: 496
Advantage: 58

Shanghai Wei Nie Chemical Technology Co., Ltd.

Tel: 13046668259
Email: 657990292@qq.com
Country: China
ProdList: 300
Advantage: 58

Shanghai Kaiwei Chemical Technology Co., Ltd.

Tel: 021-58461859 15821823057
Email: service@aiviche.com
Country: China
ProdList: 49312
Advantage: 58

Energy Chemical

Tel: 021-58432009 400-005-6266
Fax: 021-58436166
Email: marketing1@energy-chemical.com
Country: China
ProdList: 44894
Advantage: 58

Shandong Territorial sea Biological Technology Co., LTD

Tel: 15092083467
Email: 18660263263@163.com
Country: China
ProdList: 2810
Advantage: 58

Yantai Boyun Biological Technology Co. Ltd

Tel: 13793517650; 13793517650
Email: 2767277144@qq.com
Country: China
ProdList: 2856
Advantage: 58

Shanghai Sunway Pharmaceutical Technology Co.,Ltd.

Tel: 021-51816796-820 13611835272
Fax: 021-5161 3951
Email: sales2@sunwaypharm.com
Country: China
ProdList: 44119
Advantage: 58

Hubei Co-prosperity Medicine Technonlogy Co., Ltd

Tel: 2383948258 19172820304
Email: 2383948258@qq.com
Country: China
ProdList: 12987
Advantage: 58

Beijing Jin Ming Biotechnology Co., Ltd.

Tel: 010-60605840 15801484223;
Email: psaitong@jm-bio.com
Country: China
ProdList: 29757
Advantage: 58

Shanghai Haohong Pharmaceutical Co., Ltd.

Tel: 400-8210725 4008210725
Email: malulu@leyan.com
Country: China
ProdList: 40000
Advantage: 58

Bide Pharmatech Ltd.

Tel: 400-6005915
Email: sales@picasso-e.com
Country: China
ProdList: 39665
Advantage: 58

Suzhou Xinrui Biotechnology Co., Ltd.

Tel: 13401437572
Email: xinruibiotech01@163.com
Country: China
ProdList: 2741
Advantage: 58

Nanjing Norris-Pharm Technology Co., Ltd

Tel: 13901585132
Email: 2261760024@qq.com
Country: China
ProdList: 4900
Advantage: 58

Yantai Zhengxin New Material Technology Co. LTD

Tel: 13854547682 13854547682
Email: 542660804@qq.com
Country: China
ProdList: 4525
Advantage: 58

Shanghai Maclean Biochemical Technology Co., LTD

Tel: 021-021-50706066 15221275939
Email: shenlinxing@macklin.cn
Country: China
ProdList: 29784
Advantage: 58

Heze Bona Medical Technology Co., LTD

Tel: 18615487702
Email: 614989876@qq.com
Country: China
ProdList: 3000
Advantage: 58

Shanghai Jieshikai Biotechnology Co. , Ltd.

Tel: 021-57520305 13795461237
Email: zhuruyan@jskchem.com
Country: China
ProdList: 49234
Advantage: 58

Accela ChemBio Co.,Ltd.

Tel: 021-50795510 4000665055
Email: syeu@accelachem.com
Country: China
ProdList: 11015
Advantage: 58

Yantai Shengkailun Chemical Technology Co., Ltd.

Tel: 13356901049
Email: mark@sklnchem.cn
Country: China
ProdList: 9995
Advantage: 58

Shanghai Aladdin Biochemical Technology Co.,Ltd.

Tel: 400-6206333 13167063860
Email: anhua.mao@aladdin-e.com
Country: China
ProdList: 48457
Advantage: 58

Shandong Libixi Biopharmaceutical Technology Co., Ltd.

Tel: 15318973357; 15318973357
Email: 1460285141@qq.com
Country: China
ProdList: 8064
Advantage: 58

Tianjin Rongshen Chemical Co., Ltd

Tel: 18317763565; 18317763565
Email: 18317763565@163.com
Country: China
ProdList: 9516
Advantage: 58

Shanghai Hansi Chemical Industry Co., Ltd.

Tel: 17717618050
Email: zllg@gh-reagent.com
Country: China
ProdList: 10420
Advantage: 58

Cangzhou Enke Pharma Tech Co.,ltd.

Tel: 0317-5106596 15533709196
Email: 1154424302@qq.com
Country: China
ProdList: 2262
Advantage: 58

Biosynth Biological Technology (Suzhou) Co Ltd

Tel: 51288865780
Email: sales@biosynth.com
Country: China
ProdList: 6051
Advantage: 58

Santa Cruz Biotechnology Inc

Tel: 021-60936350
Email: scbt@scbt.com
Country: China
ProdList: 6594
Advantage: 58

Anyang Xiyan Technology Co., LTD

Tel: 17525889330
Email: 17525889330@163.com
Country: China
ProdList: 7856
Advantage: 58

Cangzhou Kangrui Pharma Tech Co. Ltd.,

Tel: +86-18632776803 +86-13833998158
Email: cangzhoukangrui@126.com
Country: China
ProdList: 773
Advantage: 58

SHANGHAI KEAN TECHNOLOGY CO., LTD.

Tel: +8613817748580
Fax: 021-50175322
Email: cooperation@kean-chem.com
Country: China
ProdList: 40066
Advantage: 58

Compound Net Biotechnology Inc.

Tel: +8615303909093
Email: sales@compound-net.com
Country: China
ProdList: 2914
Advantage: 58

Hebei Chuanghai Biotechnology Co., Ltd

Tel: +86-15350571055
Email: Sibel@chuanghaibio.com
Country: China
ProdList: 6085
Advantage: 58

Shanghai Acmec Biochemical Technology Co., Ltd.

Tel: +86-18621343501; +undefined18621343501
Email: product@acmec-e.com
Country: China
ProdList: 33338
Advantage: 58

103935-47-3, 2-Bromoethyl trifluoromethanesulphonateRelated Search:

Nickel(II) Trifluoromethanesulfonate Trifluoromethanesulfonic acid SAMARIUM(III) TRIFLUOROMETHANESULFONATE YTTRIUM(III) TRIFLUOROMETHANESULFONATE 3-(TRIMETHYLSILYL)-2-NAPHTHYL TRIFLUOROMETHANESULFONATE Iron(III) trifluoromethanesulfonate Lanthanum trifluoromethanesulfonate Aluminum trifluoromethanesulfonate Sodium trifluoroacetate 2,2-DIFLUOROETHYL TRIFLUOROMETHANESULFONATE Scandium trifluoromethanesulfonate PALLADIUM(II) TRIFLUOROACETATE Methyl trifluoromethanesulfonate Trifluoromethanesulfonic anhydride Trimethylsilyl trifluoromethanesulfonate Sulfurous Acid 2-CHLOROPHENYL TRIFLUOROMETHANESULFONATE Methanesulfonic acid, trifluoro-, 2-methoxy-5-nitrophenyl ester

2-Bromoethyl trifluoromethanesulphonate

1,1,1-TrifluoroMethanesulfonic acid 2-broMo-ethyl ester

2-Bromoethyl triflate

2-broMoethyl trifluoroMethanesulfonate

Methanesulfonic acid, trifluoro-, 2-broMoethyl ester

Trifluoro-methanesulfonic acid 2-bromo-ethyl ester

Methanesulfonic acid, 1,1,1-trifluoro-, 2-bromoethyl ester

103935-47-3

C3H4BrF3O3S