ChemicalBook > CAS DataBase List > 1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE

1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE

Product Name
1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE
CAS No.
21969-32-4
Chemical Name
1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE
Synonyms
magnesium,but-1-ene,chloride;chlorure de buten-2 ylmagnesium;1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE;1-Methyl-2-propenylmagnesium chloride solution;1-Methyl-2-propenylmagnesium chloride, 0.25 M in THF;1-Methyl-2-propenylmagnesium chloride, 0.25 M in 2-MeTHF;1-Methyl-2-propenylmagnesium chloride solution 0.5 in THF;1-Methyl-2-propenylmagnesium chloride 0.5M solution in THF;1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF;1-Methyl-2-propenylmagnesium chloride solution 0.5M solution in THF
CBNumber
CB4255349
Molecular Formula
C4H7ClMg
Formula Weight
114.86
MOL File
21969-32-4.mol
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1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE Property

Boiling point:
67 °C
Density 
0.917 g/mL at 25 °C
Flash point:
−4 °F
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Safety

Hazard Codes 
F,C,Xn
Risk Statements 
11-14-19-20/21/22-34-40-36/37/38-14/15
Safety Statements 
16-26-27-36/37/39-45-43-36/37
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
3
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
420042
Product name
1-Methyl-2-propenylmagnesium chloride solution
Purity
0.5 M in THF
Packaging
100ml
Price
$361
Updated
2024/03/01
Matrix Scientific
Product number
121862
Product name
1-Methyl-2-propenylmagnesiumchloride
Purity
0.25Min2-MeTHF97%
Packaging
500ml
Price
$737
Updated
2021/12/16
Matrix Scientific
Product number
121864
Product name
1-Methyl-2-propenylmagnesiumchloride
Purity
0.25MinTHF97%
Packaging
500ml
Price
$737
Updated
2021/12/16
Rieke Metals
Product number
T0381
Product name
1-Methyl-2-propenylmagnesiumchloride
Packaging
50mL
Price
$153
Updated
2021/12/16
Matrix Scientific
Product number
121864
Product name
1-Methyl-2-propenylmagnesiumchloride
Purity
0.25MinTHF97%
Packaging
50ml
Price
$232
Updated
2021/12/16
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1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Brown liquid

Uses

1-Methyl-2-propenylmagnesium chloride is a Grignard type allylating reagent that can be used for the preparation of corresponding homoallylic alcohols by reacting with various aldehydes. It can also be utilized in the synthesis of 3,4-dihydro-4-(1-methyl-2-propen-1-yl)-2(1H)-pyrimidinethione derivatives by treating with 2-mercaptopyrimidine.

1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE Suppliers

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21969-32-4, 1-METHYL-2-PROPENYLMAGNESIUM CHLORIDERelated Search:


  • 1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE
  • 1-Methyl-2-propenylmagnesium chloride 0.5M solution in THF
  • 1-Methyl-2-propenylmagnesium chloride, 0.25 M in 2-MeTHF
  • 1-Methyl-2-propenylmagnesium chloride, 0.25 M in THF
  • 1-Methyl-2-propenylmagnesium chloride solution
  • 1-METHYL-2-PROPENYLMAGNESIUM CHLORIDE, 0 .5M SOLUTION IN TETRAHYDROFURAN
  • 1-Methyl-2-propenylmagnesium chloride solution 0.5 in THF
  • 1-Methyl-2-propenylmagnesium chloride solution 0.5 M in THF
  • chlorure de buten-2 ylmagnesium
  • 1-Methyl-2-propenylmagnesium chloride solution 0.5M solution in THF
  • magnesium,but-1-ene,chloride
  • 21969-32-4
  • H2CCHCHCH3MgCl
  • Grignard Reagents
  • Organometallic Reagents
  • Alkyl
  • Chemical Synthesis
  • Grignard Reagents
  • Organometallic Reagents
  • Alkyl
  • Grignard Reagents
  • Organometallic Reagents
  • Grignard Reagent