Allylmagnesium chloride
- Product Name
- Allylmagnesium chloride
- CAS No.
- 2622-05-1
- Chemical Name
- Allylmagnesium chloride
- Synonyms
- 0/1/22;Allylchloromagnesium;Chloroallylmagnesium;Allylmagnesiumchlorid;ALLYLMAGNESIUM CHLORIDE;Allyl chlorideMagnesiuM;chloro-2-propenyl-magnesiu;2-Propenylmagnesium chloride;Magnesium, chloro-2-propenyl-;Allylmagnesium chloride(1M THF)
- CBNumber
- CB6297415
- Molecular Formula
- C3H5ClMg
- Formula Weight
- 100.83
- MOL File
- 2622-05-1.mol
Allylmagnesium chloride Property
- Melting point:
- -21°C
- Boiling point:
- 66°C
- Density
- 0.995 g/mL at 25 °C
- Flash point:
- 1 °F
- storage temp.
- water-free area
- form
- Liquid
- color
- Clear tan to brown, amber, dark gray, dark green or black
- Water Solubility
- vigorous reaction
- Sensitive
- Air & Moisture Sensitive
- BRN
- 3587316
- InChI
- InChI=1S/C3H5.ClH.Mg/c1-3-2;;/h3H,1-2H2;1H;/q;;+1/p-1
- InChIKey
- PLYLAFITHJUEGX-UHFFFAOYSA-M
- SMILES
- C([Mg]Cl)C=C
- EPA Substance Registry System
- Magnesium, chloro-2-propenyl- (2622-05-1)
Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-14/15-34-40-37-19
- Safety Statements
- 16-26-36/37/39-43-45-7/8-6A-43B-33
- RIDADR
- UN 3399 4.3/PG 1
- WGK Germany
- 1
- F
- 1-3-10
- TSCA
- TSCA listed
- HazardClass
- 4.2
- PackingGroup
- I
- HS Code
- 29319090
- Storage Class
- 4.3 - Hazardous materials which set free flammable gases upon contact with water
- Hazard Classifications
- Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 1
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H250Catches fire spontaneously if exposed to air
H260In contact with water releases flammable gases which may ignite spontaneously
H261In contact with water releases flammable gas
H302Harmful if swallowed
H303May be harmfulif swallowed
H314Causes severe skin burns and eye damage
H318Causes serious eye damage
H333May be harmful if inhaled
H335May cause respiratory irritation
H351Suspected of causing cancer
H371May cause damage to organs
H372Causes damage to organs through prolonged or repeated exposure
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P231+P232Handle under inert gas. Protect from moisture.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P370+P378In case of fire: Use … for extinction.
P402+P404Store in a dry place. Store in a closed container.
P405Store locked up.
P422Store contents under …
N-Bromosuccinimide Price
- Product number
- 225908
- Product name
- Allylmagnesium chloride solution
- Purity
- 2.0 M in THF
- Packaging
- 100ml
- Price
- $77
- Updated
- 2025/07/31
- Product number
- 225908
- Product name
- Allylmagnesium chloride solution
- Purity
- 2.0 M in THF
- Packaging
- 18l
- Price
- $6030
- Updated
- 2025/07/31
- Product number
- A1554
- Product name
- Allylmagnesium Chloride (ca. 11% in Tetrahydrofuran, ca. 1.0mol/L)
- Packaging
- 100g
- Price
- $62
- Updated
- 2025/07/31
- Product number
- 225908
- Product name
- Allylmagnesium chloride solution
- Purity
- 2.0 M in THF
- Packaging
- 800ml
- Price
- $420
- Updated
- 2025/07/31
- Product number
- A614905
- Product name
- AllylmagnesiumChloride
- Packaging
- 500mg
- Price
- $40
- Updated
- 2021/12/16
Allylmagnesium chloride Chemical Properties,Usage,Production
Chemical Properties
clear tan to brown, amber, dark grey, dark green
Uses
Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Application
Used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins.
reaction suitability
reaction type: Grignard Reaction
Synthesis
Allylmagnesium chloride was prepared as follows: 20g of allyl chloride and 12vol of THF were added to the allyl halogenated alkane supply unit 11, and the mixture was shaken well, and the mixture was prepared for use. The temperature of the outer bath of the Grignard reagent preparation unit 13 was raised to 50-55??C, and the above mixture was pumped into the Grignard reagent preparation unit 13 at the same time. Under constant stirring, magnesium chips were added from the magnesium metal supply unit 12 (solid charging funnel), while 0.4 g of I2 monomer was added to the Grignard reagent preparation unit 13 for thermal initiation. Immediately after thermal initiation, the temperature of the reaction system was lowered to a temperature between 0 and -15??C to carry out a continuous Grignard reaction and continuous preparation of allylmagnesium chloride.
Precautions
It reacts violently with water.
Air & moisture sensitive.
Stable under recommended storage conditions.
Allylmagnesium chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Allylmagnesium chloride manufacturers
- Product
- Allylmagnesium chloride 2622-05-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
- Product
- Allylmagnesium chloride 2622-05-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-09
- Product
- Allylmagnesium chloride solution 2622-05-1
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-06-27