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Allylmagnesium chloride

Product Name
Allylmagnesium chloride
CAS No.
2622-05-1
Chemical Name
Allylmagnesium chloride
Synonyms
0/1/22;Allylchloromagnesium;Chloroallylmagnesium;Allylmagnesiumchlorid;ALLYLMAGNESIUM CHLORIDE;Allyl chlorideMagnesiuM;chloro-2-propenyl-magnesiu;2-Propenylmagnesium chloride;Magnesium, chloro-2-propenyl-;Allylmagnesium chloride(1M THF)
CBNumber
CB6297415
Molecular Formula
C3H5ClMg
Formula Weight
100.83
MOL File
2622-05-1.mol
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Allylmagnesium chloride Property

Melting point:
-21°C
Boiling point:
66°C
Density 
0.995 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
water-free area
form 
Liquid
color 
Clear tan to brown, amber, dark gray, dark green or black
Water Solubility 
vigorous reaction
Sensitive 
Air & Moisture Sensitive
BRN 
3587316
InChIKey
PLYLAFITHJUEGX-UHFFFAOYSA-M
EPA Substance Registry System
Magnesium, chloro-2-propenyl- (2622-05-1)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-14/15-34-40-37-19
Safety Statements 
16-26-36/37/39-43-45-7/8-6A-43B-33
RIDADR 
UN 3399 4.3/PG 1
WGK Germany 
1
1-3-10
TSCA 
Yes
HazardClass 
4.2
PackingGroup 
I
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H250Catches fire spontaneously if exposed to air

H260In contact with water releases flammable gases which may ignite spontaneously

H261In contact with water releases flammable gas

H302Harmful if swallowed

H303May be harmfulif swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

H371May cause damage to organs

H372Causes damage to organs through prolonged or repeated exposure

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P335+P334Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P405Store locked up.

P422Store contents under …

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
225908
Product name
Allylmagnesium chloride solution
Purity
2.0 M in THF
Packaging
100ml
Price
$74.7
Updated
2024/03/01
Sigma-Aldrich
Product number
225908
Product name
Allylmagnesium chloride solution
Purity
2.0 M in THF
Packaging
18l
Price
$5850
Updated
2024/03/01
TCI Chemical
Product number
A1554
Product name
Allylmagnesium Chloride (ca. 11% in Tetrahydrofuran, ca. 1.0mol/L)
Packaging
100g
Price
$65
Updated
2024/03/01
Alfa Aesar
Product number
H51170
Product name
Allylmagnesium chloride, 1M in MeTHF
Packaging
100ml
Price
$130
Updated
2024/03/01
Alfa Aesar
Product number
H51170
Product name
Allylmagnesium chloride, 1M in MeTHF
Packaging
500ml
Price
$529
Updated
2024/03/01
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Allylmagnesium chloride Chemical Properties,Usage,Production

Chemical Properties

clear tan to brown, amber, dark grey, dark green

Uses

Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.
Grignard-reactions: reagent for the introduction of the allyl group.

Uses

Allylmagnesium chloride has been used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5?-disubstituted hydantoins. It is also used as a reagent for the introduction of the allyl group.

Application

Used in a study of the nucleophilic ring-opening of 2-methyleneaziridines to imines and subsequent conversion to 5,5′-disubstituted hydantoins.

Precautions

It reacts violently with water.
Air & moisture sensitive.
Stable under recommended storage conditions.

Allylmagnesium chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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Allylmagnesium chloride Suppliers

TOKYO CHEMICAL INDUSTRY CO., LTD.
Tel
03-36680489
Fax
03-3668-0520
Email
Sales-JP@TCIchemicals.com
Country
Japan
ProdList
28398
Advantage
80
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View Lastest Price from Allylmagnesium chloride manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
Allylmagnesium chloride 2622-05-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
Product
Allylmagnesium chloride 2622-05-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-07-09
Zhuozhou Wenxi import and Export Co., Ltd
Product
Allylmagnesium chloride solution 2622-05-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

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  • 2622-05-1
  • 622-05-1
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  • C3H5ClMg
  • CH2CHCH2MgCl
  • Organometallic Reagents
  • Alkyl
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Mg (Magnesium) Compounds
  • Typical Metal Compounds
  • Grignard Reagents
  • Classes of Metal Compounds
  • Grignard Reagents & Alkyl Metals
  • Mg (Magnesium) Compounds
  • Synthetic Organic Chemistry
  • Typical Metal Compounds
  • Alkyl