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3-Amino-4-methylbenzonitrile

Product Name
3-Amino-4-methylbenzonitrile
CAS No.
60710-80-7
Chemical Name
3-Amino-4-methylbenzonitrile
Synonyms
3-Amino-p-tolunitrile;2-Amino-4-cyanotoluene;3-AMINO-4-METHYLBENZONITRILE;Benzonitrile, 3-amino-4-methyl-;3-Amino-4-methylbenzonitrile 98%;5-Cyano-2-methylaniline, 2-Amino-4-cyanotoluene
CBNumber
CB4257974
Molecular Formula
C8H8N2
Formula Weight
132.16
MOL File
60710-80-7.mol
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3-Amino-4-methylbenzonitrile Property

Melting point:
81 °C
Boiling point:
312.8±22.0 °C(Predicted)
Density 
1.10±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
2?+-.0.10(Predicted)
form 
crystals
color 
White to off white to clear shards
InChI
InChI=1S/C8H8N2/c1-6-2-3-7(5-9)4-8(6)10/h2-4H,10H2,1H3
InChIKey
IEWMNQUBZPVSSV-UHFFFAOYSA-N
SMILES
C(#N)C1=CC=C(C)C(N)=C1
CAS DataBase Reference
60710-80-7(CAS DataBase Reference)
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Safety

Hazard Codes 
T
Risk Statements 
36/37/38
Safety Statements 
26-36
RIDADR 
3276
Hazard Note 
Toxic
HazardClass 
IRRITANT
HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

TRC
Product number
A898175
Product name
3-Amino-4-methylbenzonitrile
Packaging
2.5g
Price
$75
Updated
2021/12/16
AK Scientific
Product number
J55246
Product name
3-Amino-4-methylbenzonitrile
Packaging
1g
Price
$10
Updated
2021/12/16
Matrix Scientific
Product number
066906
Product name
3-Amino-4-methylbenzonitrile
Purity
98%
Packaging
5g
Price
$13
Updated
2021/12/16
AK Scientific
Product number
J55246
Product name
3-Amino-4-methylbenzonitrile
Packaging
5g
Price
$15
Updated
2021/12/16
Apolloscientific
Product number
OR4824
Product name
3-Amino-4-methylbenzonitrile
Purity
98%
Packaging
5g
Price
$15
Updated
2021/12/16
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3-Amino-4-methylbenzonitrile Chemical Properties,Usage,Production

Chemical Properties

off-white crystalline

Uses

3-Amino-4-methylbenzonitrile is an organic compound commonly used as an intermediate in organic synthesis, especially in pharmaceutical and pesticide chemistry.

Synthesis

939-79-7

60710-80-7

C.14.b. Synthesis of 3-amino-4-methylbenzonitrile: 120 g of 3-nitro-4-methylbenzonitrile was suspended in 1.2 L of ethanol, and 7 g of 10% Pd/C catalyst was added and the hydrogenation reaction was carried out in a 50 L hydrogen atmosphere at room temperature. Upon completion of the reaction, the catalyst was removed by diatomaceous earth filtration, followed by distillation under reduced pressure to remove the solvent to afford 95 g of pure 3-amino-4-methylbenzonitrile in 97% yield. The product was characterized by 1H-NMR (DMSO-d6; δ, ppm): 7.1 (dd, 1H); 6.90 (d, 1H); 6.85 (d, 1H); 5.35 (s, 2H, NH2); 2.15 (s, 3H).

References

[1] Patent: US6455671, 2002, B1
[2] Bioorganic and Medicinal Chemistry Letters, 2002, vol. 12, # 8, p. 1203 - 1208
[3] Chemische Berichte, 1903, vol. 36, p. 4359
[4] Chemische Berichte, 1904, vol. 37, p. 1845
[5] Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 1997, vol. 53, # 2, p. 141 - 150

3-Amino-4-methylbenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Amino-4-methylbenzonitrile Suppliers

NovoChemy Ltd.
Tel
021-31261262/ 49 (0)17662837245
Fax
(0)21-33250524
Email
sales@novochemy.com
Country
Germany
ProdList
6328
Advantage
58
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
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View Lastest Price from 3-Amino-4-methylbenzonitrile manufacturers

Henan Aochuang Chemical Co.,Ltd.
Product
3-AMINO-4-METHYLBENZONITRILE 60710-80-7
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-22
Milestone Chemical Wuxi Co.,Ltd
Product
3-AMINO-4-METHYLBENZONITRILE 60710-80-7
Price
US $0.00-0.00/kg T
Min. Order
1kg T
Purity
99.9%MIN
Supply Ability
20TONS
Release date
2023-03-20