3,5-Di-tert-butylsalicylaldehyde

ChemicalBook > CAS DataBase List > 3,5-Di-tert-butylsalicylaldehyde

3,5-Di-tert-butylsalicylaldehyde

Product Name: 3,5-Di-tert-butylsalicylaldehyde
CAS No.: 37942-07-7
Chemical Name: 3,5-Di-tert-butylsalicylaldehyde
Synonyms: 3,5-DI-TERT-BUTYL-2-HYDROXYBENZALDEHYDE;3,5-DI-T-BUTYL-2-HYDROXYBENZALDEHYDE;Dapagliflozin Impurity 108;3,5-DI-TBUTYLSALICYLALDEHYDE;3,5- di Ding JishuiYang Quan;3,5-Di-tert-butylsalicylaldehyd;3,5-DI-TERT-BUTYLSALICYLALDEHYDE;3,5-di-tert-Butyl Salicylaldehtde;Ditert-butyl-2-hydroxybenzaldehyde;3,5-Bis(tert-butyl)salicylaldehyde
CBNumber: CB4262967
Molecular Formula: C15H22O2
Formula Weight: 234.33
MOL File: 37942-07-7.mol

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3,5-Di-tert-butylsalicylaldehyde Property

Melting point:: 59-61 °C(lit.)
Boiling point:: 277.6±35.0 °C(Predicted)
Density: 1.006±0.06 g/cm3(Predicted)
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
solubility: Soluble in DMSO and methanol.
form: Solid
pka: 9.78±0.23(Predicted)
color: Off-White to Light Yellow
Sensitive: Air Sensitive
BRN: 1877810
InChIKey: RRIQVLZDOZPJTH-UHFFFAOYSA-N
CAS DataBase Reference: 37942-07-7(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
Hazard Note: Irritant
HS Code: 29124990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 140414
Product name: 3,5-Di-tert-butyl-2-hydroxybenzaldehyde
Purity: 99%
Packaging: 5g
Price: $50.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 140414
Product name: 3,5-Di-tert-butyl-2-hydroxybenzaldehyde
Purity: 99%
Packaging: 25g
Price: $61.4
Updated: 2024/03/01

TCI Chemical

Product number: D2646
Product name: 3,5-Di-tert-butylsalicylaldehyde
Purity: >98.0%(GC)
Packaging: 5g
Price: $16
Updated: 2024/03/01

TCI Chemical

Product number: D2646
Product name: 3,5-Di-tert-butylsalicylaldehyde
Purity: >98.0%(GC)
Packaging: 25g
Price: $38
Updated: 2024/03/01

Alfa Aesar

Product number: B23834
Product name: 3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%
Packaging: 5g
Price: $54.65
Updated: 2024/03/01

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3,5-Di-tert-butylsalicylaldehyde Chemical Properties,Usage,Production

Chemical Properties

3,5-Di-tert-butylsalicylaldehyde is white to yellow powder or chunks or crystal or crystalline powder

Uses

3,5-Di-tert-butylsalicylaldehyde is a salicylaldehyde derivative with antibacterial activity used in the preparation nickel complexes. 3,5-Di-tert-butylsalicylaldehyde is structurally related to 3,5-di-t-butylcatechol (DTCAT) but is not as potent an activator of rat skeletal muscle ryanodine receptor Ca2+ channel (RyRC).

Uses

3,5-Di-tert-butyl-2-hydroxybenzaldehyde is used in the synthesis of Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose, chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenyl acetylene to imines, chiral oxazolidine ligand for the enantioselective addition of diethyl zinc to aldehydes and tin Schiff base complexes with histidine analogues. It has antibacterial activity and is used in the preparation nickel complexes. It is structurally related to 3,5-di-t-butylcatechol (DTCAT) but is not as potent an activator of rat skeletal muscle ryanodine receptor Ca2+ channel (RyRC).

Uses

3,5-Di-tert-butyl-2-hydroxybenzaldehyde was used in the synthesis of

Mn(III)-salen complex and its diamino precursor 5,6-diamino-5,6-dideoxy-1,2-O-isopropylidene-3-O-methyl-β-L-idofuranose
chiral Schiff base ligand for an enantioselective copper-catalyzed addition of phenylacetylene to imines
chiral oxazolidine ligand for the enantioselective addition of diethylzinc to aldehydes
tin Schiff base complexes with histidine analogues

Definition

ChEBI: 3,5-di-tert-butyl-2-hydroxybenzaldehyde is a hydroxybenzaldehyde.

Synthesis Reference(s)

The Journal of Organic Chemistry, 59, p. 1939, 1994 DOI: 10.1021/jo00086a062
Tetrahedron, 46, p. 793, 1990 DOI: 10.1016/S0040-4020(01)81362-4
Tetrahedron Letters, 13, p. 4205, 1972 DOI: 10.1016/S0040-4039(01)94276-5

General Description

3,5-Di-tert-butyl-2-hydroxybenzaldehyde undergoes condensation reaction with

methyl-2-{N-(2′-aminoethane)}-amino-1-cyclopentenedithiocarboxylate to yield Schiff base ligand
N,N-diethyl-2-methyl-1,4-phenylenediamine during the synthesis of copper(II) and cobalt(II) complexes of salicylaldimine

3,5-Di-tert-butylsalicylaldehyde Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-2-Methyl-2-propanesulfinamide

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View Lastest Price from 3,5-Di-tert-butylsalicylaldehyde manufacturers

hebei hongtan Biotechnology Co., Ltd

Product: 3,5-Bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde 37942-07-7
Price: US $30.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 2000kg
Release date: 2024-05-14

WUHAN FORTUNA CHEMICAL CO., LTD

Product: 3,5-Di-tert-butylsalicylaldehyde 37942-07-7
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-10

Shaanxi Dideu Medichem Co. Ltd

Product: 3,5-Di-tert-butylsalicylaldehyde 37942-07-7
Price: US $0.00-0.00/KG
Min. Order: 10mg
Purity: 99%HPLC
Supply Ability: 2000tons
Release date: 2020-01-15

37942-07-7, 3,5-Di-tert-butylsalicylaldehydeRelated Search:

5-TERT-BUTYL-2-HYDROXY-BENZALDEHYDE butyl rubber Salicylaldehyde tert-Butyl methyl ether Butylated Hydroxytoluene Benzaldehyde Tetrabutylammonium bromide CHLOROPHOSPHONAZO III Di-tert-butyl peroxide 3,5-Bis-tert-butylsalicylic acid 3,5-Di-tert-butyl-4-hydroxybenzoic acid 3,5-Di-tert-butyl-4-hydroxybenzaldehyde 9-Formyl-8-hydroxy-1,1,7,7-tetramethyljulolidine ZINC 3 5-DI-TERT-BUTYLSALICYLATE 97 6,8-DI(TERT-BUTYL)-4-OXO-4H-CHROMENE-2-CARBOXYLIC ACID THIOGLYCOLIC ACID N-BUTYL ESTER 3,5-DI-TERT-BUTYL-2-METHOXYBENZALDEHYDE 1-[3,5-DI(TERT-BUTYL)-2-HYDROXYPHENYL]ETHAN-1-ONE

3,5- di Ding JishuiYang Quan

3,5-Di-tert-butylsalicylaldehyde, 95+%

3, 5-2 tertiary butyl salicylaldehyde

3,5-Di-<i>tert</i>-butylsalicylaldehyde

3,5-Di-tert-butyl-2-hydroxybenzaldehyde 99%

2-Hydroxy-3,5-di-tert-butylbenzaldehyde

3,5-DI-TBUTYLSALICYLALDEHYDE

3,5-DI-TERT-BUTYL-2-HYDROXYBENZALDEHYDE

3,5-DI-T-BUTYL-2-HYDROXYBENZALDEHYDE

3,5-DI-TERT-BUTYLSALICYLALDEHYDE

3,5-bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde

BENZALDEHYDE, 3,5-BIS(1,1-DIMETHYLETHYL)-2-HYDROXY-

3,5-di-tert-Butyl Salicylaldehtde

Ditert-butyl-2-hydroxybenzaldehyde

3,5-DI-TER-BUTYL-2-HYDROXYBENZYLALDEHYDE

3,5-DITERT-BUTYL-2-HYDROXYBENZALEDHYDE

3,5-Di-tert-butyl-2-hydroxybenzaldehyde,3,5-Di-tert-butylsalicylaldehyde

3,5-Bis(tert-butyl)-2-hydroxybenzaldehyde

3,5-Bis(tert-butyl)salicylaldehyde

3,5-Di-tert-butyl-2-hydroxybenzaldehyde ,99%

3,5-Bis(tert-butyl)-2-hydroxybenzaldehyde 99%

3,5-Bis(tert-butyl)salicylaldehyde, 2,4-Bis(tert-butyl)-6-formylphenol

3,5-Di-tert-butyl-2-hydroxybenzaldehyde, 99%, for synthesis

3,5-Di-tert-butylsalicylaldehyde&gt

Dapagliflozin Impurity 108

high quality 3,5-Bis(1,1-dimethylethyl)-2-hydroxy-benzaldehyde

3,5-Di-tert-butylsalicylaldehydene

3,5-Di-tert-butylsalicylaldehyd

37942-07-7

37492-07-7

39742-09-7

37942-04-7

HOC6H2CCH332CHO

ALDEHYDE

Carbonyl Compounds

C10 to C21

Building Blocks

Aldehydes

Organic Building Blocks

Building Blocks

C13-C60

Carbonyl Compounds

Chemical Synthesis

Organic Building Blocks

Aromatic Aldehydes & Derivatives (substituted)

Aldehydes

Phenyls & Phenyl-Het

Achiral Oxygen

37942-07-7