Diisobutylamine

ChemicalBook > CAS DataBase List > Diisobutylamine

Product Name: Diisobutylamine
CAS No.: 110-96-3
Chemical Name: Diisobutylamine
Synonyms: DIBA;(i-C4H9)2NH;Diisobutylamin;AURORA KA-7633;DIISOBUTYLAMINE;amine,diisobutyl;Di-n-isobutylaMine;Diisobutylamine,99%;diisobutylamine diba;LABOTEST-BB LTBB000475
CBNumber: CB4279808
Molecular Formula: C8H19N
Formula Weight: 129.24
MOL File: 110-96-3.mol

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Diisobutylamine Property

Melting point:: -77 °C (lit.)
Boiling point:: 137-139 °C (lit.)
Density: 0.74 g/mL at 25 °C (lit.)
refractive index: n20/D 1.4081(lit.)
Flash point:: 85 °F
storage temp.: Flammables area
solubility: insoluble to slightly soluble in water; soluble in ethanol, methanol, ethyl ether, ethyl acetate, acetone, benzene, aromatic and aliphatic hydrocarbons, fixed oils, mineral oil, oleic and stearic acids
pka: 11.07±0.28(Predicted)
form: Liquid
color: Clear
Odor: amine odor
Water Solubility: 5 g/L (20 ºC)
Sensitive: Air Sensitive
BRN: 1209251
Dielectric constant: 2.7（22℃）
LogP: 2.383 (est)
CAS DataBase Reference: 110-96-3(CAS DataBase Reference)
NIST Chemistry Reference: 1-Propanamine, 2-methyl-N-(2-methylpropyl)-(110-96-3)
EPA Substance Registry System: Diisobutylamine (110-96-3)

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Safety

Hazard Codes: C
Risk Statements: 10-22-34-52/53
Safety Statements: 26-36/37/39-45-25-16-61
RIDADR: UN 2361 3/PG 3
WGK Germany: 1
RTECS: TX1750000
F: 34
TSCA: Yes
HazardClass: 3
PackingGroup: III
HS Code: 29211990
Hazardous Substances Data: 110-96-3(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H226Flammable liquid and vapour

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 135186
Product name: Diisobutylamine
Purity: 99%
Packaging: 250ml
Price: $39.7
Updated: 2024/03/01

Sigma-Aldrich

Product number: 135186
Product name: Diisobutylamine
Purity: 99%
Packaging: 1l
Price: $57.48
Updated: 2024/03/01

TCI Chemical

Product number: D0614
Product name: Diisobutylamine
Packaging: 25mL
Price: $19
Updated: 2024/03/01

TCI Chemical

Product number: D0614
Product name: Diisobutylamine
Packaging: 500mL
Price: $41
Updated: 2024/03/01

Alfa Aesar

Product number: L15495
Product name: Diisobutylamine, 99%
Packaging: 500ml
Price: $68.65
Updated: 2024/03/01

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Diisobutylamine Chemical Properties,Usage,Production

Chemical Properties

The chemical reactivity of diisobutylamine is similar to other aliphatic amines and is governed by the unshared electron pair on the nitrogen atom. It is a strong base tending to form salts with acids. As with other secondary amines, diisobutylamine can be nitrosated, especially under acidic conditions, by nitrite ion or by nitrogen oxides from the air to form the carcinogenic and mutagenic N-nitrosodiisobutylamine (Olah et al 1975).

Uses

Diisobutylamine was used to study the effect of achiral amine on hydrogenation of ethyl pyruvate over cinchonidine-Pt/Al2O3 catalyst system. Diisobutylamine is the principal starting material for the herbicide Butylate (Zeneca).

Production Methods

Diisobutylamine can be produced by the reaction of ammonia and butanol over a dehydration catalyst at high temperature and pressure (Hawley 1977). Alternatively, ammonia, butanol, and hydrogen can be passed over a dehydrogenation catalyst. In 1976, 18,000 tons of diisobutylamine were produced (Schweizer et al 1978). Diisobutylamine is also naturally present in foods and soil.
As with other secondary amines, diisobutylamine can be nitrosated to form the highly toxic (Olah 1975) N-nitrosodiisobutylamine (Guttenplan 1987; Vlasenko et al 1981; Spiegeholder et al 1978). Thus, nitrosation of commercial preparations of diisobutylamine occurs on standing, presumably by reaction with nitrogen oxides in the air (Spiegelhalder et al 1978) and N-nitrosodiisobutylamine has been found in various fishery products (Kawabata et al 1974) and other foods (Osborne 1972; Telling 1972).

General Description

Diisobutylamine appears as a clear colorless liquid with an ammonia-like odor. Insoluble in water and less dense than water. Hence floats on water. Vapors heavier than air. Toxic oxides of nitrogen produced during combustion.

Air & Water Reactions

Highly flammable. Sensitive to heat and air. Insoluble in water.

Reactivity Profile

Diisobutylamine can react vigorously with oxidizing materials . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

Inhalation of high concentrations of vapor will cause irritation of the respiratory tract and the lungs. Contact with liquid may result in severe skin and eye irritation. Exposure to concentrated vapors may result in corneal edema. Poisonous if swallowed.

Health Hazard

Diisobutylamine is a relatively strong base and is therefore irritating to the eyes, respiratory tract, and skin. Inhalation of vapors can result in pulmonary edema following prolonged exposure. Ingestion of liquid can cause severe burning of the esophagus.

Industrial uses

Diisobutylamine is used as a chemical intermediate in the manufacture of several agricultural and pharmaceutical products.

Safety Profile

Poison by ingestion. A dangerous fire hazard when exposed to heator flame; can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Nox

Metabolism

There is little information available on the metabolism of diisobutylamine.

Diisobutylamine Preparation Products And Raw materials

Raw materials

Preparation Products

6-HYDROXYMELATONIN

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View Lastest Price from Diisobutylamine manufacturers

Hebei Duling International Trade Co. LTD

Product: Diisobutylamine 110-96-3
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 300MT/month
Release date: 2022-11-26

Henan Bao Enluo International TradeCo.，LTD

Product: Diisobutylamine 110-96-3
Price: US $50.00/kg
Min. Order: 1kg
Purity: 99.9%
Supply Ability: 10000MT
Release date: 2023-08-02

Hebei Mojin Biotechnology Co., Ltd

Product: Diisobutylamine 110-96-3
Price: US $0.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000KG/month
Release date: 2023-07-03

110-96-3, DiisobutylamineRelated Search:

Hexetidine Bis(2-ethylhexyl)amine 2-Chloro-N,N-bis(2-methylpropyl)acetamide Diisobutylamine SOLASODINE SOLASONINE VERATRINE TRIS(2-ETHYLHEXYL)AMINE TOMATINE 2,2′-Azobis(2-methylpropionamidine) dihydrochloride DIISOBUTYLAMINE HYDROCHLORIDE Octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide Isobutylamine Dibutylamine Butylamine ISOBUTANE N,N-DIISOBUTYLETHYLENEDIAMINE AMO 1618

(i-C4H9)2NH

1-Propanamine,2-methyl-N-(2-methylpropyl)-

2-methyl-n-(2-methylpropyl)-1-propanamin

amine,diisobutyl

bis(2-Methylpropyl)amine

bis(beta-methylpropyl)amine

Di(-2-methylpropyl)amine

dibutylamine(non-specificname)

Di-n-isobutylaMine

Diisobutylamin

diisobutylamine,[flammableliquid]

N-(2-Methylpropyl)-2-methyl-1-propanamin

N-(2-Methylpropyl)-2-methyl-1-propanamine

N,N-Bis(2-methylpropyl)amine

N-Isobutyl-2-methyl-1-propanamine

AURORA KA-7633

DIBA

DIISOBUTYLAMINE

LABOTEST-BB LTBB000475

Diisobutylamine,99%

2-METHYL-N-(2-METHYLPROPYL)-1-PROPANAMINE

1,1'-Iminobis(2-methylpropane)

DiisobutylaMine, 99% 1LT

DiisobutylaMine, 99% 500ML

Diisobutylamine ISO 9001：2015 REACH

diisobutylamine diba

Nicotinamide Impurity 238

110-96-3

CH32CHCH22NH

110963

CH32CHCH2NHCH2CHCH32

AMINE

Amines

Building Blocks

Organic Building Blocks

Nitrogen Compounds

Amines

Nitrogen Compounds