ChemicalBook > CAS DataBase List > [2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE

[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE

Product Name
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE
CAS No.
13321-61-4
Chemical Name
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE
Synonyms
SKL180;NSC 647346;Ethyl(triphenylphosphoranylid;ETHYL (TRIPHENYLPHOSPHORANYLIDENE)PYRUVATE;Ethyl (triphenylphosphoranylidene)pyruvate,95%;Ethyl (triphenylphosphoranylidene)pyruvate 95%;Ethyl 2-oxo-3-(triphenylphosphoranylidene)propanoate;Ethyl 2-oxo-3-(triphenyl-l5-phosphanylidene)propanoate;[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE;[(Carboxycarbonyl)methylene]triphenylphosphorane ethyl ester
CBNumber
CB4286532
Molecular Formula
C23H21O3P
Formula Weight
376.38
MOL File
13321-61-4.mol
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[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Property

Melting point:
175 °C (dec.) (lit.)
Boiling point:
524.6±33.0 °C(Predicted)
Density 
1.20±0.1 g/cm3(Predicted)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26
WGK Germany 
3
HS Code 
29310099
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
518093
Product name
Ethyl (triphenylphosphoranylidene)pyruvate
Purity
95%
Packaging
25g
Price
$413
Updated
2024/03/01
Oakwood
Product number
103739
Product name
Ethyl (triphenylphosphoranylidene)pyruvate
Packaging
1g
Price
$30
Updated
2021/12/16
Oakwood
Product number
103739
Product name
Ethyl (triphenylphosphoranylidene)pyruvate
Packaging
5g
Price
$95
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
ING0003239
Product name
[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE
Purity
95.00%
Packaging
25G
Price
$1391.63
Updated
2021/12/16
Ambeed
Product number
A706887
Product name
Ethyl2-oxo-3-(triphenylphosphoranylidene)propanoate
Purity
95%
Packaging
250mg
Price
$103
Updated
2021/12/16
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[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Chemical Properties,Usage,Production

Chemical Properties

off-white to yellow or brown powder

Uses

Reactant for:

  • Wittig condensation
  • Chemoenzymic preparation of hexafluoroleucine and tetrafluoroleucine

Reactant for synthesis of:
  • Ahiral and chiral cyclic dehydro-α-amino acid derivatives through nucleophilic addition
  • Peptidyl α-keto-based inhibitors of cruzain
  • Deoxyfluoro-L-arabinofuranosyl triazole nucleoside derivatives with antiviral activity
  • Anti-human immunodificiency virus analogs

[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Preparation Products And Raw materials

Raw materials

Preparation Products

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[2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE Suppliers

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View Lastest Price from [2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Ethyl (triphenylphosphoranylidene)pyruvate 13321-61-4
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50 tons
Release date
2020-01-17

13321-61-4, [2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANERelated Search:


  • [2-(ETHOXYCARBONYL)-2-OXOETHYLIDENE]TRIPHENYLPHOSPHORANE
  • ETHYL (TRIPHENYLPHOSPHORANYLIDENE)PYRUVATE
  • Ethyl (triphenylphosphoranylidene)pyruvate, [2-(Ethoxycarbonyl)-2-oxoethylidene]triphenylphosphorane
  • Ethyl 2-oxo-3-(triphenylphosphoranylidene)propanoate
  • [(Carboxycarbonyl)methylene]triphenylphosphorane ethyl ester
  • NSC 647346
  • Ethyl (triphenylphosphoranylidene)pyruvate 95%
  • [2-(Ethoxycarbonyl)-2-oxoethylidene]triphenylphosphorane , 95 % min.
  • Ethyl(triphenylphosphoranylid
  • Ethyl (triphenylphosphoranylidene)pyruvate,95%
  • Propanoic acid, 2-oxo-3-(triphenylphosphoranylidene)-, ethyl ester
  • Ethyl 2-oxo-3-(triphenyl-l5-phosphanylidene)propanoate
  • SKL180
  • 13321-61-4
  • C6H53PCHCOCO2C2H5
  • C23H21O3P
  • Olefination
  • Synthetic Reagents
  • Wittig Reagents
  • C-C Bond Formation
  • C-C Bond Formation
  • Olefination
  • Wittig Reagents