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1,3-Dichloropropene

Product Name
1,3-Dichloropropene
CAS No.
542-75-6
Chemical Name
1,3-Dichloropropene
Synonyms
D-D;1,3-D;1,3-DICHLOROPENE;DICHLOROPROPYLENE;1,3-DICHLOROPROPYLENE;3-Chloropropenyl chloride;dd95;D-D92;D-D95;Nemex
CBNumber
CB4324650
Molecular Formula
C3H4Cl2
Formula Weight
110.97
MOL File
542-75-6.mol
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1,3-Dichloropropene Property

Melting point:
-60 °C
Boiling point:
97-112 °C(lit.)
Density 
1.2
vapor pressure 
E-isomer 3700 Pa, Z-isomer 3500 Pa at 25 °C
refractive index 
n20/D 1.472(lit.)
Flash point:
78 °F
storage temp. 
2-8°C
solubility 
soluble in Chloroform, Methanol
color 
Colorless to Light yellow to Light orange
Water Solubility 
<0.01 g/100 mL at 16.5 ºC
Merck 
14,3075
BRN 
1719556
Exposure limits
ACGIH: TWA 1 ppm (Skin)
NIOSH: TWA 1 ppm(5 mg/m3)
InChIKey
UOORRWUZONOOLO-OWOJBTEDSA-N
LogP
2.040
CAS DataBase Reference
542-75-6(CAS DataBase Reference)
IARC
2B (Vol. 41, Sup 7, 71) 1999
NIST Chemistry Reference
1-Propene, 1,3-dichloro-(542-75-6)
EPA Substance Registry System
1,3-Dichloropropene (542-75-6)
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Safety

Hazard Codes 
T,N
Risk Statements 
10-20/21-25-36/37/38-43-50/53-65-24/25-20
Safety Statements 
36/37-45-60-61
RIDADR 
UN 1992 3/PG 3
OEB
B
OEL
TWA: 1 ppm (5 mg/m3) [skin]
WGK Germany 
3
RTECS 
UC8310000
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29032990
Hazardous Substances Data
542-75-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H304May be fatal if swallowed and enters airways

H315Causes skin irritation

H317May cause an allergic skin reaction

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P331Do NOT induce vomiting.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
403733
Product name
1,3-Dichloropropene
Purity
90%, technical grade
Packaging
250ml
Price
$128
Updated
2024/03/01
Sigma-Aldrich
Product number
48530-U
Product name
1,3-Dichloropropene
Purity
cis + trans, analytical standard
Packaging
2000mg
Price
$51.5
Updated
2022/05/15
TCI Chemical
Product number
D0405
Product name
1,3-Dichloropropene (cis- and trans- mixture)
Purity
>92.0%(GC)
Packaging
25g
Price
$39
Updated
2024/03/01
TCI Chemical
Product number
D0405
Product name
1,3-Dichloropropene (cis- and trans- mixture)
Purity
>92.0%(GC)
Packaging
500g
Price
$99
Updated
2024/03/01
Alfa Aesar
Product number
L10332
Product name
1,3-Dichloropropene, cis + trans, tech. 90%
Packaging
100g
Price
$80.2
Updated
2021/12/16
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1,3-Dichloropropene Chemical Properties,Usage,Production

Description

This nematocide is used as a sol fumigant prior to crop cultivation. Mainly farmers and process operators employed at pesticide plants are exposed.

Chemical Properties

clear yellowish to brownish liquid

Chemical Properties

1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.

Uses

1,3-Dichloropropene (a technical-grade mixture of the cis-and transisomers) is used as a preplanting fumigant, mainly for the control of nematodes affecting the roots of plants, selected plant diseases, garden centipedes, wireworms, and weeds; as a solvent; and as an intermediate in the manufacture of 3,3-dichloro-1-propene and other pesticides. It is registered for use on all vegetable, fruit, and nut crops, all forage crops, tobacco, all fiber crops, and all nursery crops (EPA 1998). In Hawaii, 1,3-dichloropropene is used to control nematodes on pineapples at planting (Albrecht 1987). In 2009, three products containing 1,3-dichloropropene as an active ingredient were registered for restricted, non-residential use in the United States (EPA 2009). No products containing 1,3-dichloropropene are registered for use by homeowners (EPA 1998).

Uses

1,3-Dichloropropene is a soil fumigant /nematicide used mainly for the pre-plant control of most species of nematodes and soil insect pests in citrus, pineapples, deciduous fruits and nuts, grapes, berries and field and nursery crops. The product contains equal amounts of E- and Z-isomer. The Z-isomer is more biologically active than the E-isomer.

Uses

Widely used as a preplanting soil fumigant for the control of nematodes

Production Methods

1,3-DCP is produced either by high-temperature chlorination of propylene or from 1,3-dichloro-2-propanol by dehydration with phosphoryl chloride or phosphorus pentoxide in benzene. All commercial preparations of 1,3-DCP are mixtures of the cis- and trans-isomers.
According to SRI Consulting, Dow AgroSciences LLC (Freeport, Texas) is the only current manufacturer of 1,3- DCP. Active registrants of 1,3-DCP pesticide formulations include Dow AgroSciences LLC (Indianapolis, Indiana),Soil Chemicals Corporation (Hollister, California), and Trical (Hollister, California).

General Description

A clear colorless liquid. Flash point 95°F. Denser (at 10.2 lb / gal) than water and insoluble in water. Vapors are heavier than air. Used to make other chemicals and as soil fumigant.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

1,3-Dichloropropene reacts vigorously with oxidizing materials. Reacts with aluminum, active metals, and halogenated compounds. Also reacts with acids and thiocyanates. Corrosive to magnesium, magnesium alloys and aluminum alloys. Incompatible with some metal salts .

Health Hazard

VAPOR: Irritating to eyes, nose and throat. LIQUID: Will burn skin and eyes. Harmful if swallowed.

Fire Hazard

FLAMMABLE. POISONOUS GASES ARE PRODUCED IN FIRE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Toxic and irritating gases may be generated.

Agricultural Uses

Soil fumigant, Nematicide: This chemical is also used in combinations with dichloropropanes as a soil fumigant to kill nematodes, insects and fungus on cotton, potatoes, tobacco, sugar beets, vegetables, grain, citrus planting sites, deciduous fruit and nut-tree planting sites, and ornamental trees and floral sites. Top four applications in California are on sweet potatoes, carrots, wine grapes and outdoor propagation nurseries. It is used on a wide variety of crops. Not approved for use in EU countries. Actively registered in the U.S.

Trade name

DURHAM NEMATOCIDE®[C]; FUMAZONE®[C]; NEMAGON®[C]; NEMEX®; PROKILL NEMATOCIDE®[C]; TELONE®; TELONE II®; TELONE II-B®; TELONE® EC DRIP; VIDDEN D®; VORLEX®

Contact allergens

This nematocide is used as a soil fumigant prior to crop cultivation. Farmers and process operators employed at pesticide plants are mainly exposed

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. Mildly toxic by inhalation. A strong irritant. Mutation data reported. A pesticide. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidzers. Reacts vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and CHLORIDES.

Potential Exposure

Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.

Carcinogenicity

Technical-grade 1,3-dichloropropene (co ntaining 1.0% epichlorohydrin as a stabilizer) is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals. The technical-grade 1,3-dichloropropene used in the cancer studies in experimental animals was a mixture of cis- and trans-isomers and varied in purity and the stabilizer used (see Properties).

Metabolic pathway

Degradation of 14C-1,3-dichloropropene in aerobic soils in the dark at 25℃ at concentration of approximately 100 μg g-1 results in the formation of 3-chloroallyl alchohol, 3-chloroacrylic acid, numerous minor carboxylic acid metabolites, and carbon dioxide. In addition, there is extensive incorporation of 14C labeled material into the soil organic matter in the soils. By a specific bacterium (Pseudomonas cichorii 170) which is isolated from soil, 1,3-dichloropropene is degraded in different pathways from those of soil degradation. The terminal degradate by this bacterium is acetoaldehye which undergoes mineralization.

Shipping

UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.

Degradation

E-1,3-Dichloropropene (1) and Z-1,3-dichloropropene (2) degraded rapidly in aqueous solution (independent of pH) under both dark and light exposed conditions (25 °C), with DTW values of ca. 1-6 days. Hydrolytic dechlorination reactions yielded E- and Z-3-chloroallyl alcohol (3,4) and hydrochloric acid (5) as the major products. Further oxidation of 3 and 4 yielded E- and Z-3-chloroacrylic acid (6, 7) as minor products (McCall, 1987; Milano et al., 1988; Batzer and Yoder, 1995).
1,3-Dichloropropene degraded in the vapour phase (with ozone and hydroxyl radicals) to yield chloroacetaldehyde (8), formyl chloride (9) and chloroacetic acid (10 (Tuazon et al., 1984). The estimated air photolysis DT50 was ca. 7-12 hours (Roby and Melichar, 1997).

Toxicity evaluation

In water hydrolyzes to 3-chloropropenol and chloride ion. Both isomers of 3-chloropropenol are toxic but less so than the parent compound.

Incompatibilities

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.

Waste Disposal

Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.

1,3-Dichloropropene Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1,3-Dichloropropene manufacturers

Hebei Mojin Biotechnology Co., Ltd
Product
1,3-Dichloropropene 542-75-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-06-20
Shijiazhuang tongyang Import and Export Co., LTD
Product
1,3-Dichloropropene 542-75-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99
Supply Ability
100 mt
Release date
2021-08-13
Career Henan Chemical Co
Product
1,3-Dichloropropene 542-75-6
Price
US $1.00/g
Min. Order
1g
Purity
99%
Supply Ability
1000KGS
Release date
2019-12-24

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