ChemicalBook > CAS DataBase List > Methyl 2-chlorophenylacetate

Methyl 2-chlorophenylacetate

Product Name
Methyl 2-chlorophenylacetate
CAS No.
57486-68-7
Chemical Name
Methyl 2-chlorophenylacetate
Synonyms
2-(2-chlorophenyl)propanoate;METHYL 2-CHLOROPHENYLACETATE;Methyl 2-chlorobenzeneacetate;Methyl 2-chlorophenylacetate,98%;METHYL 2-(2-CHLOROPHENYL)ACETATE;Methyl (2-Chlorophenyl)acetate >Methyl 2-chlorophenylacetate, 98% 5GR;Methyl 2-(2-chlorophenyl)acetate ,98%;2-CHLOROPHENYLACETIC ACID METHYL ESTER;O-Chloro-phenylacetic acid methyl ester
CBNumber
CB4356800
Molecular Formula
C9H9ClO2
Formula Weight
184.62
MOL File
57486-68-7.mol
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Methyl 2-chlorophenylacetate Property

Boiling point:
128 °C / 23mmHg
Density 
1.21
refractive index 
1.524-1.526
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid
color 
Clear colorless
InChI
InChI=1S/C9H9ClO2/c1-12-9(11)6-7-4-2-3-5-8(7)10/h2-5H,6H2,1H3
InChIKey
KHBWTRFWQROKJZ-UHFFFAOYSA-N
SMILES
C1(CC(OC)=O)=CC=CC=C1Cl
CAS DataBase Reference
57486-68-7(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Safety Statements 
24/25
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
EME00173
Product name
Methyl 2-(2-chlorophenyl)acetate
Packaging
1g
Price
$73.1
Updated
2025/07/31
TCI Chemical
Product number
C1740
Product name
Methyl (2-Chlorophenyl)acetate
Purity
>98.0%(GC)
Packaging
25g
Price
$58
Updated
2025/07/31
TCI Chemical
Product number
C1740
Product name
Methyl (2-Chlorophenyl)acetate
Purity
>98.0%(GC)
Packaging
100g
Price
$171
Updated
2025/07/31
TRC
Product number
M295660
Product name
Methyl (2-Chlorophenyl)acetate
Packaging
500mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
J51808
Product name
Methyl (2-Chlorophenyl)acetate
Packaging
5g
Price
$10
Updated
2021/12/16
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Methyl 2-chlorophenylacetate Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Synthesis

67-56-1

2444-36-2

57486-68-7

To a solution of o-chlorophenylacetic acid (1.04 g, 6 mmol) in methanol (25 mL) was added concentrated sulfuric acid (6 drops) and the reaction mixture was heated to reflux for 16 hours. Upon completion of the reaction, the methanol was removed by concentration under reduced pressure, and the residue was dissolved in ethyl acetate and washed with saturated aqueous sodium bicarbonate, water and saturated aqueous sodium chloride in that order. The organic layer was dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give o-chlorophenylacetic acid methyl ester (1.08 g, yield 97.5%) as a light yellow oil.GC-MS (EI) m/z: 184, 186 [M+].

References

[1] Bioorganic and Medicinal Chemistry, 2003, vol. 11, # 13, p. 2843 - 2866
[2] Tetrahedron Letters, 2003, vol. 44, # 2, p. 331 - 334
[3] Patent: WO2005/7165, 2005, A1. Location in patent: Page 43
[4] Patent: WO2005/7633, 2005, A1. Location in patent: Page 30-31
[5] Bioorganic and Medicinal Chemistry Letters, 2013, vol. 23, # 20, p. 5515 - 5518

Methyl 2-chlorophenylacetate Preparation Products And Raw materials

Raw materials

2-Chlorobenzyl chloride 2-(2-Chlorophenyl)acetonitrile Sodium cyanide Acetic acid Sulfuric acid

Preparation Products

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View Lastest Price from Methyl 2-chlorophenylacetate manufacturers

Henan Fengda Chemical Co., Ltd
Product
Methyl 2-chlorophenylacetate 57486-68-7
Price
US $5.00-0.10/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-04-15

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