ChemicalBook > CAS DataBase List > 3-Chlorobenzylamine

3-Chlorobenzylamine

Product Name
3-Chlorobenzylamine
CAS No.
4152-90-3
Chemical Name
3-Chlorobenzylamine
Synonyms
TIMTEC-BB SBB004155;RARECHEM AL BW 0019;3-CHLOROBENZYLAMINE;M-CHLOROBENZYL AMINE;3-Chlorobenzylamine 97%;3-Chlorobenzylamine,98%;3-Chlorobenzylamine >3-Chlorobenzylamine, 97+%;3-chloro-benzenemethanamin;m-Chlorobenzenemethanamine
CBNumber
CB4362966
Molecular Formula
C7H8ClN
Formula Weight
141.6
MOL File
4152-90-3.mol
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3-Chlorobenzylamine Property

Melting point:
97-98 °C
Boiling point:
110-112 °C/17 mmHg (lit.)
Density 
1.159 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.559(lit.)
Flash point:
209 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
8.77±0.10(Predicted)
form 
Liquid
Specific Gravity
1.159
color 
Clear colorless to faint yellow
Sensitive 
Air Sensitive
BRN 
774509
CAS DataBase Reference
4152-90-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzenemethanamine, 3-chloro-(4152-90-3)
EPA Substance Registry System
Benzenemethanamine, 3-chloro- (4152-90-3)
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Safety

Hazard Codes 
C,Xi
Risk Statements 
34-20/21/22-36/37/38
Safety Statements 
26-36/37/39-45-36
RIDADR 
UN 2735 8/PG 2
WGK Germany 
3
Hazard Note 
Corrosive
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29214990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
127167
Product name
3-Chlorobenzylamine
Purity
98%
Packaging
5g
Price
$75.7
Updated
2025/07/31
TCI Chemical
Product number
C1089
Product name
3-Chlorobenzylamine
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$35
Updated
2025/07/31
TCI Chemical
Product number
C1089
Product name
3-Chlorobenzylamine
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$96
Updated
2025/07/31
TRC
Product number
C363585
Product name
3-Chlorobenzylamine
Packaging
500mg
Price
$45
Updated
2021/12/16
AK Scientific
Product number
J94939
Product name
3-Chlorobenzylamine
Packaging
5g
Price
$27
Updated
2021/12/16
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3-Chlorobenzylamine Chemical Properties,Usage,Production

Chemical Properties

clear colorless to faint yellow liquid

Uses

3-Chlorobenzylamine is used as pharmaceutical, pesticide and dye intermediates. It is used in the synthesis of 3-Chlorobenzamide and N-(3-Chlorobenzyl)-4-(2-indolyl)-2-pyrimidinamine.

General Description

3-Chlorobenzylamine undergoes reductive amination during dihydroquinolone synthesis. It is used in the synthesis of N- (3-chlorobenzyl) toluene-p-sulphonamide.

Synthesis

766-84-7

4152-90-3

The general procedure for the synthesis of 3-chlorobenzylamine from 3-chlorobenzonitrile was as follows: in a 25 mL round-bottomed flask, CuNP/WS catalyst was added to a mixed solution containing 5 mL of double-distilled water and 1 mmol of 3-chlorobenzonitrile. Subsequently, 4 mmol NaBH4 was added to the reaction mixture in 4 portions and stirred at room temperature for an appropriate time. The reaction process was monitored by thin layer chromatography (TLC) using ethyl acetate/hexane (1:5) as eluent. After completion of the reaction, the reaction mixture was filtered and the catalyst was rinsed twice with dichloromethane. The organic phase was washed with distilled water, dried over anhydrous MgSO4 and finally the solvent was evaporated under vacuum to give the target product 3-chlorobenzylamine.

References

[1] Journal of Organic Chemistry, 2012, vol. 77, # 1, p. 221 - 228
[2] ChemSusChem, 2017, vol. 10, # 5, p. 842 - 846
[3] Journal of the American Chemical Society, 2017, vol. 139, # 38, p. 13554 - 13561
[4] Journal of Medicinal Chemistry, 2017, vol. 60, # 19, p. 7965 - 7983
[5] Inorganic and Nano-Metal Chemistry, 2018, vol. 48, # 3, p. 176 - 181

3-Chlorobenzylamine Preparation Products And Raw materials

Raw materials

3-Chlorobenzaldehyde ZINC N,N-Dimethylformamide Ammonium formate 3-Chlorobenzyl chloride Glycine Diethyl ether Lithium Aluminum Hydride 3-Chlorobenzonitrile Hydroxylamine hydrochloride Hexamethylenetetramine

Preparation Products

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3-Chlorobenzylamine Suppliers

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View Lastest Price from 3-Chlorobenzylamine manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
3-Chlorobenzylamine 4152-90-3
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100tons
Release date
2023-08-10
Henan Fengda Chemical Co., Ltd
Product
3-Chlorobenzylamine 4152-90-3
Price
US $8.00-0.40/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2024-03-22
Career Henan Chemical Co
Product
3-Chlorobenzylamine 4152-90-3
Price
US $1.00/KG
Min. Order
1KG
Purity
85.0-99.8%
Supply Ability
20tons
Release date
2020-01-08

4152-90-3, 3-ChlorobenzylamineRelated Search:

3-Iodobenzylamine Dibenzylamine 4-Hydroxybenzylamine Phenoxybenzamine hydrochloride 3-Chloroperoxybenzoic acid 3-Chlorobenzyl chloride 3,4-DICHLOROBENZENE-1-CARBOHYDRAZIDE 3,4-Dichlorobenzylamine 2,3-DICHLOROBENZAMIDE Tetrachlorophthalimide 3-CHLOROBENZAMIDE 2-Amino-5-chlorobenzamide 2,5-DICHLOROBENZHYDRAZIDE (3,4-Dichlorobenzyl)methylamine 5-CHLOROSALICYLANILIDE 3-Chloro-4-methylbenzylamine 2-(AMINOMETHYL)-4-CHLOROPHENOL N-(4-AMINO-2-METHYLPHENYL)-4-CHLOROPHTHALIMIDE

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  • 4152-90-3
  • ClC6H4CH2NH2
  • AMINE
  • C7
  • Amines
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