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tert-Butyl methacrylate

Product Name
tert-Butyl methacrylate
CAS No.
585-07-9
Chemical Name
tert-Butyl methacrylate
Synonyms
TBMA;T-BUTYL METHACRYLATE;tert-Butylmethacrylat;AgeSin?TBMA;stabilizedwithmehq;ert-Butylmethacrylate;TERT-BUTYL METHACRYLATE;TERTIARY-BUTYL METHACRYLATE;Methacrylic acid tert-butyl;Butylmethacrylatetechnicalca
CBNumber
CB4392031
Molecular Formula
C8H14O2
Formula Weight
142.2
MOL File
585-07-9.mol
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tert-Butyl methacrylate Property

Melting point:
-60°C
Boiling point:
132 °C (lit.)
Density 
0.875 g/mL at 25 °C (lit.)
vapor pressure 
7.13hPa at 25℃
refractive index 
n20/D 1.415(lit.)
Flash point:
81°F
storage temp. 
2-8°C
solubility 
Insoluble in water
form 
clear liquid
color 
Colorless
Water Solubility 
464mg/L at 20℃
InChI
InChI=1S/C8H14O2/c1-6(2)7(9)10-8(3,4)5/h1H2,2-5H3
InChIKey
SJMYWORNLPSJQO-UHFFFAOYSA-N
SMILES
C(OC(C)(C)C)(=O)C(C)=C
LogP
2.54 at 25℃
CAS DataBase Reference
585-07-9(CAS DataBase Reference)
EPA Substance Registry System
tert-Butyl methacrylate (585-07-9)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-38
Safety Statements 
16
RIDADR 
3272
WGK Germany 
1
RTECS 
OZ3675500
TSCA 
TSCA listed
HazardClass 
3
PackingGroup 
III
HS Code 
29161400
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P242Use only non-sparking tools.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
463353
Product name
tert-Butyl methacrylate
Purity
98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor
Packaging
100ml
Price
$84.2
Updated
2024/03/01
Sigma-Aldrich
Product number
463353
Product name
tert-Butyl methacrylate
Purity
98%, contains 200 ppm monomethyl ether hydroquinone as inhibitor
Packaging
250ml
Price
$102
Updated
2024/03/01
TCI Chemical
Product number
M0326
Product name
tert-Butyl Methacrylate Monomer (stabilized with MEHQ)
Purity
>98.0%(GC)
Packaging
25mL
Price
$36
Updated
2024/03/01
TCI Chemical
Product number
M0326
Product name
tert-Butyl Methacrylate Monomer (stabilized with MEHQ)
Purity
>98.0%(GC)
Packaging
500mL
Price
$129
Updated
2024/03/01
scipoly
Product number
M-210
Product name
t-Butyl methacrylate
Packaging
50g
Price
$36
Updated
2024/07/03
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tert-Butyl methacrylate Chemical Properties,Usage,Production

Description

Tert-butyl methacrylate (TBMA) is an ester of Methacrylic acid used as a raw material component in synthesising polymers. TBMA is a functional monomer consisting of a methacrylate group with a characteristic high reactivity and a cyclic hydrophobic group. Copolymers of tert-Butyl Methacrylate (TBMA) can be prepared with (meth)acrylic acid and its salts, amides, and esters, as well as with (meth)acrylates, acrylonitrile, maleic acid esters, vinyl acetate, vinyl chloride, vinylidene chloride, styrene, butadiene, unsaturated polyesters and drying oils, etc. It can be used in emulsion polymerization similar to other well-known acrylates like Butyl Methacrylate or Methylmethacrylate. It is a very useful feedstock for chemical syntheses because it readily undergoes addition reactions with a wide variety of organic and inorganic compounds. It imparts chemical resistance, adhesion, hydrophobicity, hardness, scratch resistance, heat resistance, high solids, and weatherability to polymers.

Chemical Properties

Colorless liquid

Uses

tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, biomaterials and flocculants.

General Description

A colorless liquid with an ester like odor. Flash point below 141°F. Less dense than water and insoluble in water.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

TERT-BUTYL METHACRYLATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.

Health Hazard

Inhalation or contact with material may irritate or burn skin and eyes. Fire may produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Flammability and Explosibility

Flammable

Purification Methods

Purify as for butyl acrylate. [Beilstein 2 IV 1582.]

tert-Butyl methacrylate Preparation Products And Raw materials

Raw materials

Preparation Products

optical diskbase material modified PMMA copolymer
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tert-Butyl methacrylate Suppliers

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View Lastest Price from tert-Butyl methacrylate manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd
Product
tert-Butyl methacrylate 585-07-9
Price
US $55.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20 tons
Release date
2024-11-26
Shandong Deshang Chemical Co., Ltd.
Product
tert-Butyl methacrylate 585-07-9
Price
US $10.00-7.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10 tons
Release date
2024-07-16
Hebei Yanxi Chemical Co., Ltd.
Product
tert-Butyl methacrylate 585-07-9
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2023-09-11

585-07-9, tert-Butyl methacrylateRelated Search:

Isobutyl acrylate POLY(N-BUTYL METHACRYLATE) Buprofezin Methyl acrylate Butyl acrylate Cyhalofop-butyl BUTYL OLEATE tert-Butyl acrylate tert-Butanol Butyl methacrylate 2,2,3,4,4,4-Hexafluorobutyl methacrylate Dibutyl phthalate Lercanidipine DI-TERT-BUTYL 2 6-DIMETHYL-1 4-DIHYDROP& 2-Methyl-2-adamantylmethacrylate Coumarin 338 Tipranavir TRITYL METHACRYLATE

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