1,2-Epoxy-4-vinylcyclohexane
- Product Name
- 1,2-Epoxy-4-vinylcyclohexane
- CAS No.
- 106-86-5
- Chemical Name
- 1,2-Epoxy-4-vinylcyclohexane
- Synonyms
- EP-101;epoxide101;Epoxide 101;unoxatepoxide101;Unoxat epoxide 101;4-Vinylcyclohexene oxide;vinylcyclohexenemonoxide;3-Vinylcyclohexene oxide;4-Vinyl epoxycyclohexane;Vinylcyclohexene monoxide
- CBNumber
- CB4410193
- Molecular Formula
- C8H12O
- Formula Weight
- 124.18
- MOL File
- 106-86-5.mol
1,2-Epoxy-4-vinylcyclohexane Property
- Melting point:
- -100°C(lit.)
- Boiling point:
- 169 °C(lit.)
- Density
- 0.952 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.469(lit.)
- Flash point:
- 115 °F
- storage temp.
- 2-8°C
- form
- clear liquid
- color
- Colorless to Almost colorless
- Specific Gravity
- 0.952
- InChI
- InChI=1S/C8H12O/c1-2-6-3-4-7-8(5-6)9-7/h2,6-8H,1,3-5H2
- InChIKey
- SLJFKNONPLNAPF-UHFFFAOYSA-N
- SMILES
- C12C(O1)CCC(C=C)C2
- CAS DataBase Reference
- 106-86-5(CAS DataBase Reference)
- NIST Chemistry Reference
- 7-Oxabicyclo[4.1.0]heptane, 3-ethenyl-(106-86-5)
- EPA Substance Registry System
- 7-Oxabicyclo[4.1.0]heptane, 3-ethenyl- (106-86-5)
Safety
- Hazard Codes
- T,Xn
- Risk Statements
- 45-10-20/21/22-40-36-22
- Safety Statements
- 53-16-23-36/37/39-45-36/37-26
- RIDADR
- UN 3271 3/PG 3
- WGK Germany
- 3
- RTECS
- RN8770000
- HazardClass
- 3.2
- PackingGroup
- III
- HS Code
- 29109000
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H226Flammable liquid and vapour
H302Harmful if swallowed
H319Causes serious eye irritation
H351Suspected of causing cancer
- Precautionary statements
-
P201Obtain special instructions before use.
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P308+P313IF exposed or concerned: Get medical advice/attention.
N-Bromosuccinimide Price
- Product number
- 152544
- Product name
- 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers
- Purity
- 98%
- Packaging
- 250ml
- Price
- $117.8
- Updated
- 2025/07/31
- Product number
- E0956
- Product name
- 1,2-Epoxy-4-vinylcyclohexane (mixture of isomers)
- Purity
- >98.0%(GC)
- Packaging
- 25mL
- Price
- $25
- Updated
- 2025/07/31
- Product number
- E0956
- Product name
- 1,2-Epoxy-4-vinylcyclohexane (mixture of isomers)
- Purity
- >98.0%(GC)
- Packaging
- 250mL
- Price
- $95
- Updated
- 2025/07/31
- Product number
- E892145
- Product name
- 1,2-Epoxy-4-vinylcyclohexane
- Packaging
- 2.5mL
- Price
- $45
- Updated
- 2021/12/16
- Product number
- 2309-1-01
- Product name
- 4-Vinyl-1-cyclohexene 1,2-epoxide, mixture of isomers
- Purity
- 98%
- Packaging
- 25g
- Price
- $15
- Updated
- 2021/12/16
1,2-Epoxy-4-vinylcyclohexane Chemical Properties,Usage,Production
Chemical Properties
Colorless liquid
Uses
Vinylcyclohexene monoxide is a chemical intermediate; it can be copolymerized with other epoxides to yield polyglycols having unsaturation available for further reaction.
Definition
ChEBI: 3-Vinyl-7-oxabicyclo[4.1.0]heptane is an oxacycle.
Synthesis Reference(s)
Tetrahedron Letters, 22, p. 2089, 1981 DOI: 10.1016/S0040-4039(01)93284-8
Synthesis
100-40-3
106-86-5
General Steps: 1. Add known amounts of 4-vinyl-1-cyclohexene and TBHP (tert-butyl hydroperoxide) without co-solvent in a 0.25 L capacity jacketed four-neck glass reactor. Set the feed molar ratio (FMR) of olefin to TBHP from 1:1 to 10:1. 2. Start the stirrer and adjust the stirring rate to 300-600 rpm. Heat the reaction mixture through the water bath and reactor jacket, and monitor the temperature using a digital thermocouple to ensure that the temperature of the reaction mixture stabilizes in the range of 323-353 K, with a fluctuation of no more than ±0.5 K. 3. When the reaction mixture reaches a constant temperature, set the FMR to 1:1 to 10:1, without adding co-solvent. 3. When the reaction mixture reached a constant temperature, a known amount of polymer loaded catalyst (0.15-0.6 mol Mo) was added. The time of catalyst addition was recorded as the reaction onset time (t = 0) and an initial sample was taken immediately. 4. Samples were taken at specific time intervals during the reaction and analyzed using Shimadzu GC-2014 gas chromatography (GC). 5. The experimental results showed that the PBI.Mo and Ps.AMP.Mo catalysts exhibited high selectivity in the epoxidation reaction of 4-vinyl-1-cyclohexene, which predominantly yielded 1,2-epoxy-4-vinylcyclohexane, and the GC analyses did not detect terminal or dicyclic oxide products. Detailed results of the batch experiments are discussed in Sect.
Toxics Screening Level
The initial threshold screening level (ITSL) for 1,2-epoxy-4-vinylcyclohexane is 6.0 μg/m3 based on an annual averaging time.
References
[1] RSC Advances, 2014, vol. 4, # 61, p. 32054 - 32062
[2] Applied Catalysis A: General, 2013, vol. 466, p. 142 - 152
[3] Journal of the American Chemical Society, 2009, vol. 131, # 36, p. 12890 - 12891
[4] Patent: CN108101868, 2018, A. Location in patent: Paragraph 0027-0068
[5] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 21, p. 3115 - 3116
1,2-Epoxy-4-vinylcyclohexane Preparation Products And Raw materials
Raw materials
Preparation Products
1,2-Epoxy-4-vinylcyclohexane Suppliers
- Tel
- 800-4238616
- Fax
- +1-888-520-1075 / +1-503-283-1987
- sales@tciamerica.com
- Country
- Americas
- ProdList
- 23653
- Advantage
- 75
View Lastest Price from 1,2-Epoxy-4-vinylcyclohexane manufacturers
- Product
- 1,2-Epoxy-4-vinylcyclohexane 106-86-5
- Price
- US $0.00/Kg/Drum
- Min. Order
- 1KG
- Purity
- 98%min
- Supply Ability
- 20 tons
- Release date
- 2021-08-02
- Product
- 1,2-Epoxy-4-vinylcyclohexane 106-86-5
- Price
- US $30.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 100 tons
- Release date
- 2024-08-13
- Product
- 1,2-Epoxy-4-vinylcyclohexane 106-86-5
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 10 mt
- Release date
- 2024-12-09