Chemical nature Synthesis and reactions
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1-Bromohexane

Chemical nature Synthesis and reactions
Product Name
1-Bromohexane
CAS No.
111-25-1
Chemical Name
1-Bromohexane
Synonyms
N-HEXYL BROMIDE;Bromohexane;Hexylbromid;1-Bromhexan;HEXYL BROMIDE;1-BROMOHEXANE;1-bromo-hexan;N-BROMOHEXANE;JACS-111-25-1;1-hexylbromide
CBNumber
CB4447030
Molecular Formula
C6H13Br
Formula Weight
165.07
MOL File
111-25-1.mol
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1-Bromohexane Property

Melting point:
−85 °C(lit.)
Boiling point:
154-158 °C(lit.)
Density 
1.176 g/mL at 25 °C(lit.)
vapor density 
5.7 (vs air)
vapor pressure 
<10 mm Hg ( 20 °C)
refractive index 
n20/D 1.448(lit.)
Flash point:
135 °F
storage temp. 
Store below +30°C.
solubility 
<1g/l
form 
Liquid
color 
Clear
Water Solubility 
Immiscible with water.
BRN 
1731290
Dielectric constant
5.8（24℃）
Stability:
Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
InChIKey
MNDIARAMWBIKFW-UHFFFAOYSA-N
CAS DataBase Reference
111-25-1(CAS DataBase Reference)
NIST Chemistry Reference
Hexane, 1-bromo-(111-25-1)
EPA Substance Registry System
Hexane, 1-bromo- (111-25-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38-10
Safety Statements 
26-36-16
RIDADR 
UN 1993 3/PG 3
WGK Germany 
2
RTECS 
MO0925000
TSCA 
Yes
HazardClass 
3
PackingGroup 
III
HS Code 
29033036
Toxicity
LD50 orally in Rabbit: > 2000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P241Use explosion-proof electrical/ventilating/lighting/…/equipment.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B68240
Product name
1-Bromohexane
Purity
98%
Packaging
100g
Price
$23.5
Updated
2024/03/01
Sigma-Aldrich
Product number
B68240
Product name
1-Bromohexane
Purity
98%
Packaging
1kg
Price
$171
Updated
2024/03/01
Sigma-Aldrich
Product number
8.01603
Product name
1-Bromohexane
Purity
for synthesis
Packaging
100mL
Price
$40
Updated
2024/03/01
Sigma-Aldrich
Product number
8.01603
Product name
1-Bromohexane
Purity
for synthesis
Packaging
500mL
Price
$67.3
Updated
2024/03/01
TCI Chemical
Product number
B0600
Product name
1-Bromohexane
Purity
>98.0%(GC)
Packaging
25g
Price
$25
Updated
2024/03/01
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1-Bromohexane Chemical Properties,Usage,Production

Chemical nature

1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.

Synthesis and reactions

Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.

Chemical Properties

1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group.

Uses

1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds.

Application

1-Bromohexane is a very useful synthetic intermediate，it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond.

Synthesis Reference(s)

Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0

Purification Methods

Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]

1-Bromohexane Preparation Products And Raw materials

Raw materials

Preparation Products

2-(2-HEXYLOXYETHOXY)ETHANOL TRIHEXYLPHOSPHINE Sodium 1-hexanesulfonate Sodium 1-hexanesulfonate monohydrate 1-(3 5-DIMETHOXYPHENYL)HEPTAN-1-ONE 96 (N-HEXYL)TRIMETHYLAMMONIUM BROMIDE 2-Hexyldecanoic Acid
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1-Bromohexane Suppliers

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View Lastest Price from 1-Bromohexane manufacturers

Hebei Miaoyin Technology Co.,Ltd
Product
Hexylbromid 111-25-1
Price
US $20.00/kg
Min. Order
1kg
Purity
99.9%
Supply Ability
10000
Release date
2023-04-14
Hebei Yanxi Chemical Co., Ltd.
Product
1-Bromohexane 111-25-1
Price
US $0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
20tons
Release date
2023-10-13
Hebei Chuanghai Biotechnology Co,.LTD
Product
bromohexane 111-25-1
Price
US $19.00/KG
Min. Order
1KG
Purity
99.%
Supply Ability
10 ton
Release date
2024-07-30

111-25-1, 1-BromohexaneRelated Search:

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  • HALOGEN
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