TETRAPROPYLAMMONIUM PERRUTHENATE

Uses

Product Name: TETRAPROPYLAMMONIUM PERRUTHENATE
CAS No.: 114615-82-6
Chemical Name: TETRAPROPYLAMMONIUM PERRUTHENATE
Synonyms: TPAP;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;Tetrapropylammonium tetraoxoruthenate;TerapropylaMMoniuMperruthenate;etrapropylammoniumperruthenate;TETRAPROPYLAMMONIUM PERRUTHENATE;TetrapropylaMMoniuM perruthenate 97%;tetrapropylammonium perruthenate(VII);Tetrapropylammonium Perruthenate (TPAP);TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)
CBNumber: CB4468073
Molecular Formula: C12H28NO4Ru
Formula Weight: 351.43
MOL File: 114615-82-6.mol

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TETRAPROPYLAMMONIUM PERRUTHENATE Property

Melting point:: ~160 °C (dec.) (lit.)
storage temp.: Inert atmosphere,2-8°C
solubility: Methanol (Slightly)
form: crystal
color: green
Water Solubility: Insoluble in water.
Sensitive: Hygroscopic
Stability:: store cold
InChIKey: NQSIKKSFBQCBSI-UHFFFAOYSA-N

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Safety

Hazard Codes: O,Xi
Risk Statements: 5-8-36/37/38
Safety Statements: 17-26-36
RIDADR: UN 1479 5.1/PG 2
WGK Germany: 3
F: 3-10
HazardClass: 5.1
PackingGroup: III
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H272May intensify fire; oxidizer

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P220Keep/Store away from clothing/…/combustible materials.

P221Take any precaution to avoid mixing with combustibles/…

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 330744
Product name: Tetrapropylammonium perruthenate
Purity: 97%
Packaging: 250mg
Price: $72.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 330744
Product name: Tetrapropylammonium perruthenate
Purity: 97%
Packaging: 1g
Price: $252
Updated: 2024/03/01

TCI Chemical

Product number: T1559
Product name: Tetrapropylammonium Perruthenate
Packaging: 1g
Price: $93
Updated: 2024/03/01

TCI Chemical

Product number: T1559
Product name: Tetrapropylammonium Perruthenate
Packaging: 5g
Price: $270
Updated: 2024/03/01

Alfa Aesar

Product number: B24511
Product name: Tetra-n-propylammonium perruthenate(VII)
Purity: 98%
Packaging: 0.5g
Price: $82
Updated: 2024/03/01

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TETRAPROPYLAMMONIUM PERRUTHENATE Chemical Properties,Usage,Production

Uses

A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones.

Chemical Properties

dark green solid

Uses

Tetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.

Definition

ChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.

General Description

Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.

Purification Methods

It is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially.

TETRAPROPYLAMMONIUM PERRUTHENATE Preparation Products And Raw materials

Raw materials

Preparation Products

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TETRAPROPYLAMMONIUM PERRUTHENATE Suppliers

Belgium 2 Brazil 1 China 195 France 1 Germany 4 India 5 Japan 2 South Korea 1 Switzerland 1 United Kingdom 6 United States 27 Global 245

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View Lastest Price from TETRAPROPYLAMMONIUM PERRUTHENATE manufacturers

Career Henan Chemical Co

Product: TETRAPROPYLAMMONIUM PERRUTHENATE 114615-82-6
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000KGS
Release date: 2019-12-23

114615-82-6, TETRAPROPYLAMMONIUM PERRUTHENATERelated Search:

Tetrapropylammonium hydroxide Tetrapropylammonium bromide Oxalyl chloride 1 4-BIS(DIPHENYLAMINO)BENZENE Zinc peroxide Tetrakis-(u-acetato-O,O'')-diruthenium Dodecyltrimethylammonium Bromide Ruthenium Ruthenium dioxide TETRAPROPYLAMMONIUM PERRUTHENATE

TETRAPROPYLAMMONIUM PERRUTHENATE

TETRA-N-PROPYLAMMONIUM PERRUTHENATE

TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)

TPAP

Tetrapropylammonium tetraoxoruthenate

TerapropylaMMoniuMperruthenate

TetrapropylaMMoniuM perruthenate,97% TPAP, (n-C3H7)4NRuO4

1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoru

TetrapropylaMMoniuM perruthenate,TPAP,(n-C3H7)NRuO4

TetrapropylaMMoniuM perruthenate 97%

Tetrapropylammonium perruthenate, min. 97%

Tetrapropylammoniumperruthenate,min.97%TPAP

1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-)

Tetrapropylammonium Perruthenate (TPAP)

Tetra-n-propylammonium perruthenate(VII), 98+%

Tetra n-propylammonium perruthenate Oxidation

tetrapropylammonium perruthenate(VII)

1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-) (1:1)

etrapropylammoniumperruthenate

114615-82-6

C12H28NRuO4

C3H74NRuO4

CH3CH224NRuO4

CH3CH2CH24NRuO4

C12H28NO4Ru

Quaternary Ammonium Compounds

Classes of Metal Compounds

Oxidation

Transition Metal Compounds

Transition Metal Complexes (Environmentally-friendly Oxidation)

Catalysts for Organic Synthesis

Metal Complexes

Ammonium Polyhalides, etc. (Quaternary)

Homogeneous Catalysts

Ru (Ruthenium) Compounds

Environmentally-friendly Oxidation

Others

Synthetic Reagents

Boron, Nitrile, Thio,& TM-Cpds

Ammonium Polyhalides, etc. (Quaternary)

Catalysts for Organic Synthesis

Classes of Metal Compounds

Environmentally-friendly Oxidation

Homogeneous Catalysts

Metal Complexes

Oxidation

Quaternary Ammonium Compounds

Ru (Ruthenium) Compounds

Synthetic Organic Chemistry

Transition Metal Complexes (Environmentally-friendly Oxidation)

Transition Metal Compounds

Ru

Alkylammonium salt