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ChemicalBook > CAS DataBase List > ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

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Product Name
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
CAS No.
12245-39-5
Chemical Name
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
Synonyms
NSC 240030;rh(acac)(cod);Acetylacetonato(1,5-;(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)RH&;acetylacetonate-1,5-cyclooctadienerhodium;ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I);Acetylacetonato(cycloocta-1,5-diene)rhodium(I);(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium;(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu;(Acetylacetonato)(1,5-cyclooctadiene)rhodium(Ⅰ)
CBNumber
CB4469944
Molecular Formula
C13H19O2Rh
Formula Weight
310.19
MOL File
12245-39-5.mol
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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Property

Melting point:
138-140 °C(lit.)
storage temp. 
Inert atmosphere,2-8°C
form 
Crystals
color 
Yellow to orange
Sensitive 
Air Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey
WDIAJTWVVLHUJU-SUESZSCISA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
RTECS 
VI9292000
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
683108
Product name
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Purity
99%
Packaging
2g
Price
$977
Updated
2024/03/01
Sigma-Aldrich
Product number
335029
Product name
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Purity
99%
Packaging
100mg
Price
$125
Updated
2023/06/20
Sigma-Aldrich
Product number
8.24420
Product name
Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
Purity
for synthesis
Packaging
500mg
Price
$91.2
Updated
2023/01/07
Sigma-Aldrich
Product number
8.24420
Product name
Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
Purity
for synthesis
Packaging
100mg
Price
$139
Updated
2023/01/07
Alfa Aesar
Product number
H26083
Product name
(1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate
Packaging
250mg
Price
$198
Updated
2023/06/20
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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Chemical Properties,Usage,Production

Reactions

  1. Precursor for asymmetric hydrogenation reactions.
  2. Rh-catalyzed carbozincation of ynamides. 

Chemical Properties

Orange crystal

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

General Description

Atomic number of base material: 45 Rhodium

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
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Shanghai Hanhong Scientific Co.,Ltd.
Tel
021-54306202 13764082696;
Email
info@hanhongsci.com
Country
China
ProdList
42982
Advantage
64
Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
ProdList
32344
Advantage
50
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
335
Advantage
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Chengdu Ai Keda Chemical Technology Co., Ltd.
Tel
4008-755-333 18080918076
Fax
028-86757656
Email
800078821@qq.com
Country
China
ProdList
9725
Advantage
55
Thermo Fisher Scientific
Tel
800-810-5118
Fax
+86-10-84193589
Email
cnchemical@thermofisher.com
Country
China
ProdList
17779
Advantage
75
Beijing HuaMeiHuLiBiological Chemical
Tel
010-56205725
Fax
010-65763397
Email
waley188@sohu.com
Country
China
ProdList
12338
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View Lastest Price from ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) 12245-39-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) 12245-39-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-08

12245-39-5, ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)Related Search:


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