ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

Reactions

Product Name: ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
CAS No.: 12245-39-5
Chemical Name: ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
Synonyms: NSC 240030;rh(acac)(cod);Acetylacetonato(1,5-;(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)RH&;acetylacetonate-1,5-cyclooctadienerhodium;ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I);Acetylacetonato(cycloocta-1,5-diene)rhodium(I);(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium;(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu;(Acetylacetonato)(1,5-cyclooctadiene)rhodium(Ⅰ)
CBNumber: CB4469944
Molecular Formula: C13H19O2Rh
Formula Weight: 310.19
MOL File: 12245-39-5.mol

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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Property

Melting point:: 138-140 °C(lit.)
storage temp.: Inert atmosphere,2-8°C
form: Crystals
color: Yellow to orange
Sensitive: Air Sensitive
Hydrolytic Sensitivity: 8: reacts rapidly with moisture, water, protic solvents
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey: WDIAJTWVVLHUJU-SUESZSCISA-N

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-37/39
WGK Germany: 3
RTECS: VI9292000
TSCA: No
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 683108
Product name: (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Purity: 99%
Packaging: 2g
Price: $977
Updated: 2024/03/01

Sigma-Aldrich

Product number: 335029
Product name: (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Purity: 99%
Packaging: 100mg
Price: $125
Updated: 2023/06/20

Sigma-Aldrich

Product number: 8.24420
Product name: Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
Purity: for synthesis
Packaging: 500mg
Price: $91.2
Updated: 2023/01/07

Sigma-Aldrich

Product number: 8.24420
Product name: Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
Purity: for synthesis
Packaging: 100mg
Price: $139
Updated: 2023/01/07

Alfa Aesar

Product number: H26083
Product name: (1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate
Packaging: 250mg
Price: $198
Updated: 2023/06/20

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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Chemical Properties,Usage,Production

Reactions

Precursor for asymmetric hydrogenation reactions.
Rh-catalyzed carbozincation of ynamides.

Chemical Properties

Orange crystal

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

General Description

Atomic number of base material: 45 Rhodium

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd

Product: ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) 12245-39-5
Price: US $15.00-10.00/KG
Min. Order: 1KG
Purity: 99%+ HPLC
Supply Ability: Monthly supply of 1 ton
Release date: 2021-06-27

Career Henan Chemical Co

Product: ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) 12245-39-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 100KG
Release date: 2020-01-08

12245-39-5, ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)Related Search:

1,5-CYCLOOCTADIENE Acetylacetone Acetylacetonatobis(ethylene)rhodium(I) 1,5-Cyclooctadiene ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

(1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate

(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium(I)

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12245-39-5

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Catalysis and Inorganic Chemistry

organometallic complex