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ChemicalBook > CAS DataBase List > ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)

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Product Name
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
CAS No.
12245-39-5
Chemical Name
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)
Synonyms
NSC 240030;rh(acac)(cod);Acetylacetonato(1,5-;(ACETYLACETONATO)(1,5-CYCLOOCTADIENE)RH&;acetylacetonate-1,5-cyclooctadienerhodium;ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I);Acetylacetonato(cycloocta-1,5-diene)rhodium(I);(1,5-cyclooctadiene)(2,4-pentanedionato)rhodium;(1,5-cyclooctadiene)(2,4-pentanedionato)-rhodiu;(Acetylacetonato)(1,5-cyclooctadiene)rhodium(Ⅰ)
CBNumber
CB4469944
Molecular Formula
C13H19O2Rh
Formula Weight
310.19
MOL File
12245-39-5.mol
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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Property

Melting point:
138-140 °C(lit.)
storage temp. 
Inert atmosphere,2-8°C
form 
Crystals
color 
Yellow to orange
Sensitive 
Air Sensitive
Hydrolytic Sensitivity
8: reacts rapidly with moisture, water, protic solvents
Exposure limits
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
InChIKey
WDIAJTWVVLHUJU-SUESZSCISA-N
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-37/39
WGK Germany 
3
RTECS 
VI9292000
TSCA 
No
HS Code 
28439000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
683108
Product name
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Purity
99%
Packaging
2g
Price
$977
Updated
2024/03/01
Sigma-Aldrich
Product number
335029
Product name
(Acetylacetonato)(1,5-cyclooctadiene)rhodium(I)
Purity
99%
Packaging
100mg
Price
$125
Updated
2023/06/20
Sigma-Aldrich
Product number
8.24420
Product name
Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
Purity
for synthesis
Packaging
500mg
Price
$91.2
Updated
2023/01/07
Sigma-Aldrich
Product number
8.24420
Product name
Acetylacetonato(1,5-cyclooctadiene)rhodium(I)
Purity
for synthesis
Packaging
100mg
Price
$139
Updated
2023/01/07
Alfa Aesar
Product number
H26083
Product name
(1,5-Cyclooctadiene)rhodium(I) 2,4-pentanedionate
Packaging
250mg
Price
$198
Updated
2023/06/20
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ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Chemical Properties,Usage,Production

Reactions

  1. Precursor for asymmetric hydrogenation reactions.
  2. Rh-catalyzed carbozincation of ynamides. 

Chemical Properties

Orange crystal

Uses

Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis

General Description

Atomic number of base material: 45 Rhodium

Safety Profile

Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of Rh

ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) manufacturers

Zhuozhou Wenxi import and Export Co., Ltd
Product
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) 12245-39-5
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I) 12245-39-5
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100KG
Release date
2020-01-08

12245-39-5, ACETYLACETONATO(1,5-CYCLOOCTADIENE)RHODIUM(I)Related Search:


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