ChemicalBook > CAS DataBase List > 1-Chloro-N,N,2-trimethylpropenylamine
1-Chloro-N,N,2-trimethylpropenylamine
- Product Name
- 1-Chloro-N,N,2-trimethylpropenylamine
- CAS No.
- 26189-59-3
- Chemical Name
- 1-Chloro-N,N,2-trimethylpropenylamine
- Synonyms
- 1-Chloro-N,N,2-trimethylprop-1-en-1-amine;1-CHLORO-N,N,2-TRIMETHYL-1-PROPENYLAMINE;Ghosez′s reagent;TETRAMETHYL-ALPHA-CHLORENAMINE;1-CHLORO-N,N,2-TRIMETHYLPROPENYLAMINE;(1-CHLORO-2-METHYLPROPENYL)DIMETHYLAMINE;1-chloro-N,N,2-trimethyl-1-Propen-1-amine;1-chloride-N, N, 2-trimethyl-1-acrylamine;1-Chloro-N,N,2-trimethylpropenylamine ,98%;1-Propen-1-amine, 1-chloro-N,N,2-trimethyl-
- CBNumber
- CB4484804
- Molecular Formula
- C6H12ClN
- Formula Weight
- 133.62
- MOL File
- 26189-59-3.mol
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1-Chloro-N,N,2-trimethylpropenylamine Property
- Boiling point:
- 129-130 °C(lit.)
- Density
- 1.01 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.453(lit.)
- Flash point:
- 80 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Sparingly), Methanol (Slightly)
- form
- Liquid
- pka
- 4.27±0.70(Predicted)
- color
- Colorless to yellow
- Stability:
- Hygroscopic, Moisture Sensitive, Unstable in Solution
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Safety
- Hazard Codes
- C
- Risk Statements
- 10-34
- Safety Statements
- 16-26-36/37/39-45
- RIDADR
- UN 2734 8/PG 1
- WGK Germany
- 3
- HS Code
- 29211990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H226Flammable liquid and vapour
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 498270
- Product name
- 1-Chloro-N,N,2-trimethyl-1-propenylamine
- Purity
- 96%
- Packaging
- 5ml
- Price
- $183
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 498270
- Product name
- 1-Chloro-N,N,2-trimethyl-1-propenylamine
- Purity
- 96%
- Packaging
- 50ml
- Price
- $1270
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 498270
- Product name
- 1-Chloro-N,N,2-trimethyl-1-propenylamine
- Purity
- 96%
- Packaging
- 250ml
- Price
- $6300
- Updated
- 2024/03/01
TRC
- Product number
- C349260
- Product name
- 1-Chloro-N,N-2-trimethylpropenylamine
- Packaging
- 2.5g
- Price
- $155
- Updated
- 2021/12/16
TRC
- Product number
- C349260
- Product name
- 1-Chloro-N,N-2-trimethylpropenylamine
- Packaging
- 500mg
- Price
- $55
- Updated
- 2021/12/16
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1-Chloro-N,N,2-trimethylpropenylamine Chemical Properties,Usage,Production
Chemical Properties
Colorless to yellow liquid
Uses
1-Chloro-N,N,2-trimethyl-1-propenylamine is an acid halogenation reagent developed by Ghosez, that enables the conversion of carboxylic acids into the corresponding chlorides under strictly neutral conditions. This method was successfully used in the total synthesis of caloporoside, roseophilin, (-)-enniatin B, (±)-epimeloscine and (±)-meloscine.
Synthesis Reference(s)
Journal of the American Chemical Society, 94, p. 2869, 1972 DOI: 10.1021/ja00763a061
Organic Syntheses, Coll. Vol. 6, p. 282, 1988
Tetrahedron Letters, 25, p. 5043, 1984 DOI: 10.1016/S0040-4039(01)91114-1
1-Chloro-N,N,2-trimethylpropenylamine Preparation Products And Raw materials
Raw materials
N,N-Dimethylformamide
Phosphorus oxychloride
Triethylamine
Sodium bicarbonate
Dichloromethane
Dimethylamine
Isobutyryl chloride
Magnesium sulfate
PETROLEUM ETHER
Preparation Products
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1-Chloro-N,N,2-trimethylpropenylamine Suppliers
- Tel
- --
- Fax
- --
- info@acros.com
- Country
- Belgium
- ProdList
- 6772
- Advantage
- 81
- Tel
- --
- Fax
- --
- eburon@innet.be
- Country
- Belgium
- ProdList
- 490
- Advantage
- 66
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View Lastest Price from 1-Chloro-N,N,2-trimethylpropenylamine manufacturers
Henan Fengda Chemical Co., Ltd
- Product
- 1-Chloro-N,N,2-trimethylpropenylamine 26189-59-3
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 1-Chloro-N,N,2-trimethyl-1-propenylamine 26189-59-3
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-10
Zhuozhou Wenxi import and Export Co., Ltd
- Product
- 1-Chloro-N,N,2-trimethyl-1-propenylamine 26189-59-3
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-08
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