ChemicalBook > CAS DataBase List > BENZYL PHENYL CARBONATE 97

BENZYL PHENYL CARBONATE 97

Product Name
BENZYL PHENYL CARBONATE 97
CAS No.
28170-07-2
Chemical Name
BENZYL PHENYL CARBONATE 97
Synonyms
Phenyl benzyl carbonate;BENZYL PHENYL CARBONATE 97;Benzyl phenyl carbonate 97%;Benzyl Phenyl Carbonate >Benzyl phenyl carbonate≥ 98%(GC);Carbonic Acid Benzyl Phenyl Ester;Carbonic acid, phenyl phenylmethyl ester
CBNumber
CB4505260
Molecular Formula
C14H12O3
Formula Weight
228.24
MOL File
28170-07-2.mol
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BENZYL PHENYL CARBONATE 97 Property

Boiling point:
120-130 °C0.5 mm Hg(lit.)
Density 
1.156 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5490(lit.)
Flash point:
>230 °F
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
clear liquid
color 
Colorless to Almost colorless
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Safety

Hazard Codes 
Xi
Risk Statements 
41-43
Safety Statements 
26-36/37/39
WGK Germany 
3
HS Code 
29209090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H317May cause an allergic skin reaction

H318Causes serious eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
630640
Product name
Benzyl phenyl carbonate
Purity
97%
Packaging
5g
Price
$61.8
Updated
2022/05/15
TCI Chemical
Product number
B3574
Product name
Benzyl Phenyl Carbonate
Purity
>95.0%(GC)
Packaging
5g
Price
$52
Updated
2025/07/31
TCI Chemical
Product number
B3574
Product name
Benzyl Phenyl Carbonate
Purity
>95.0%(GC)
Packaging
25g
Price
$153
Updated
2025/07/31
TRC
Product number
B315765
Product name
Benzyl Phenyl Carbonate
Packaging
50mg
Price
$45
Updated
2021/12/16
Chem-Impex
Product number
31345
Product name
Benzylphenylcarbonate,≥97%(GC)
Purity
≥97%(GC)
Packaging
1G
Price
$14.56
Updated
2021/12/16
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BENZYL PHENYL CARBONATE 97 Chemical Properties,Usage,Production

Chemical Properties

Colorless to clear yellow liquid

Uses

Benzyl phenyl carbonate can be used to synthesize carbamate protected polyamines.

General Description

Benzyl phenyl carbonate can be synthesized by reacting phenyl chloroformate with benzyl alcohol in the presence of pyridine.

Synthesis

1885-14-9

28170-07-2

Synthesis of benzyl phenyl carbonate (Synthesis, 2002, 15, 2195-2202) Benzyl alcohol (10.8 g, 100.0 mmol) was dissolved in 100 mL of dichloromethane (CH2Cl2). After the solution was cooled to 0°C, phenyl chloroformate (15.7 g, 100 mmol) was added slowly and dropwise. The reaction mixture was stirred at room temperature overnight. Upon completion of the reaction, 100 mL of water (H2O) was added, followed by washing twice with 100 mL of 2 M sulfuric acid (H2SO4). The organic phase was separated and dried over anhydrous sodium sulfate (Na2SO4). The solvent was removed by distillation under reduced pressure to give the colorless liquid product benzyl phenyl carbonate (22.5 g, 99% yield). The product was characterized by 1H NMR (CDCl3, 300 MHz): δ= 7.45-7.31 (m, 6H, arylhydrogen), 7.25-7.14 (m, 4H, arylhydrogen), 5.25 (s, 2H, benzylhydrogen).

References

[1] Patent: US2013/203960, 2013, A1. Location in patent: Page/Page column
[2] Patent: US2009/36353, 2009, A1

BENZYL PHENYL CARBONATE 97 Preparation Products And Raw materials

Raw materials

Preparation Products

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BENZYL PHENYL CARBONATE 97 Suppliers

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View Lastest Price from BENZYL PHENYL CARBONATE 97 manufacturers

Shaanxi Dideu Medichem Co. Ltd
Product
Benzyl Phenyl Carbonate 28170-07-2
Price
US $1.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000KG
Release date
2020-01-10
Career Henan Chemical Co
Product
BENZYL PHENYL CARBONATE 97 28170-07-2
Price
US $1.00/KG
Min. Order
1KG
Purity
≥98%
Supply Ability
200kg
Release date
2019-08-30

28170-07-2, BENZYL PHENYL CARBONATE 97Related Search:

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