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Vinylene carbonate

Product Name
Vinylene carbonate
CAS No.
872-36-6
Chemical Name
Vinylene carbonate
Synonyms
1,3-DIOXOL-2-ONE;vinyl carbonate;Vinylene carbote;The ethylene carbonate;Vinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT;1,3-Dioxo-2-one;WITH HYDROQUINONE;Vinylene carbonat;VINYLENE CARBONATE;2H-1,3-dioxol-2-one
CBNumber
CB9119200
Molecular Formula
C3H2O3
Formula Weight
86.05
MOL File
872-36-6.mol
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Vinylene carbonate Property

Melting point:
19-22 °C(lit.)
Boiling point:
162 °C(lit.)
Density 
1.360 g/mL at 20 °C
vapor pressure 
3.35hPa at 25℃
refractive index 
n20/D 1.421(lit.)
Flash point:
163 °F
storage temp. 
2-8°C
solubility 
11.5 g/100 mL
form 
Liquid
Specific Gravity
1.355
color 
Colorless to pale yellow
Water Solubility 
11.5 g/100 mL
Sensitive 
Moisture Sensitive
BRN 
105683
InChIKey
VAYTZRYEBVHVLE-UHFFFAOYSA-N
LogP
-0.36 at 20℃
CAS DataBase Reference
872-36-6(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Dioxol-2-one(872-36-6)
EPA Substance Registry System
1,3-Dioxol-2-one (872-36-6)
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Safety

Hazard Codes 
Xi,N,T
Risk Statements 
43-36-51/53-48/22-41-38-24-22
Safety Statements 
37/39-26-24-61-45-36/37/39
RIDADR 
UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany 
3
RTECS 
FG3325000
TSCA 
Yes
HS Code 
29209090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
809977
Product name
Vinylene carbonate
Purity
99.5%, acid <200 ppm, H2O <100 ppm
Packaging
25g
Price
$476
Updated
2024/03/01
Sigma-Aldrich
Product number
757144
Product name
Vinylene carbonate
Purity
contains 80 ppm BHT as stabilizer, 99%
Packaging
25g
Price
$703
Updated
2023/01/07
TCI Chemical
Product number
V0015
Product name
Vinylene Carbonate (stabilized with BHT)
Purity
>98.0%(GC)
Packaging
5g
Price
$84
Updated
2024/03/01
TCI Chemical
Product number
V0015
Product name
Vinylene Carbonate (stabilized with BHT)
Purity
>98.0%(GC)
Packaging
25g
Price
$244
Updated
2024/03/01
Alfa Aesar
Product number
041400
Product name
Vinylene carbonate, 97+%
Purity
stab. with BHT
Packaging
0.5g
Price
$25.65
Updated
2024/03/01
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Vinylene carbonate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

Vinylene carbonate is used as an additive to electrolyte solutions for anode side Lithiumion batteries. It also acts as a sealant to seal at least a portion of the silicon-polyvinyl acid interface. It is further used for great improvement of high temperature performance of the battery.

Application

Vinylene carbonate (VC) can be used as an electrolytic additive for ionic liquid electrolyte for the formation of lithium-ion batteries. It can also be used in the formation of hybrid solid electrolyte interphase (SEI) for the fabrication of lithium-based batteries.

Preparation

Vinylene carbonate is produced by the known method by eliminating hydrogen chloride from chloroethylene glycol carbonate by means of tertiary amines, in particular triethylamine. Chloroethylene glycol carbonate is obtained by free radical chlorination of ethylene glycol carbonate by means of chlorine or sulphuryl chloride. This synthesis was published for the first time in 1953 by Newman and Addor (JACS, 1953, page 1263; JACS 1955, page 3789).

General Description

This product has been enhanced for energy efficiency. Carbonate building block offered as a solution in ethyl acetate for more convenient handling. Vinylene carbonate may also be used as a dienophile in Diels-Alder reactions.

Flammability and Explosibility

Non flammable

Purification Methods

Purify it by zone melting, or distillation, and stabilize it with 0.5% of 2,6-di-tert-butyl-p-cresol. [Beilstein 19 III/IV 1597, 19/4 V 72.]

Vinylene carbonate Preparation Products And Raw materials

Raw materials

Preparation Products

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Vinylene carbonate Suppliers

Wuhan Roche Technology Development Co., Ltd.,
Tel
18986168071
Fax
027-88121016
Email
18986168071@163.com
Country
China
ProdList
80
Advantage
55
Hunan Zengda Biological Technology Co., LTD
Tel
18711085600
Email
1652923704@qq.com
Country
China
ProdList
4582
Advantage
58
Hebei Dj Yan Chemical Co., Ltd.
Tel
17531190177
Fax
QQ:672648158
Email
peter@yan-xi.com
Country
China
ProdList
459
Advantage
58
Shijiazhuang Yangxin Chemical Technology Co., LTD
Tel
13731170049
Email
jianyuhuagong888@163.com
Country
China
ProdList
50
Advantage
58
LinkChem Co.,Ltd.
Tel
21-21-20222982 13124863828
Email
sales@linkchem.cn
Country
China
ProdList
2976
Advantage
58
Hubei Lidu New Material Technology Co., Ltd.
Tel
19307246857 19307246857
Email
15327516800@163.com
Country
China
ProdList
761
Advantage
58
Shijiazhuang Jianxin Biotechnology Co., LTD
Tel
0311-1906231-3169 19062313169
Email
19062313169@163.com
Country
China
ProdList
286
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
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View Lastest Price from Vinylene carbonate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Vinylene carbonate 872-36-6
Price
US $65.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/week
Release date
2024-06-06
Dorne Chemical Technology co. LTD
Product
Vinylene carbonate 872-36-6
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000kg
Release date
2024-03-26
Hubei Lidu New Material Technology Co., Ltd
Product
VINYLENE CARBONATE 872-36-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20tons
Release date
2024-09-19

872-36-6, Vinylene carbonateRelated Search:


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  • WITH HYDROQUINONE
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