Vinylene carbonate

Product Name: Vinylene carbonate
CAS No.: 872-36-6
Chemical Name: Vinylene carbonate
Synonyms: 1,3-DIOXOL-2-ONE;vinyl carbonate;Vinylene carbote;The ethylene carbonate;Vinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT;1,3-Dioxo-2-one;WITH HYDROQUINONE;Vinylene carbonat;VINYLENE CARBONATE;2H-1,3-dioxol-2-one
CBNumber: CB9119200
Molecular Formula: C3H2O3
Formula Weight: 86.05
MOL File: 872-36-6.mol

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Vinylene carbonate Property

Melting point:: 19-22 °C(lit.)
Boiling point:: 162 °C(lit.)
Density: 1.360 g/mL at 20 °C
vapor pressure: 3.35hPa at 25℃
refractive index: n20/D 1.421(lit.)
Flash point:: 163 °F
storage temp.: 2-8°C
solubility: 11.5 g/100 mL
form: Liquid
Specific Gravity: 1.355
color: Colorless to pale yellow
Water Solubility: 11.5 g/100 mL
Sensitive: Moisture Sensitive
BRN: 105683
InChIKey: VAYTZRYEBVHVLE-UHFFFAOYSA-N
LogP: -0.36 at 20℃
CAS DataBase Reference: 872-36-6(CAS DataBase Reference)
NIST Chemistry Reference: 1,3-Dioxol-2-one(872-36-6)
EPA Substance Registry System: 1,3-Dioxol-2-one (872-36-6)

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Safety

Hazard Codes: Xi,N,T
Risk Statements: 43-36-51/53-48/22-41-38-24-22
Safety Statements: 37/39-26-24-61-45-36/37/39
RIDADR: UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany: 3
RTECS: FG3325000
TSCA: Yes
HS Code: 29209090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 809977
Product name: Vinylene carbonate
Purity: 99.5%, acid <200 ppm, H2O <100 ppm
Packaging: 25g
Price: $476
Updated: 2024/03/01

Sigma-Aldrich

Product number: 757144
Product name: Vinylene carbonate
Purity: contains 80 ppm BHT as stabilizer, 99%
Packaging: 25g
Price: $703
Updated: 2023/01/07

TCI Chemical

Product number: V0015
Product name: Vinylene Carbonate (stabilized with BHT)
Purity: >98.0%(GC)
Packaging: 5g
Price: $84
Updated: 2024/03/01

TCI Chemical

Product number: V0015
Product name: Vinylene Carbonate (stabilized with BHT)
Purity: >98.0%(GC)
Packaging: 25g
Price: $244
Updated: 2024/03/01

Alfa Aesar

Product number: 041400
Product name: Vinylene carbonate, 97+%
Purity: stab. with BHT
Packaging: 0.5g
Price: $25.65
Updated: 2024/03/01

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Vinylene carbonate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

Vinylene carbonate is used as an additive to electrolyte solutions for anode side Lithiumion batteries. It also acts as a sealant to seal at least a portion of the silicon-polyvinyl acid interface. It is further used for great improvement of high temperature performance of the battery.

Application

Vinylene carbonate (VC) can be used as an electrolytic additive for ionic liquid electrolyte for the formation of lithium-ion batteries. It can also be used in the formation of hybrid solid electrolyte interphase (SEI) for the fabrication of lithium-based batteries.

Preparation

Vinylene carbonate is produced by the known method by eliminating hydrogen chloride from chloroethylene glycol carbonate by means of tertiary amines, in particular triethylamine. Chloroethylene glycol carbonate is obtained by free radical chlorination of ethylene glycol carbonate by means of chlorine or sulphuryl chloride. This synthesis was published for the first time in 1953 by Newman and Addor (JACS, 1953, page 1263; JACS 1955, page 3789).

General Description

This product has been enhanced for energy efficiency. Carbonate building block offered as a solution in ethyl acetate for more convenient handling. Vinylene carbonate may also be used as a dienophile in Diels-Alder reactions.

Flammability and Explosibility

Non flammable

Purification Methods

Purify it by zone melting, or distillation, and stabilize it with 0.5% of 2,6-di-tert-butyl-p-cresol. [Beilstein 19 III/IV 1597, 19/4 V 72.]

Vinylene carbonate Preparation Products And Raw materials

Raw materials

Preparation Products

Diphenyl carbonate

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Vinylene carbonate Suppliers

Belgium 1 China 384 Europe 3 France 1 Germany 4 India 3 Japan 1 Switzerland 1 Ukraine 2 United Kingdom 10 United States 36 Global 446

Wuhan Roche Technology Development Co., Ltd.,

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Hebei Dj Yan Chemical Co., Ltd.

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J & K SCIENTIFIC LTD.

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3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
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Email: 3bsc@sina.com
Country: China
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Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
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TCI (Shanghai) Development Co., Ltd.

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BeiJing Hwrk Chemicals Limted

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View Lastest Price from Vinylene carbonate manufacturers

Dorne Chemical Technology co. LTD

Product: Vinylene carbonate 872-36-6
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-03-26

hebei hongtan Biotechnology Co., Ltd

Product: Vinylene carbonate 872-36-6
Price: US $30.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 2000kg
Release date: 2024-03-22

Shandong Hanjiang Chemical Co., Ltd

Product: Vinylene carbonate 872-36-6
Price: US $0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10T
Release date: 2024-01-25

872-36-6, Vinylene carbonateRelated Search:

Vinyl acetate Chloroethylene carbonate Calcium carbonate Polycarbonate Dimethyl carbonate Lithium carbonate Sodium carbonate Zinc carbonate Barium carbonate Propylene carbonate Ammonium carbonate Fluoroethylene carbonate Ethylene carbonate 4-Vinyl-1,3-dioxolan-2-one ALLYL PHENYL CARBONATE 97 VINYLTRIISOPROPENOXYSILANE Vinyltriacetoxysilane PHENYL FORMATE

Vinylene carbonate, 97+%, stab. with BHT

Vinylene carbonate contains <=2% BHT as stabilizer, 97%

The ethylene carbonate

Vinylene carbonate contains 80 ppm BHT as stabilizer, 99%

WITH HYDROQUINONE

Vinylene carbonate 99.5%, acid <200 ppm, H2O <100 ppm

Vinylene carbonate, 97%, stabilized

Vinylene carbote

Vinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT

Vinylene carbonate solution

VINYLENE CARBONATE

Carbonic acid, cyclic vinylene ester

carbonicacid,cyclicvinyleneester

Vinylene carbonate (stabilized with HQ)

Vinylenecarbonate,97%

VINYLENE CARBONATE, STAB.

1,3-DIOXOL-2-ONE

1,3-Dioxo-2-one

Vinylene carbonate, stabilized, 98%

1,3-DIOXAL-2-ONE (VINYLENE CARBONATE)

VINYLENE CARBONATE (VC)

Vinylenecarbonate,97+%,stab.withhydroquinone

Vinylene carbonate, 98%, stabilized

Vinylene Carbonate (stabilized with BHT)

Vinylene carbonate,1,3-Dioxol-2-one

Vinylene carbonate, stabilized, 98% 5GR

Vinylene carbonat

Vinylene carbonate, 99%, for synthesis

Vinylene Carbonate,98%

vinyl carbonate

Vinylene carbonate(872-36-6)

2H-1,3-dioxol-2-one

1-methyl-2,3-dihydro-1H-phosphole 1-oxide

Vinylene carbonate contains

872-36-6

212-825-5

C3H2O3

Organic Building Blocks

Building Blocks

Carbonates

Carbonyl Compounds

Fine Chemical

fine chemicals

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