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Vinylene carbonate

Product Name
Vinylene carbonate
CAS No.
872-36-6
Chemical Name
Vinylene carbonate
Synonyms
1,3-DIOXOL-2-ONE;vinyl carbonate;Vinylene carbote;The ethylene carbonate;Vinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT;1,3-Dioxo-2-one;WITH HYDROQUINONE;Vinylene carbonat;VINYLENE CARBONATE;2H-1,3-dioxol-2-one
CBNumber
CB9119200
Molecular Formula
C3H2O3
Formula Weight
86.05
MOL File
872-36-6.mol
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Vinylene carbonate Property

Melting point:
19-22 °C(lit.)
Boiling point:
162 °C(lit.)
Density 
1.360 g/mL at 20 °C
vapor pressure 
3.35hPa at 25℃
refractive index 
n20/D 1.421(lit.)
Flash point:
163 °F
storage temp. 
2-8°C
solubility 
11.5 g/100 mL
form 
Liquid
Specific Gravity
1.355
color 
Colorless to pale yellow
Water Solubility 
11.5 g/100 mL
Sensitive 
Moisture Sensitive
BRN 
105683
InChIKey
VAYTZRYEBVHVLE-UHFFFAOYSA-N
LogP
-0.36 at 20℃
CAS DataBase Reference
872-36-6(CAS DataBase Reference)
NIST Chemistry Reference
1,3-Dioxol-2-one(872-36-6)
EPA Substance Registry System
1,3-Dioxol-2-one (872-36-6)
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Safety

Hazard Codes 
Xi,N,T
Risk Statements 
43-36-51/53-48/22-41-38-24-22
Safety Statements 
37/39-26-24-61-45-36/37/39
RIDADR 
UN2810 - class 6.1 - PG 3 - EHS - Toxic, liquids, organic, n.o.s., HI: all
WGK Germany 
3
RTECS 
FG3325000
TSCA 
Yes
HS Code 
29209090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H311Toxic in contact with skin

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
809977
Product name
Vinylene carbonate
Purity
99.5%, acid <200 ppm, H2O <100 ppm
Packaging
25g
Price
$476
Updated
2024/03/01
Sigma-Aldrich
Product number
757144
Product name
Vinylene carbonate
Purity
contains 80 ppm BHT as stabilizer, 99%
Packaging
25g
Price
$703
Updated
2023/01/07
TCI Chemical
Product number
V0015
Product name
Vinylene Carbonate (stabilized with BHT)
Purity
>98.0%(GC)
Packaging
5g
Price
$84
Updated
2024/03/01
TCI Chemical
Product number
V0015
Product name
Vinylene Carbonate (stabilized with BHT)
Purity
>98.0%(GC)
Packaging
25g
Price
$244
Updated
2024/03/01
Alfa Aesar
Product number
041400
Product name
Vinylene carbonate, 97+%
Purity
stab. with BHT
Packaging
0.5g
Price
$25.65
Updated
2024/03/01
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Vinylene carbonate Chemical Properties,Usage,Production

Chemical Properties

clear colorless to light yellow liquid

Uses

Vinylene carbonate is used as an additive to electrolyte solutions for anode side Lithiumion batteries. It also acts as a sealant to seal at least a portion of the silicon-polyvinyl acid interface. It is further used for great improvement of high temperature performance of the battery.

Application

Vinylene carbonate (VC) can be used as an electrolytic additive for ionic liquid electrolyte for the formation of lithium-ion batteries. It can also be used in the formation of hybrid solid electrolyte interphase (SEI) for the fabrication of lithium-based batteries.

Preparation

Vinylene carbonate is produced by the known method by eliminating hydrogen chloride from chloroethylene glycol carbonate by means of tertiary amines, in particular triethylamine. Chloroethylene glycol carbonate is obtained by free radical chlorination of ethylene glycol carbonate by means of chlorine or sulphuryl chloride. This synthesis was published for the first time in 1953 by Newman and Addor (JACS, 1953, page 1263; JACS 1955, page 3789).

General Description

This product has been enhanced for energy efficiency. Carbonate building block offered as a solution in ethyl acetate for more convenient handling. Vinylene carbonate may also be used as a dienophile in Diels-Alder reactions.

Flammability and Explosibility

Non flammable

Purification Methods

Purify it by zone melting, or distillation, and stabilize it with 0.5% of 2,6-di-tert-butyl-p-cresol. [Beilstein 19 III/IV 1597, 19/4 V 72.]

Vinylene carbonate Preparation Products And Raw materials

Raw materials

Preparation Products

Diphenyl carbonate
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View Lastest Price from Vinylene carbonate manufacturers

Dorne Chemical Technology co. LTD
Product
Vinylene carbonate 872-36-6
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10000kg
Release date
2024-03-26
Hubei Lidu New Material Technology Co., Ltd
Product
VINYLENE CARBONATE 872-36-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20tons
Release date
2024-09-19
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Vinylene carbonate 872-36-6
Price
US $65.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000kg/week
Release date
2024-06-06

872-36-6, Vinylene carbonateRelated Search:

Vinyl acetate Chloroethylene carbonate Calcium carbonate Polycarbonate Dimethyl carbonate Lithium carbonate Sodium carbonate Zinc carbonate Barium carbonate Propylene carbonate Ammonium carbonate Fluoroethylene carbonate Ethylene carbonate 4-Vinyl-1,3-dioxolan-2-one ALLYL PHENYL CARBONATE 97 VINYLTRIISOPROPENOXYSILANE Vinyltriacetoxysilane PHENYL FORMATE

  • Vinylene carbonate, 97+%, stab. with BHT
  • Vinylene carbonate contains <=2% BHT as stabilizer, 97%
  • The ethylene carbonate
  • Vinylene carbonate contains 80 ppm BHT as stabilizer, 99%
  • WITH HYDROQUINONE
  • Vinylene carbonate 99.5%, acid <200 ppm, H2O <100 ppm
  • Vinylene carbonate, 97%, stabilized
  • Vinylene carbote
  • Vinylene carbonate, 99%, water ≤50 ppm, stabilized with 90 ppm BHT
  • Vinylene carbonate solution
  • VINYLENE CARBONATE
  • Carbonic acid, cyclic vinylene ester
  • carbonicacid,cyclicvinyleneester
  • Vinylene carbonate (stabilized with HQ)
  • Vinylenecarbonate,97%
  • VINYLENE CARBONATE, STAB.
  • 1,3-DIOXOL-2-ONE
  • 1,3-Dioxo-2-one
  • Vinylene carbonate, stabilized, 98%
  • 1,3-DIOXAL-2-ONE (VINYLENE CARBONATE)
  • VINYLENE CARBONATE (VC)
  • Vinylenecarbonate,97+%,stab.withhydroquinone
  • Vinylene carbonate, 98%, stabilized
  • Vinylene Carbonate (stabilized with BHT)
  • Vinylene carbonate,1,3-Dioxol-2-one
  • Vinylene carbonate, stabilized, 98% 5GR
  • Vinylene carbonat
  • Vinylene carbonate, 99%, for synthesis
  • Vinylene Carbonate,98%
  • vinyl carbonate
  • Vinylene carbonate(872-36-6)
  • 2H-1,3-dioxol-2-one
  • 1-methyl-2,3-dihydro-1H-phosphole 1-oxide
  • Vinylene carbonate contains
  • 872-36-6
  • 212-825-5
  • C3H2O3
  • Organic Building Blocks
  • Building Blocks
  • Carbonates
  • Carbonyl Compounds
  • Fine Chemical
  • fine chemicals
  • Other