5-Norbornene-2-methanol

Product Name: 5-Norbornene-2-methanol
CAS No.: 95-12-5
Chemical Name: 5-Norbornene-2-methanol
Synonyms: Bicyclo[2.2.1]hept-5-en-2-ylmethanol;Cyclol;5-Norbornen-2-methanol;2-HYDROXYMETHYL-1-BICYCLO(2.2.1)HEPT-5-ENE;TIMTEC-BB SBB008580;5-Norbronene-2-methanol;5-NORBORNENE-2-METHANOL;Norborn-5-ene-2-methanol;5-Hyboradiene-2-methanol;5-Norbornene-2-yl methanol
CBNumber: CB4666688
Molecular Formula: C8H12O
Formula Weight: 124.18
MOL File: 95-12-5.mol

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5-Norbornene-2-methanol Property

Boiling point:: 97 °C/20 mmHg (lit.)
Density: 1.027 g/mL at 25 °C (lit.)
refractive index: n20/D 1.500(lit.)
Flash point:: 188 °F
storage temp.: Keep in dark place,Sealed in dry,Room Temperature
form: clear liquid
pka: 14.92±0.10(Predicted)
color: Colorless to Almost colorless
optical activity: Consistent with structure
CAS DataBase Reference: 95-12-5(CAS DataBase Reference)
NIST Chemistry Reference: 5-Norbornene-2-methanol(95-12-5)
EPA Substance Registry System: Bicyclo[2.2.1]hept-5-ene-2-methanol (95-12-5)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 36/37/39-45
WGK Germany: 3
HS Code: 2906190090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 248533
Product name: 5-Norbornene-2-methanol
Purity: 98%, mixture of endo and exo
Packaging: 5g
Price: $116.93
Updated: 2025/07/31

TCI Chemical

Product number: N0979
Product name: 5-Norbornen-2-methanol (mixture of isomers)
Purity: >98.0%(GC)
Packaging: 5g
Price: $57
Updated: 2025/07/31

TCI Chemical

Product number: N0979
Product name: 5-Norbornen-2-methanol (mixture of isomers)
Purity: >98.0%(GC)
Packaging: 25g
Price: $181
Updated: 2025/07/31

TRC

Product number: B789408
Product name: Bicyclo[2.2.1]hept-5-en-2-ylmethanol
Packaging: 100mg
Price: $60
Updated: 2021/12/16

TRC

Product number: B789408
Product name: Bicyclo[2.2.1]hept-5-en-2-ylmethanol
Packaging: 500mg
Price: $75
Updated: 2021/12/16

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5-Norbornene-2-methanol Chemical Properties,Usage,Production

Uses

Monomer for the modification of condensation and addition polymers for coatings.

Uses

5-Norbornene-2-methanol has been used in the preparation of:

4-(norborn-2-ene-5-ylmethyleneoxy)-2,2′:6′,2′′-terpyridine
5- {[(3,5-di-t-butyl-4-hydroxy-benzoyl)oxy]methyl}-2-norbornene (BHBN)

Definition

Stable, colorless liquid. Miscible with most common organic solvents; slightly soluble in hot water. Combustible.

General Description

Co-polymerization of 5-norbornene-2-methanol with ethylene using heterogeneous silica supported catalysts has been reported.

Synthesis

542-92-7

107-18-6

95-12-5

Cyclopentadiene was mixed with acryl alcohol in a pressure reactor at a molar ratio of 1:2.4 and the reaction was carried out at 170-180 °C and a pressure of 4-5 atm to give 5-norbornene-2-methanol. The product had a yield of 74%, a boiling point of 82-83 °C (10 mmHg), a refractive index nD20 of 1.4970, and a density d420 of 1.027 g/cm3. IR spectra showed characteristic absorption peaks: 3500 cm?1 (OH stretching vibration), 2930-2895 cm?1 and 2880-2830 cm?1 (C-H stretching vibration), 1200 -1100 cm?1 (C-O stretching vibration).1H NMR spectral data (δ, ppm; J, Hz): 0.45 (1H, H6exo, dd, J = 4.1, 13.4), 1.19 (1H, H7anti, t, J = 7.9), 1.44 (1H, H6endo, t, J = 4.1), 1.68-1.72 (1H , H7syn, m), 2.86 (1H, H5, m), 3.29 (1H, H4, m), 3.36-3.46 (2H, C8H2, m), 3.46 (1H, H1, ddd, J = 4.4, 4.6, 4.8), 3.92 (1H, OH, br s), 6.00-6.08 (2H, H2, H3, m).13C NMR spectral data (δC, ppm): 28.8 (C6), 41.8 (C5), 42.3 (C1), 43.6 (C4), 49.4 (C7), 65.8 (C8), 132.3 (C3), 137.8 (C2).

References

[1] Petroleum Chemistry, 2000, vol. 40, # 4, p. 272 - 274
[2] Russian Journal of General Chemistry, 2018, vol. 88, # 10, p. 2204 - 2208
[3] Zh. Obshch. Khim., 2018, vol. 88, # 10, p. 1718 - 1722,5
[4] Russian Journal of Organic Chemistry, 2003, vol. 39, # 7, p. 947 - 951
[5] Russian Journal of Applied Chemistry, 2008, vol. 81, # 10, p. 1803 - 1807

5-Norbornene-2-methanol Preparation Products And Raw materials

Raw materials

Preparation Products

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5-Norbornene-2-methanol Suppliers

Americas 1 China 146 Europe 3 Germany 3 India 3 Japan 1 Poland 1 Switzerland 1 United Kingdom 3 United States 24 Global 186

TCI (Shanghai) Development Co., Ltd.

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Energy Chemical

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Aemon Chemical

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View Lastest Price from 5-Norbornene-2-methanol manufacturers

Shaanxi Dideu Medichem Co. Ltd

Product: 5-Norbornene-2-methanol 95-12-5
Price: US $0.00-0.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 1000KG
Release date: 2024-08-14

Henan Fengda Chemical Co., Ltd

Product: 5-Norbornene-2-methanol 95-12-5
Price: US $200.00-1.00/KG
Min. Order: 1KG
Purity: 99%, 99.5% Sublimated
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-31

Shaanxi Dideu Medichem Co. Ltd

Product: 5-Norbornen-2-methanol 95-12-5
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20T
Release date: 2020-01-06

95-12-5, 5-Norbornene-2-methanolRelated Search:

Norbornene Methanol 5-ETHYLIDENE-2-NORBORNENE 2,5-Norbornadiene 5-Norbornene-2,3-dicarboxylic acid 5-NORBONENE-2-METHANAMINE DiMethyl bicyclo[2.2.1]heptane-1,4-carboxylate Bicyclo[2.2.1]heptane-2,5-dione Bicyclo[2.2.2]octane-1,4-dimethanol bicyclo[1.1.1]pentan-1-ylmethanol 2-NORBORNEN-2-YLBORONIC ACID DiMethyl bicyclo[1.1.1]pentane-1,3-dicarboxylate Bicyclo[1.1.1]pentane-1-carboxylic acid BICYCLO[3.3.1]NONANE-2,6-DIONE tert-Butyl 5-norbornene-2-carboxylate bicyclo[2.2.2]octane-1-carboxylic acid bicyclo[1.1.1]pentan-1-ylmethanamine hydrochloride 2-(Aminomethyl)norbornane

TIMTEC-BB SBB008580

2-(Hydroxymethyl)bicyclo(2.2.1)hept-5-ene

2-Hydroxymethyl-1-bicyclo[2.2.1]-5-ene

5-Hydroxymethyl-2-norbornene

Bicyclo[2.2.1]hept-5-en-2-ylmethanol - Mixture of endo and exo

5-Hydroxymethylnorborn-2-ene

Bicyclo[2.2.1]hepta-2-ene-5-methanol

Bicyclo[2.2.1]hepta-5-ene-2-methanol

Norborn-5-ene-2-methanol

5-norbornene-2-methanol, mixture of endo and

5-Norbronene-2-methanol

5-NORBORNENE-2-METHANOL(NMO)MIXTURE OF ENDO AND EXO

5-NORBORNENE-2-METHANOL (MIXTURE OF ENDO AND EXO)

5-Norbornene-2-methanol (exo/endo)

5-Norbornen-2-methanol

5-bicyclo[2.2.1]hept-2-enylmethanol

2-Hydroxymethyl-1-bicyclo[2.2

Bicyclo[2.2.1]hept-5-ene-2-carboxylate-2-methanol

5-Norbornen-2-methanol (mixture of isomers)

BICYCLO(2,2,1)HEPT-5-ENE-2-METHANOL

BICYCLO[2.2.1]5-HEPTENE-2-METHANOL

5-NORBORNENE-2-METHANOL

2-HYDROXYMETHYL-5-NORBORNENE

2-HYDROXYMETHYL-1-BICYCLO(2.2.1)HEPT-5-ENE

5-Hydroxymethylbicyclo(2.2.1)hept-2-ene

Bicyclo[2.2.1]hept-5-en-2-ylmethanol

Cyclol

5-NORBORNENE-2-METHANOL, 98%, MIXTURE OF ENDO AND EXO

5-Norbornene-2-yl methanol

5-Norbornene-2-methanol 98%

5-Norbornen-2-methanol (mixture of isomers) &gt

5-Norbornene-2-methanol ISO 9001：2015 REACH

5-Hyboradiene-2-methanol

2-bicyclo[2.2.1]hept-5-enylmethanol

5-norbornene-2-methanol 2-(Hydroxymethyl)bicyclo[2.2.1]hept-5-ene

95-12-5

1995/12/5

92-12-5

95-12-8

35-03-8

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Cyclic

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Cyclic

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Norbornene Derivatives