trans-2-Benzylamino-1-cyclohexanol
- Product Name
- trans-2-Benzylamino-1-cyclohexanol
- CAS No.
- 40571-86-6
- Chemical Name
- trans-2-Benzylamino-1-cyclohexanol
- Synonyms
- amino)cycL;trans-2-(BenzyL;TRANS-2-(BENZYLAMINO)CYCLOHEXANOL;TRANS-2-BENZYLAMINO-1-CYCLOHEXANOL;Trans-2-(N-Benzylamino)cyclohexanol;(1R,2R)-2-(benzylamino)cyclohexanol;(1R,2R)-2-(benzylaMino)cyclopentanol;trans-2-(Benzylamino)cyclohexan-1-ol;Trans-2-benzylamino-1-cyclohexanol, 99+%;(2-hydroxycyclohexyl)-(phenylmethyl)ammonium
- CBNumber
- CB4668460
- Molecular Formula
- C13H19NO
- Formula Weight
- 205.3
- MOL File
- 40571-86-6.mol
trans-2-Benzylamino-1-cyclohexanol Property
- Melting point:
- 69-72 °C
- Boiling point:
- 69-72°C
- Density
- 0.9923 (rough estimate)
- refractive index
- 1.5175 (estimate)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- form
- crystal
- pka
- 14.83±0.40(Predicted)
- color
- white
Safety
- Risk Statements
- 11-36/37/38
- Safety Statements
- 24/25
- TSCA
- No
- HS Code
- 2921490090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- B233868
- Product name
- trans-2-(Benzylamino)cyclohexanol
- Packaging
- 500mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- 300099
- Product name
- (1R,2R)-2-(Benzylamino)cyclohexanol, 98%
- Packaging
- 1g
- Price
- $22
- Updated
- 2021/12/16
- Product number
- FB153893
- Product name
- trans-2-Benzylamino-1-cyclohexanol
- Packaging
- 500mg
- Price
- $80
- Updated
- 2021/12/16
- Product number
- Y3342
- Product name
- trans-2-Benzylamino-1-cyclohexanol;trans-2-Benzylamino-1-cyclohexanol
- Packaging
- 1g
- Price
- $82
- Updated
- 2021/12/16
- Product number
- FB153893
- Product name
- trans-2-Benzylamino-1-cyclohexanol
- Packaging
- 1g
- Price
- $136
- Updated
- 2021/12/16
trans-2-Benzylamino-1-cyclohexanol Chemical Properties,Usage,Production
Chemical Properties
VERY SLIGHTLY YELLOW TO BEIGE CRYSTALLINE POWDER
Uses
suzuki reaction
Synthesis
286-20-4
100-46-9
40571-86-6
General procedure for the synthesis of trans-2-benzylaminocyclohexanol from cyclohexene oxide and benzylamine: cyclohexene oxide (20 g, 204 mmol) was mixed with benzylamine (44 g, 411 mmol), and the reaction was carried out for 6 hours at 80 °C. After completion of the reaction, the excess benzylamine was removed by distillation under reduced pressure. The crude product was purified by silica gel column chromatography with the eluent being a chloroform solution of 5-10% methanol to give (1RS,2RS)-trans-2-benzylaminocyclohexanol (26 g, 127 mmol, 62% yield) as white crystals.
References
[1] Tetrahedron Letters, 2008, vol. 49, # 9, p. 1546 - 1550
[2] Tetrahedron, 2011, vol. 67, # 47, p. 9214 - 9218
[3] Journal of Organic Chemistry, 2007, vol. 72, # 10, p. 3713 - 3722
[4] Tetrahedron Letters, 1990, vol. 31, # 32, p. 4661 - 4664
[5] Synthetic Communications, 2001, vol. 31, # 21, p. 3295 - 3302
trans-2-Benzylamino-1-cyclohexanol Preparation Products And Raw materials
Raw materials
Preparation Products
trans-2-Benzylamino-1-cyclohexanol Suppliers
- Tel
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- Fax
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- info@abcr.de
- Country
- Germany
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- 6831
- Advantage
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- Tel
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- sales@chemos-group.com
- Country
- Germany
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View Lastest Price from trans-2-Benzylamino-1-cyclohexanol manufacturers
- Product
- trans-2-Benzylamino-1-cyclohexanol 40571-86-6
- Price
- US $2.00/KG
- Min. Order
- 1g
- Purity
- 98%min
- Supply Ability
- ask
- Release date
- 2020-01-08