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Benzenesulfonic acid

Product Name
Benzenesulfonic acid
CAS No.
98-11-3
Chemical Name
Benzenesulfonic acid
Synonyms
BL70;17-120a;1998/11/3;besylicacid;Besylic acid;Benzolsulfonsure;BENZOLSULFONSAEURE;benzenesulfonicaci;Benzensulfonic acid;BENZENESULFONIC ACID
CBNumber
CB4668758
Molecular Formula
C6H6O3S
Formula Weight
158.18
MOL File
98-11-3.mol
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Benzenesulfonic acid Property

Melting point:
30-60 °C
Boiling point:
137℃
Density 
1.32
refractive index 
1.5151 (estimate)
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
H2O: soluble0.1g/10 mL, clear, colorless
pka
0.7(at 25℃)
form 
Damp Crystalline Solid or Fused Mass
color 
Yellow to light brown
PH
2 (H2O, 20℃)(saturated solution)
Water Solubility 
soluble
Sensitive 
Hygroscopic
Merck 
14,1070
BRN 
742513
Stability:
Stable. Incompatible with strong oxidizing agents, bases, many organic compounds.
InChIKey
SRSXLGNVWSONIS-UHFFFAOYSA-N
CAS DataBase Reference
98-11-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzenesulfonic acid(98-11-3)
EPA Substance Registry System
Benzenesulfonic acid (98-11-3)
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Safety

Hazard Codes 
C
Risk Statements 
22-34
Safety Statements 
26-36/37/39-45-36
RIDADR 
UN 2583 8/PG 2
WGK Germany 
1
RTECS 
DB4200000
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29041000
Hazardous Substances Data
98-11-3(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 1175 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H290May be corrosive to metals

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P234Keep only in original container.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

P390Absorb spillage to prevent material damage.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.00468
Product name
Benzenesulfonic acid
Purity
for synthesis
Packaging
5 g
Price
$21.27
Updated
2021/03/22
Sigma-Aldrich
Product number
8.00468
Product name
Benzenesulfonic acid
Purity
for synthesis
Packaging
250 g
Price
$76.96
Updated
2021/03/22
Sigma-Aldrich
Product number
12635
Product name
Benzenesulfonic acid
Purity
98.0% (T)
Packaging
25g-f
Price
$77.5
Updated
2020/08/18
Sigma-Aldrich
Product number
12635
Product name
Benzenesulfonic acid
Purity
98.0% (T)
Packaging
100g-f
Price
$222
Updated
2020/08/18
Sigma-Aldrich
Product number
8.00468
Product name
Benzenesulfonic acid
Purity
for synthesis
Packaging
1 kg
Price
$239.57
Updated
2021/03/22
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Benzenesulfonic acid Chemical Properties,Usage,Production

Description

Benzene sulfonic acid is an organo sulfur compound with the formula C6H5SO3H. It is the simplest aromatic sulfonic acid. It forms colorless deliquescent sheet crystals or a white waxy solid that is soluble in water and ethanol, slightly soluble in benzene and insoluble in carbon disulfide and diethyl ether. It is often stored in the form of alkali metal salts. Its aqueous solution is strongly acidic.

Chemical Properties

green solid

Definition

ChEBI: The simplest member of the class of a benzenesulfonic acids that consists of a benzene carrying a single sulfo group.

Definition

A white crystalline acid made by sulfonation of benzene. Any further substitution onto the benzene ring is directed into the 3 position.

Definition

benzenesulphonic acid: A colourlessdeliquescent solid, C6H5SO2OH,m.p. 43–44°C, usually found as anoily liquid. It is made by treating benzenewith concentrated sulphuricacid. Its alkyl derivatives are used asdetergents.

Application

The alkali metal salt of benzene sulfonic acid was once widely used in the production of phenol :
C6H5SO3Na + 2 NaOH → C6H5ONa + Na2SO3
C6H5ONa + HCl → C6H5OH + NaCl
The process has been largely displaced by the Hock process, which generates less waste. Benzene sulfonic acid is mainly consumed by conversion to other specialty chemicals. A variety of pharmaceutical drugs are prepared as salts of benzene sulfonic acid and are known as besylates or besilates.

Preparation

Benzene sulfonic acid is prepared from the sulfonation of benzene using concentrated sulfuric acid :
This conversion illustrates aromatic sulfonation, which has been called "one of the most important reactions in industrial organic chemistry.".

Reactions

Benzene sulfonic acid exhibits the reactions typical of other aromatic sulfonic acids, forming sulfonamides , sulfonyl chloride, and esters. The sulfonation is reversed above 220 °C. Dehydration with phosphorus pentoxide gives benzene sulfonic acid anhydride ((C6H5SO2)2O). Conversion to the corresponding benzene sulfonyl chloride (C6H5SO2Cl) is effected with phosphorus penta chloride. It is a strong acid, being dissociated in water.

Synthesis Reference(s)

The Journal of Organic Chemistry, 61, p. 1530, 1996 DOI: 10.1021/jo9520710
Tetrahedron Letters, 19, p. 1211, 1978 DOI: 10.1016/S0040-4039(01)94501-0

General Description

Deliquescent needles or large plates.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

Benzenesulfonic acid reacts with bases and many organic compounds.

Fire Hazard

Flash point data for Benzenesulfonic acid are not available, however Benzenesulfonic acid is probably combustible.

Safety Profile

Poison by ingestion, sbn contact, and probably inhalation. A severe skin and eye irritant. See also SULFATES and SULFONATES.

Purification Methods

Purify benzenesulfonic acid by dissolving it in a small volume of distilled H2O and stirring with slightly less than the theoretical amount of BaCO3. When effervescence is complete and the solution is still acidic, filter off the insoluble barium benzenesulfonate. The salt is collected and dried to constant weight in vacuo, then suspended in H2O and stirred with a little less than the equivalent (half mol.) of sulfuric acid. The insoluble BaSO4 (containing a little barium benzenesulfonate) is filtered off and the filtrate containing the free acid is evaporated in a high vacuum. The oily residue will eventually crystallise when completely anhydrous. A 32% commercial acid is allowed to fractionally crystallise at room temperature over P2O5 in a vacuum desiccator giving finally colourless deliquescent plates m 52.5o. The anhydrous crystalline acid is deliquescent and should be stored over anhydrous Na2SO4 in the dark and should be used in subdued sunlight as it darkens under sunlight. The main impurity is Fe which readily separates as the Fe salt in the early fractions [Taylor & Vincent J Chem Soc 3218 1952]. The S-benzylisothiuronium salt has m 148o (from EtOH/H2O). It is an IRRITANT to the skin and eyes. [See Adams & Marvel Org Synth Coll Vol I 84 1941, Michael & Adair Chem Ber 10 585 1877, Beilstein 11 IV 27.]

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Benzenesulfonic acid Suppliers

Nanjing Datang Chemical Co., Ltd
Tel
+86-25-85431992
Fax
+86-25-85287178
Email
vip@chemdatang.com
Country
China
ProdList
72
Advantage
66
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24555
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820-
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1401
Advantage
62
卡托研究化学公司
Tel
020-81215950- ;020-81215950-
Email
customer@uwalab.com;customer@uwalab.com
Country
United States
ProdList
10423
Advantage
58
Shanghai kadel chemical technology co., LTD
Tel
021-4007787-550
Email
2850202386@qq.com
Country
China
ProdList
10709
Advantage
58
Henan Jiuke Chemical Co. LTD
Tel
0370-2071226-
Fax
0370-2071226
Email
954866649@qq.com
Country
China
ProdList
2917
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833- ;010-82848833-
Fax
86-10-82849933
Email
jkinfo@jkchemical.com;market6@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
21-61259100-
Fax
86-21-61259102
Email
sh@meryer.com
Country
China
ProdList
40264
Advantage
62
Alfa Aesar
Tel
400-610-6006; 021-67582000
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30159
Advantage
84
ShangHai DEMO Chemical Co.,Ltd
Tel
400-021-7337 qq:2355568890
Fax
0086-21-50182339
Email
sales@demochem.com; export1@demochem.com
Country
China
ProdList
2582
Advantage
57
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View Lastest Price from Benzenesulfonic acid manufacturers

Guangzhou Sunton Biotechnology Co., Ltd.
Product
Benzenesulfonic acid 98-11-3
Price
US $48.00-40.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
200tons
Release date
2021-03-26
Handan Tongyi New Material Technology Co., Ltd
Product
Benzenesulfonic Acid 98-11-3
Price
US $10.00/KG
Min. Order
1KG
Purity
99.99
Supply Ability
500kg/month
Release date
2021-03-10
Wuhan Mulei New Material Technology Co. Ltd
Product
Benzenesulfonic Acid 98-11-3
Price
US $20.00/Kg/Drum
Min. Order
25Kg/Drum
Purity
99.99%
Supply Ability
1 ton per week
Release date
2021-04-02

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