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Hydrogenated bisphenol A (HBPA)

Product Name
Hydrogenated bisphenol A (HBPA)
CAS No.
80-04-6
Chemical Name
Hydrogenated bisphenol A (HBPA)
Synonyms
HYDROGENATED BISPHENOL A;2,2-BIS(4-HYDROXYCYCLOHEXYL)PROPANE;H-BPA;Maruzen H-BPA;PERHYDROBISPHENOL A;BISPHENOL A HYDROGENATED;4'-Isopropylidenedicyclohexanol;HYDROGENATED BISPHENOL A (HBPA);4,4'-ISOPROPYLIDENEDICYCLOHEXANOL;4,4'-Isopropylidinedicyclohexanol
CBNumber
CB4669962
Molecular Formula
C15H28O2
Formula Weight
240.38
MOL File
80-04-6.mol
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Hydrogenated bisphenol A (HBPA) Property

Melting point:
187 °C(Solv: benzene (71-43-2); ethanol (64-17-5))
Boiling point:
230-234 °C14 mm Hg(lit.)
Density 
1.048±0.06 g/cm3(Predicted)
vapor pressure 
0.001Pa at 25℃
Flash point:
>230 °F
solubility 
Insoluble in water
form 
powder to lump
pka
15.01±0.40(Predicted)
color 
White to Almost white
Water Solubility 
192mg/L at 20℃
LogP
2.5 at 25℃
CAS DataBase Reference
80-04-6(CAS DataBase Reference)
EPA Substance Registry System
Cyclohexanol, 4,4'-(1-methylethylidene)bis- (80-04-6)
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Safety

Hazard Codes 
Xi
Risk Statements 
36
Safety Statements 
26
WGK Germany 
3
HS Code 
2906.19.5000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
416517
Product name
4,4′-Isopropylidenedicyclohexanol, mixture of isomers
Purity
90%
Packaging
250g
Price
$18.88
Updated
2024/03/01
TCI Chemical
Product number
B0928
Product name
2,2-Bis(4-hydroxycyclohexyl)propane (mixture of isomers)
Purity
>93.0%(GC)
Packaging
25g
Price
$28
Updated
2024/03/01
TCI Chemical
Product number
B0928
Product name
2,2-Bis(4-hydroxycyclohexyl)propane (mixture of isomers)
Purity
>93.0%(GC)
Packaging
500g
Price
$72
Updated
2024/03/01
TRC
Product number
P835313
Product name
4,4''-(Propane-2,2-diyl)dicyclohexanol
Packaging
500mg
Price
$75
Updated
2021/12/16
Usbiological
Product number
279787
Product name
Hydrogenated bisphenol A
Packaging
25g
Price
$305
Updated
2021/12/16
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Hydrogenated bisphenol A (HBPA) Chemical Properties,Usage,Production

Description

2,2-Bis(4-hydroxycyclohexyl)propane, also known as 4,4'-Isopropylidenedicyclohexanol, is a crystalline, colorless, and odorless compound. The conformation of the cyclohexane rings gives rise to cis-cis, cis-trans and trans-trans isomers. The industrial product is a mixture of these stereoisomers. The physical properties depend on the relative amounts of the isomers present. The trans-trans compound has the lowest energy and is formed from the other isomers at higher temperature. It has the lowest solubility in solvents such as methanol, butanol, and acetone and has the highest melting point of these isomers.

Uses

4,4'-isopropylidenedicyclohexanol is unsaturated polyester resin, epoxy resin raw materials, especially as glass, steel, artificial marble bathtub, plating tank and other components, and has a water resistance, chemical resistance, thermal stability and light stability.

Production Methods

4,4'-Isopropylidenedicyclohexanol is produced by hydrogenation of bisphenol A, 2,2-bis(4-hydroxyphenyl)propane, an industrially important compound made from acetone and phenol (Phenol Derivatives). Bisphenol A is hydrogenated at about 10-30 MPa and at 150-250 ℃ on a nickel, cobalt, or ruthenium catalyst.

Flammability and Explosibility

Non flammable

Structure and conformation

4,4' -Isopropylidenedicyclohexanol (HBPA), hydrogenated from bisphenol A (BPA), is a promising and revealing alicyclic candidate to offer diamine or dianhydride monomers. Due to the different spatial conformations of hydroxyls, HBPA has three isomers, including H' BPA, H''BPA, and H'''BPA, and their contents are 47%, 45%, and 8%, respectively. However, few reports about nonplanar HBPA-based polyimides were found, probably because of the difficulty separating HBPA isomers[1-2].

References

[1] Z. Hou. “Soluble copolyimides containing 4,4′-isopropylidenedicyclohexanol (HBPA) isomer units: Synthesis, characterization, thermal, mechanical, and optical properties.” High Performance Polymers 32 1 (2019): 406–417.
[2] Zhiming Mi. “Transparent and soluble polyimide films containing 4,4′-isopropylidenedicyclohexanol (Cis-HBPA) units: Preparation, characterization, thermal, mechanical, and dielectric properties.” Journal of Polymer Science Part A: Polymer Chemistry 56 18 (2018): 2115–2128.

Hydrogenated bisphenol A (HBPA) Preparation Products And Raw materials

Raw materials

Preparation Products

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Hydrogenated bisphenol A (HBPA) Suppliers

HUNAN CHANGLIAN NEW MATERIAL TECHNOLOGY CO,LTD.
Tel
13786066360 13786066360
Email
13786066360@126.com
Country
China
ProdList
11
Advantage
58
Puyang Huicheng Electronic Material Co. Ltd.
Tel
0393-0393-0393-8910800 15036113989
Fax
0393-8912775
Email
info@huichengchem.com
Country
China
ProdList
557
Advantage
64
Jinan Valley Ruite Chemical Co. , Ltd.
Tel
0531-58668199 13153172728
Email
2199755103@qq.com
Country
China
ProdList
30
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Changzhou Sunchem Pharmaceutical Chemical Material Co.,Ltd.
Tel
0519-85195575 15861192208
Fax
85195585
Email
850305@sunkechem.com
Country
China
ProdList
75
Advantage
69
Changzhou Sunlight Pharmaceutical Co., Ltd
Tel
0519-83131668 15995063688
Fax
+86-519-83138041
Email
info@sunlightchem.com
Country
China
ProdList
99
Advantage
69
TAIYUAN RHF CO.,LTD.
Tel
+86 351 7031519
Fax
+86 351 7031519
Email
sales@RHFChem.com
Country
China
ProdList
2338
Advantage
56
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
Advantage
81
Beijing HwrkChemical Technology Co., Ltd
Tel
010-89508211 18501085097
Fax
010-89508210
Email
sales.bj@hwrkchemical.com
Country
China
ProdList
8418
Advantage
55
Pure Chemistry Scientific Inc.
Tel
001-857-928-2050 or 1-888-588-9418
Fax
001-617-206-9595
Email
sales@chemreagents.com
Country
United States
ProdList
10186
Advantage
62
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View Lastest Price from Hydrogenated bisphenol A (HBPA) manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Hydrogenated bisphenol A (HBPA) 80-40-6
Price
US $99.00-35.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-13
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
4,4'-Isopropylidenedicyclohexanol 80-04-6
Price
US $70.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-05-31
Hebei Weibang Biotechnology Co., Ltd
Product
4,4'-Isopropylidenedicyclohexanol 80-04-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-28

80-04-6, Hydrogenated bisphenol A (HBPA)Related Search:


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  • HYDROGENATED BISPHENOL A (HBPA)
  • 80-04-6
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