Hydrogenated bisphenol A （HBPA）

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Hydrogenated bisphenol A （HBPA）

Product Name: Hydrogenated bisphenol A （HBPA）
CAS No.: 80-04-6
Chemical Name: Hydrogenated bisphenol A （HBPA）
Synonyms: HYDROGENATED BISPHENOL A;2,2-BIS(4-HYDROXYCYCLOHEXYL)PROPANE;H-BPA;Maruzen H-BPA;PERHYDROBISPHENOL A;BISPHENOL A HYDROGENATED;4'-Isopropylidenedicyclohexanol;HYDROGENATED BISPHENOL A (HBPA);4,4'-ISOPROPYLIDENEDICYCLOHEXANOL;4,4'-Isopropylidinedicyclohexanol
CBNumber: CB4669962
Molecular Formula: C15H28O2
Formula Weight: 240.38
MOL File: 80-04-6.mol

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Hydrogenated bisphenol A （HBPA） Property

Melting point:: 187 °C(Solv: benzene (71-43-2); ethanol (64-17-5))
Boiling point:: 230-234 °C14 mm Hg(lit.)
Density: 1.048±0.06 g/cm3(Predicted)
vapor pressure: 0.001Pa at 25℃
Flash point:: >230 °F
solubility: Insoluble in water
form: powder to lump
pka: 15.01±0.40(Predicted)
color: White to Almost white
Water Solubility: 192mg/L at 20℃
LogP: 2.5 at 25℃
CAS DataBase Reference: 80-04-6(CAS DataBase Reference)
EPA Substance Registry System: Cyclohexanol, 4,4'-(1-methylethylidene)bis- (80-04-6)

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Safety

Hazard Codes: Xi
Risk Statements: 36
Safety Statements: 26
WGK Germany: 3
HS Code: 2906.19.5000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word: Warning
Hazard statements: H319Causes serious eye irritation
Precautionary statements: P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 416517
Product name: 4,4′-Isopropylidenedicyclohexanol, mixture of isomers
Purity: 90%
Packaging: 250g
Price: $18.88
Updated: 2024/03/01

TCI Chemical

Product number: B0928
Product name: 2,2-Bis(4-hydroxycyclohexyl)propane (mixture of isomers)
Purity: >93.0%(GC)
Packaging: 25g
Price: $28
Updated: 2024/03/01

TCI Chemical

Product number: B0928
Product name: 2,2-Bis(4-hydroxycyclohexyl)propane (mixture of isomers)
Purity: >93.0%(GC)
Packaging: 500g
Price: $72
Updated: 2024/03/01

TRC

Product number: P835313
Product name: 4,4''-(Propane-2,2-diyl)dicyclohexanol
Packaging: 500mg
Price: $75
Updated: 2021/12/16

Usbiological

Product number: 279787
Product name: Hydrogenated bisphenol A
Packaging: 25g
Price: $305
Updated: 2021/12/16

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Hydrogenated bisphenol A （HBPA） Chemical Properties,Usage,Production

Description

2,2-Bis(4-hydroxycyclohexyl)propane, also known as 4,4'-Isopropylidenedicyclohexanol, is a crystalline, colorless, and odorless compound. The conformation of the cyclohexane rings gives rise to cis-cis, cis-trans and trans-trans isomers. The industrial product is a mixture of these stereoisomers. The physical properties depend on the relative amounts of the isomers present. The trans-trans compound has the lowest energy and is formed from the other isomers at higher temperature. It has the lowest solubility in solvents such as methanol, butanol, and acetone and has the highest melting point of these isomers.

Uses

4,4'-isopropylidenedicyclohexanol is unsaturated polyester resin, epoxy resin raw materials, especially as glass, steel, artificial marble bathtub, plating tank and other components, and has a water resistance, chemical resistance, thermal stability and light stability.

Production Methods

4,4'-Isopropylidenedicyclohexanol is produced by hydrogenation of bisphenol A, 2,2-bis(4-hydroxyphenyl)propane, an industrially important compound made from acetone and phenol (Phenol Derivatives). Bisphenol A is hydrogenated at about 10-30 MPa and at 150-250 ℃ on a nickel, cobalt, or ruthenium catalyst.

Flammability and Explosibility

Non flammable

Structure and conformation

4,4' -Isopropylidenedicyclohexanol (HBPA), hydrogenated from bisphenol A (BPA), is a promising and revealing alicyclic candidate to offer diamine or dianhydride monomers. Due to the different spatial conformations of hydroxyls, HBPA has three isomers, including H' BPA, H''BPA, and H'''BPA, and their contents are 47%, 45%, and 8%, respectively. However, few reports about nonplanar HBPA-based polyimides were found, probably because of the difficulty separating HBPA isomers[1-2].

References

[1] Z. Hou. “Soluble copolyimides containing 4,4′-isopropylidenedicyclohexanol (HBPA) isomer units: Synthesis, characterization, thermal, mechanical, and optical properties.” High Performance Polymers 32 1 (2019): 406–417.
[2] Zhiming Mi. “Transparent and soluble polyimide films containing 4,4′-isopropylidenedicyclohexanol (Cis-HBPA) units: Preparation, characterization, thermal, mechanical, and dielectric properties.” Journal of Polymer Science Part A: Polymer Chemistry 56 18 (2018): 2115–2128.

Hydrogenated bisphenol A （HBPA） Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Hydrogenated bisphenol A （HBPA） manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Hydrogenated bisphenol A （HBPA） 80-40-6
Price: US $99.00-35.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-05-13

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: 4,4'-Isopropylidenedicyclohexanol 80-04-6
Price: US $70.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 5000
Release date: 2024-05-31

Hebei Weibang Biotechnology Co., Ltd

Product: 4,4'-Isopropylidenedicyclohexanol 80-04-6
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2024-11-28

80-04-6, Hydrogenated bisphenol A （HBPA）Related Search:

9,9-Bis(4-hydroxyphenyl)fluorene Bisphenol A Bis(4-hydroxyphenyl) Sulfone 4,4'-DIHYDROXYDIPHENYLMETHANE Tetrabromobisphenol A 4,4'-Sulphonylbis(2,6-dibromophenol) tert-Butyl acrylate Hydrogenated bisphenol A epoxy resin A HYDROGENATED BISPHENOL A 4-tert-Butylcyclohexanol TRANS-4-TERT-BUTYLCYCLOHEXANOL 4-TERT-AMYLCYCLOHEXANOL 2,2-DI(4,4-DI(TERT-BUTYLPEROXY)CYCLOHEXYL)PROPANE, 20 WT% SOLUTION IN ETHYLBENZENE CIS-4-TERT-BUTYLCYCLOHEXANOL 1,9-Nonanediol TRANS-4-TERT-PENTYLCYCLOHEXANOL dicyclohexylmethane 4,4'-Isopropylidenedicyclohexanol

BISPHENOL A HYDROGENATED

HYDROGENATED BISPHENOL A

4,4'-ISOPROPYLIDENEDICYCLOHEXANOL

2,2-BIS(4-HYDROXYCYCLOHEXYL)PROPANE

2,2-BIS(4-HYDROXYCYCLOHEXYL)PROPANONE

P,P'-DIHYDROXY-2,2-DICYCLOHEXYLPROPANE

PERHYDROBISPHENOL A

4,4’-(1-methylethylidene)bis-cyclohexano

4,4’-(1-methylethylidene)bis-Cyclohexanol

4'-Isopropylidenedicyclohexanol

4,4’-isopropylidenedicyclohexanol,mixtureo

2,2-Bis(hydroxycyclohexyl)propanone

4,4-Isopropylidenedicyclohexanol,mixture of isomers

4,4'-ISOPROPYLIDENEDICYCLOHEXANOL, 90%,MIXTURE OF ISOMERS

HYDROGENATED BISPHENOL A, 4,4'-ISOPROPYLIDENEDICYCLOHEXANOL

4,4'-Isopropylidinedicyclohexanol

Cyclohexanol, 4,4-(1-methylethylidene)bis-

2,2-Bis(4-hydroxycyclohexyl)propane (mixture of isomers)

Maruzen H-BPA

H-BPA

4-[1-(4-hydroxycyclohexyl)-1-methyl-ethyl]cyclohexanol

4-[2-(4-hydroxycyclohexyl)propan-2-yl]cyclohexan-1-ol

2,2-Bis(4-hydroxycyclohexyl) propane OR Hydrogenated bisphenol A(HBPA)

2,2-Bis(4-hydroxycyclohexyl)propane&nbsp

p,p'-Dihydroxy-2,2-dicyclohexylpropane Perhydrobisphenol A

4,4'-(Propane-2,2-diyl)dicyclohexanol

4,4'-Isopropylidenedicyclohexanol (HBPA)

4,4'-(Dimethylmethylene)bis(cyclohexane-1-ol)

4,4'-Isopropylidenebiscyclohexanol

4,4'-Isopropylidenedicyclohexanol, mixture of isomers 90%

4-[2-(4-hydroxycyclohexyl)propan-2-yl]-1-cyclohexanol

4,4'-Isopropylidenedicyclohexanol

4,4'-Isopropylidenedicyclohexanol, mixture of isomers

4,4'-(Propane-2,2-diyl)dicyclohexanol

HYDROGENATED BISPHENOL A (HBPA)

80-04-6

1980-04-06

80-40-6

CH32CC6H10OH2

pharm intermediate

Alcohols

Monomers

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