4-(1H-Pyrazol-1-yl)aniline

Product Name: 4-(1H-Pyrazol-1-yl)aniline
CAS No.: 17635-45-9
Chemical Name: 4-(1H-Pyrazol-1-yl)aniline
Synonyms: AKOS B029459;BUTTPARK 98\50-47;CHEMBRDG-BB 4102901;4-(1-Pyrazolyl)aniline;1-(4-AMINOPHENYL)PYRAZOLE;4-PYRAZOL-1-YL-PHENYLAMINE;4-(1H-PYRAZOL-1-YL)ANILINE;1-(4-Aminophenyl)-1H-pyrazole;4-1H-Pyrazol-1-yl-phenylamine;4-PYRAZOL-1-YL-PHENYLAMINE 95%
CBNumber: CB4670492
Molecular Formula: C9H9N3
Formula Weight: 159.19
MOL File: 17635-45-9.mol

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4-(1H-Pyrazol-1-yl)aniline Property

Melting point:: 54 °C
Boiling point:: 312.0±25.0 °C(Predicted)
Density: 1.20±0.1 g/cm3(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: solid
pka: 4.03±0.10(Predicted)
Appearance: Gray to brown Solid
InChI: InChI=1S/C9H9N3/c10-8-2-4-9(5-3-8)12-7-1-6-11-12/h1-7H,10H2
InChIKey: CSFIQHZIFKIQNO-UHFFFAOYSA-N
SMILES: C1(N)=CC=C(N2C=CC=N2)C=C1
CAS DataBase Reference: 17635-45-9(CAS DataBase Reference)

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36/37/39-37/39
HazardClass: IRRITANT
HS Code: 2921420090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: CBR01115
Product name: 4-(1H-Pyrazol-1-yl)aniline hydrochloride
Purity: Aldrich<SUP>CPR</SUP>
Packaging: 1 g
Price: $107
Updated: 2025/07/31

TRC

Product number: P842233
Product name: 4-(1H-Pyrazol-1-yl)aniline
Packaging: 10mg
Price: $45
Updated: 2021/12/16

Apolloscientific

Product number: OR23297
Product name: 4-(1H-Pyrazol-1-yl)aniline
Packaging: 5g
Price: $69
Updated: 2021/12/16

SynQuest Laboratories

Product number: 3H30-1-F7
Product name: 4-(1H-Pyrazol-1-yl)aniline
Packaging: 5G
Price: $76
Updated: 2021/12/16

Apolloscientific

Product number: OR23297
Product name: 4-(1H-Pyrazol-1-yl)aniline
Packaging: 1g
Price: $25
Updated: 2021/12/16

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4-(1H-Pyrazol-1-yl)aniline Chemical Properties,Usage,Production

Synthesis

3463-30-7

17635-45-9

GENERAL STEPS: In a typical reaction, 5.0 mg of Pd-gCN catalyst (containing 5.0 wt% Pd) was mixed with 1.0 mM 1-(4-nitrophenyl)-1H-pyrazole in ethanol (2 mL) and 60% hydrazine hydrate solution (2 mM, 1.2 equiv, 0.07 mL). The mixture was placed in a 10 mL round-bottomed flask and reacted at reflux temperature (70°C) for 4 hours, followed by cooling to room temperature. After completion of the reaction, the reaction mixture was filtered and the filtrate was purified by silica gel column chromatography to afford 4-(1H-pyrazol-1-yl)aniline (1-(4-aminophenyl)pyrazole). For dinitroaromatic substrates, 4.0 mM (2.4 eq., 0.14 mL) of 60% hydrazine hydrate solution is required.

References

[1] Chemical and Pharmaceutical Bulletin, 2000, vol. 48, # 12, p. 1935 - 1946
[2] Applied Catalysis A: General, 2016, vol. 523, p. 31 - 38
[3] Patent: EP3159340, 2017, A1. Location in patent: Paragraph 0086; 0091
[4] Patent: US2015/336982, 2015, A1. Location in patent: Paragraph 0165; 0167
[5] Patent: CN105418590, 2016, A. Location in patent: Paragraph 0152; 0153; 0154

4-(1H-Pyrazol-1-yl)aniline Preparation Products And Raw materials

Raw materials

Preparation Products

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4-(1H-Pyrazol-1-yl)aniline Suppliers

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View Lastest Price from 4-(1H-Pyrazol-1-yl)aniline manufacturers

Shanghai Rlavie Technology Co ltd

Product: 4-Pyrazol-1-yl-phenylamine 17635-45-9
Price: US $0.00-0.00/KG
Min. Order: 1g
Purity: 98%min
Supply Ability: 4-Pyrazol-1-yl-phenylamine
Release date: 2021-11-22

Career Henan Chemical Co

Product: 4-(1H-Pyrazol-1-yl)aniline 17635-45-9
Price: US $1.00/KG
Min. Order: 1KG
Purity: 98%
Supply Ability: 100KG
Release date: 2018-08-20

17635-45-9, 4-(1H-Pyrazol-1-yl)anilineRelated Search:

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17635-45-9

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