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Parylene N

Product Name
Parylene N
CAS No.
1633-22-3
Chemical Name
Parylene N
Synonyms
Paracyclophane;1,4(1,4)-dibenzenacyclohexaphane;parylene N;PCF;DI-P-XYLYLENE;DI-P-XYLENE;PLANYLENE N;Paracyclophan;Di-1,4-xylylene;Parylene N ,99%
CBNumber
CB4691420
Molecular Formula
C16H16
Formula Weight
208.3
MOL File
1633-22-3.mol
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Parylene N Property

Melting point:
285-288 °C(lit.)
Boiling point:
282.51°C (rough estimate)
Density 
1.0102 (estimate)
vapor pressure 
0.001Pa at 25℃
refractive index 
1.5000 (estimate)
storage temp. 
Sealed in dry,Room Temperature
form 
powder to crystal
color 
White to Almost white
Water Solubility 
INSOLUBLE
BRN 
1910888
InChI
InChI=1S/C16H16/c1-2-14-4-3-13(1)9-10-15-5-7-16(8-6-15)12-11-14/h1-8H,9-12H2
InChIKey
OOLUVSIJOMLOCB-UHFFFAOYSA-N
SMILES
C12C=CC(=CC=1)CCC1C=CC(=CC=1)CC2
LogP
5.14 at 20℃
NIST Chemistry Reference
[2.2]Paracyclophane(1633-22-3)
EPA Substance Registry System
Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene (1633-22-3)
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Safety

Hazard Codes 
Xi,C,F
Risk Statements 
11-34
Safety Statements 
24/25-45-36/37/39-26-16
WGK Germany 
3
RTECS 
YD2404000
Hazard Note 
Irritant
TSCA 
Yes
HS Code 
29029080
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
P225
Product name
[2.2]Paracyclophane
Purity
97%
Packaging
5G
Price
$36.4
Updated
2024/03/01
TCI Chemical
Product number
P1165
Product name
[2.2]Paracyclophane
Purity
>99.0%(GC)
Packaging
1g
Price
$99
Updated
2024/03/01
Alfa Aesar
Product number
B20136
Product name
[2.2]Paracyclophane, 99%
Packaging
1g
Price
$54.65
Updated
2024/03/01
Alfa Aesar
Product number
B20136
Product name
[2.2]Paracyclophane, 99%
Packaging
5g
Price
$201
Updated
2024/03/01
TRC
Product number
P205825
Product name
[2.2]Paracyclophane
Packaging
50mg
Price
$60
Updated
2021/12/16
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Parylene N Chemical Properties,Usage,Production

Description

[2.2]Paracyclophane is used as an intermediate in organic synthesis or as a reagent in chemical reactions. It serves as the structural backbone of 4-toluenesulfinyl [2.2]p-dicyclohexane and can be used in the synthesis of various mono- and disubstituted [2.2]p-dicyclohexane derivatives. It can also be used for the preparation of metal complexes, and the interaction of the Ag+ cation with the cation -π of [2.2]paracyclophane can be used to synthesise Ag+ - [2.2]paracyclophane complexes using the Ag+ cation. The complex is formed by binding the cation Ag+ to three carbon atoms on a benzene ring of the [2.2]paracyclophane ligand using a cation-π interaction[1].

Chemical Properties

WHITE TO LIGHT BEIGE CRYSTALS OR CRYSTAL. POWDER

Uses

2,2]-Paracyclophane is the raw material for the synthesis of parylene which is widely used in microelectronic integrated circuit.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 1043, 1981 DOI: 10.1021/jo00318a047

Flammability and Explosibility

Not classified

Purification Methods

Purify it by recrystallisation from AcOH. 1H-NMR : 1.62 (Ar-H) and -1.71 (CH2) [Waugh & Fessenden J Am Chem Soc 79 846 1957, IR and UV: Cram et al. J Am Chem Soc 76 6132 1954, Cram & Steinberg J Am Chem Soc 73 5691 1951. It complexes with unsaturated compounds: Cram & Bauer J Am Chem Soc 81 5971 1959, Syntheses: Brink Synthesis 807 1975, Givens et al. J Org Chem 44 16087 1979, Kaplan et al. Tetrahedron Lett 3665 1976]. [Beilstein 5 IV 2223.]

References

[1] DR. PETR VA?URA; Dr. T U; Prof David Sykora. Interaction of the Silver(I) Cation with [2.2]Paracyclophane: Experimental and Theoretical Study[J]. ChemistrySelect, 2022. DOI:10.1002/slct.202203008.

Parylene N Preparation Products And Raw materials

Raw materials

Preparation Products

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Parylene N Suppliers

Americas 1 Belgium 1 China 231 Czech 1 Europe 1 Germany 5 India 3 Japan 2 South Korea 2 Switzerland 1 The Netherlands 1 Ukraine 1 United Kingdom 10 United States 29 Global 289
Brunschwig chemie
Tel
--
Fax
--
Email
brunschwig@brunschwig.nl
Country
The Netherlands
ProdList
4996
Advantage
67
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View Lastest Price from Parylene N manufacturers

Shenzhen FCD Technology Co., Ltd
Product
Parylene N 1633-22-3
Price
US $0.00-0.00/g
Min. Order
500g
Purity
99.7%
Supply Ability
100kg
Release date
2024-07-12
Shenzhen FCD Technology Co., Ltd
Product
[2.2]Paracyclophane,Parylene N Dimer 1633-22-3
Price
US $0.00-0.00/g
Min. Order
500g
Purity
99.7%
Supply Ability
100kg
Release date
2024-07-10
WUHAN FORTUNA CHEMICAL CO., LTD
Product
[2.2]Paracyclophane 1633-22-3
Price
US $0.00-0.00/Kg/Drum
Min. Order
1KG
Purity
99%
Supply Ability
10 TONS
Release date
2021-06-16

1633-22-3, Parylene NRelated Search:

1,2,5,6,9,10-Hexabromocyclododecane C36 Dimer acid CYCLODODECANE P-XYLENE P-MENTHANE Poly(dimethylsiloxane) POLY(ETHYLENE TEREPHTHALATE) Dichlorodi-p-xylylene (R)-(-)-4,12-BIS(DIPHENYLPHOSPHINO)-[2.2]-PARACYCLOPHANE racemic-4,12-Dihydroxy[2.2]paracyclophane,min.97% Racemic-4,12-dibromo[2.2]paracyclophane DICHLORO[(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2,2]-PARACYCLOPHANE][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM Dichloro[2,2]paracyclophane (S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS poly-p-xylene 1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane (R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS 4,16-DIBROMO[2.2]PARACYCLOPHANE

  • TRICYCLO[8.2.2.24,7]HEXADECA-4,6,10,12,13,15-HEXAENE
  • TRICYCLO[8.2.2.2]HEXADECA-4,6,10,12,13,15-HEXAENE
  • [2.2]paracylophan
  • Cyclobis(benzene-1,4-dimethylene)
  • Di-1,4-xylylene
  • Tricyclo[8.2.2.24,7]hexadeca-1(12),4,6,10,13,15-hexaene
  • 4,4'-DIMETHYLENE-1,2-DIPHENYLETHANE
  • [2.2]PARACYCLOPHAN
  • [2.2]PARACYCLOPHANE
  • DI-P-XYLENE
  • DI-P-XYLYLENE
  • [2.2]Paracylophane
  • Tricyclo[8,2,2,24,7]hexadeca-4,6,1,12,13,15-hexaene
  • Parylene N ([2,2]Paracyclophane)
  • (2.2)PARACYCLOPHAN 97%
  • [2.2]-PARACYCLOPHANE 99+%
  • DI-PARA-XYLYLENE
  • PCF
  • Dimer,Parylene N
  • Parylene N ,99%
  • [2.2](1,4)Cyclophane
  • Di-p-xylylene Tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaene
  • Tricyclo[8,2,2,2]4,7 hexa-4,6,10,12,13,15-decane
  • 2.2ü-Paracyclophane, 99%
  • 4,4'-Ethylene(1,1'-ethylenebisbenzene)
  • Dicyclo-p-xylylene
  • Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12(1),13,15-hexaene
  • [2.2]Paracyclophane,98%
  • PLANYLENE N
  • Paracyclophane
  • [2.2]-paracyclophane (Parylene N)
  • Paracyclophan
  • TwodiMericp-xylene
  • [2.2]Paracyclophane&gt
  • 1,4(1,4)-dibenzenacyclohexaphane
  • Parylene N dimer
  • tricyclo[8.2.2.2??]hexadeca-1(13),4(16),5,7(15),10(14),11-hexaene
  • Di-p-xylylene, Parylene N
  • [2.2]Paracyclophane,Parylene N Dimer
  • parylene N
  • 1633-22-3
  • C16H16
  • Organic Building Blocks
  • Cyclophanes
  • Macrocycles for Host-Guest Chemistry
  • Building Blocks
  • Arenes
  • coating
  • Arenes
  • Building Blocks
  • Chemical Synthesis
  • Organic Building Blocks
  • fine chemicals, specialty chemicals, intermediates, electronic chemical, organic synthesis, functional materials
  • Cyclophanes
  • Functional Materials
  • Macrocycles for Host-Guest Chemistry
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