4-Pyrrolidinopyridine

Product Name: 4-Pyrrolidinopyridine
CAS No.: 2456-81-7
Chemical Name: 4-Pyrrolidinopyridine
Synonyms: Pyridine, 4-(1-pyrrolidinyl)-;4-PyrroL;4-Pyrrolidinylpyridine;IOSTEROL;idinopyridine;TIMTEC-BB SBB004083;4-PYRROLIDINOPYRIDINE;Pyrrolidinyl pyridine;1-(4-PYRIDYL)PYRROLIDINE;N-(4-PYRIDYL)PYRROLIDINE
CBNumber: CB4719087
Molecular Formula: C9H12N2
Formula Weight: 148.21
MOL File: 2456-81-7.mol

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4-Pyrrolidinopyridine Property

Melting point:: 54-58 °C(lit.)
Boiling point:: 171-173 °C (20.2527 mmHg)
Density: 1.0628 (rough estimate)
refractive index: 1.5378 (estimate)
Flash point:: >230 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: methanol: 0.1 g/mL, clear
pka: 9.58±0.10(Predicted)
form: Crystalline Mass, Crystals and/or Chunks
color: White to yellow to light brown
PH: 10.5 (3g/l, H2O, 21℃)
Water Solubility: 3 g/L (21 ºC)
BRN: 472443
InChIKey: RGUKYNXWOWSRET-UHFFFAOYSA-N
CAS DataBase Reference: 2456-81-7(CAS DataBase Reference)

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Safety

Hazard Codes: T
Risk Statements: 25-34-41-23/24/25
Safety Statements: 26-36/37/39-45
RIDADR: UN 2923 8/PG 3
WGK Germany: 3
F: 8-10-23
HazardClass: 8
PackingGroup: II
HS Code: 29333999

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 213373
Product name: 4-Pyrrolidinopyridine
Purity: 98%
Packaging: 25g
Price: $73.2
Updated: 2024/03/01

Sigma-Aldrich

Product number: 213373
Product name: 4-Pyrrolidinopyridine
Purity: 98%
Packaging: 5g
Price: $88.4
Updated: 2024/03/01

TCI Chemical

Product number: P0939
Product name: 4-Pyrrolidinopyridine
Purity: >98.0%(T)
Packaging: 5g
Price: $23
Updated: 2024/03/01

TCI Chemical

Product number: P0939
Product name: 4-Pyrrolidinopyridine
Purity: >98.0%(T)
Packaging: 25g
Price: $66
Updated: 2024/03/01

Alfa Aesar

Product number: B23989
Product name: 4-(1-Pyrrolidinyl)pyridine, 98%
Packaging: 5g
Price: $67.65
Updated: 2024/03/01

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4-Pyrrolidinopyridine Chemical Properties,Usage,Production

Description

4-Pyrrolidinopyridine is the pyridine derivative. It can be used as catalyst employed in polymerization reactions or Hypernucleophilic acylation catalyst. For example, it can be used as the catalyst for the geometry-selective (E-selective) acylation of tetrasubstituted α, α'-alkenediols. It can also be used as the ligand in metal complexes such as the Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes.

Chemical Properties

white to light brown crystalline mass

Uses

Catalyst employed in polymerization reactions. Ligand in metal complexes.

Synthesis Reference(s)

Synthetic Communications, 9, p. 251, 1979 DOI: 10.1080/00397917908064147
Synthesis, p. 985, 1988 DOI: 10.1055/s-1988-27777

References

http://www.sigmaaldrich.com/catalog/product/aldrich/213373?lang=en&region=US
http://www.sigmaaldrich.com/catalog/product/sial/83275?lang=en&region=US
Yamanaka M et al. "Origin of High E -Selectivity in 4-Pyrrolidinopyridine-Catalyzed Tetrasubstituted α,α′-Alkenediol: A Computational and Experimental Study." Journal of Organic Chemistry 80.6(2015):3075-82.
J. G. Ma?ecki, and A. Maroń. "Chloride and pseudohalide hydride-carbonyl ruthenium(II) complexes with 4-pyrrolidinopyridine as co-ligand."Transition Metal Chemistry 38.2(2013):133-142.

4-Pyrrolidinopyridine Preparation Products And Raw materials

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Preparation Products

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View Lastest Price from 4-Pyrrolidinopyridine manufacturers

Dideu Industries Group Limited

Product: 4-Pyrrolidinopyridine 2456-81-7
Price: US $1.10/g
Min. Order: 1g
Purity: 99.00%
Supply Ability: 100 Tons Min
Release date: 2021-10-25

Career Henan Chemical Co

Product: 4-Pyrrolidinopyridine 2456-81-7
Price: US $1.00/KG
Min. Order: 1KG
Purity: 95-99%
Supply Ability: 1ton
Release date: 2019-12-30

2456-81-7, 4-PyrrolidinopyridineRelated Search:

Pyridine Cetylpyridinium chloride 1-Hexadecylpyridinium bromide N-Methyl-2-pyrrolidone Polyvinylpyrrolidone L-N-[(4'-BOC)PIPERIDINO]PROLINE METHYL-2-PYRROLIDONE 3-Dodecyl-1-(2,2,6,6-tetramethyl-4-piperidyl)pyrrolidine-2,5-dione (S)-(-)-4-PYRROLIDINOPYRINDINYL(PENTAMETHYLCYCLOPENTADIENYL)IRON 2-PYRROLIDIN-2-YLPYRIDINE 6-(1-PYRROLIDINYL)NICOTINALDEHYDE Pyrrole L-N-(4'-N-CBZ-PIPERIDINO)PROLINE 4-(1-pyrrolidinyl)piperidine dihydrochloride N-(1-ACETYL-2,2,6,6-TETRAMETHYL-4-PIPERIDINYL)-2-DODECYLSUCCINIMIDE (S)-N-[4'-BENZYL)PIPERIDINO]PROLINE 2-DODECYL-N-(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL)SUCCINIMIDE 4-Pyrrolidinopyridine

4-PYRROLIDIN-1-YL-PYRIDINE

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4-(1-Pyrrolidyl) pyridine

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4-Pyrrolidinopyridine,98%

IOSTEROL

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4-Pyrrolidinopyridine purum, >=98.0% (NT)

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4-Pyrrolidinopyridine&gt

4-Pyrrolidinopyridine ISO 9001：2015 REACH

2456-81-7

Pyridines

Condensation & Active Esterification

Heterocyclic Building Blocks

C9 to C46

Building Blocks

Heterocycle-Pyridine series

Pyridine

Pyridines derivates

Pyridines

Condensation & Active Esterification

Synthetic Organic Chemistry

C9 to C46

Heterocyclic Building Blocks

2456-81-7