ChemicalBook > CAS DataBase List > 6-Shogaol

6-Shogaol

Product Name
6-Shogaol
CAS No.
555-66-8
Chemical Name
6-Shogaol
Synonyms
SHOGAOL;6-SHOGAOL;6-Shagaol;SHOGAOL, 6-;6-gingerenol;6-Shogaol-RM;6-Shogaol USP/EP/BP;[6]-Shogaol D5 (Major);TIANFU-CHEM - 6-Shogaol;1-(4-Hydroxy-3-methoxyphenyl)-4-decen-3-one
CBNumber
CB4748322
Molecular Formula
C17H24O3
Formula Weight
276.37
MOL File
555-66-8.mol
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6-Shogaol Property

Boiling point:
427.5±35.0 °C(Predicted)
Density 
1.0448 g/cm3(Temp: 25 °C)
storage temp. 
Keep in dark place,Inert atmosphere,2-8°C
solubility 
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
pka
10.01±0.20(Predicted)
form 
Liquid
color 
Colourless to Light Yellow
Odor
Mild, warm-herbaceous, sweet odor
BRN 
2056098
InChI
InChI=1S/C17H24O3/c1-3-4-5-6-7-8-15(18)11-9-14-10-12-16(19)17(13-14)20-2/h7-8,10,12-13,19H,3-6,9,11H2,1-2H3
InChIKey
OQWKEEOHDMUXEO-BQYQJAHWSA-N
SMILES
C(C1=CC=C(O)C(OC)=C1)CC(=O)C=CCCCCC
LogP
3.789 (est)
CAS DataBase Reference
555-66-8(CAS DataBase Reference)
NIST Chemistry Reference
6-shogaol(555-66-8)
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Safety

Hazard Codes 
Xn
Risk Statements 
22
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
SMB00311
Product name
[6]-Shogaol
Purity
≥90% (HPLC)
Packaging
50mg
Price
$947
Updated
2024/03/01
Sigma-Aldrich
Product number
39303
Product name
[6]-Shogaol
Purity
analytical standard
Packaging
10mg
Price
$740
Updated
2024/03/01
Cayman Chemical
Product number
11901
Product name
6-Shogaol
Purity
≥95%
Packaging
1mg
Price
$44
Updated
2024/03/01
Cayman Chemical
Product number
11901
Product name
6-Shogaol
Purity
≥95%
Packaging
5mg
Price
$172
Updated
2024/03/01
Cayman Chemical
Product number
11901
Product name
6-Shogaol
Purity
≥95%
Packaging
10mg
Price
$321
Updated
2024/03/01
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6-Shogaol Chemical Properties,Usage,Production

Chemical Properties

White crystalline powder. B.P. higher than 300℃. Very slightly soluble in water, soluble in alcohol and oils.

Uses

[6]-Shogaol is an aromatic constituent of ginger and the chain-dehydroxylated analog of [6]-Gingerol. [6]-Shogaol has activity very similar to [6]-Gingerol and produced an inhibition of spontaneous motor activity, antipyretic and analgesic effects, and prolonged hexobarbital-induced sleeping time. [6]-Shogaol also has potent antitussive activity and affected the cortical EEG.

Definition

ChEBI: [6]-Shogaol is a monomethoxybenzene, a member of phenols and an enone.

Application

Shogaol has little or no application in perfumery, and very little interest to the flavor industry, but it is included in this work mainly for the purpose of elucidating the problems apparently existing around the description of the odorand flavor of "Zingerone".

Preparation

6-Shogaol is prepared by condensation of Vanillin with Acetone, followed by hydrogenation. The resulting ketone is then condensed with Hexaldehyde under conditions which inactivate the hydroxyl group during the reaction.

Anticancer Research

6-Shogaol is the dehydrated product of 6-gingerol, extracted from the rhizome ofginger. Treatment of HCC cell line with 6-shogaol resulted in cells with apoptoticphenotypes, which showed signs of cell and nuclear shrinkage as well as substantialchromatin condensation. De-phosphorylation of PERK and activation of theexpression of CHOP initiate caspase cascade reaction inducing apoptosis inHCC. Two-dimensional gel electrophoretic analysis of proteome revealed that in response to the treatment with 6-shogaol, a significant stimulation was observed inproteins related to the ER stress, signifying that apoptosis induced by 6-shogoal didinvolve ER stress. Cells showed marked rise in the UPR target expression, HSP70,Grp94, Grp78/Bip and the other ER chaperones on exposure to 6-shogoal in a time-dependentmanner, which elicited activation of caspase-3 and degradation of polyADP ribose polymerase (PARP). Various ER chaperone proteins improve adaptationof cancer cells to hypoxic environment and aid in developing resistance againstanticancer therapy (Zorzi and Bonvini 2011; Urra et al. 2016). Screening of specificinhibitors of Grp78 as antitumour agents (Hu et al. 2012; Liu et al. 2013; Venkatesanet al. 2015) implies that inhibition of Grp78/Bip is a very promising anticancerstrategy. HCC cells are selectively killed by 6-shogaol in the absence of anynoticeable toxic consequence on normal healthy cells and very little toxicity asstudied on SMMC7721 xenograft mice. Administration of 6-shogaol and salubrinaltogether for distinct time intervals resulted in significant increase in ER stress in thecell. It appears that 6-shogaol in combination with salubrinal has great therapeuticvalue against various malignancies including HCC (Hu et al. 2012).

6-Shogaol Preparation Products And Raw materials

Raw materials

Preparation Products

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6-Shogaol Suppliers

cfm Oskar Tropitzsch
Tel
--
Fax
--
Country
Germany
ProdList
1136
Advantage
62
Service Chemical Inc.
Tel
--
Fax
--
Email
sales@chemos-group.com
Country
Germany
ProdList
6350
Advantage
71
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View Lastest Price from 6-Shogaol manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
6-Shogaol 555-66-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-01
Hebei Mojin Biotechnology Co., Ltd
Product
3-Isothioureidopropionic acid 555-66-8
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-10-16
Shanghai Standard Technology Co., Ltd.
Product
6-Shogaol 555-66-8
Price
US $0.00/ml
Min. Order
0.1ml
Purity
≥98%(HPLC)
Supply Ability
100 ml
Release date
2020-03-05

555-66-8, 6-ShogaolRelated Search:


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  • 6-SHOGAOL
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  • 6-Shagaol
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  • 1-(4-Hydroxy-3-methoxyphenyl)-4-decen-3-one
  • 6-Shogaol USP/EP/BP
  • [6]-Shogaol D5 (Major)
  • TIANFU-CHEM - 6-Shogaol
  • 1-(4-Hydroxy-3-methoxyphenyl)dec-4-en-3-one
  • 6-gingerenol
  • 6-Shogaol-RM
  • 555-66-8
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