Bis(2,4-pentanedionato-O,O')palladium(II)
- Product Name
- Bis(2,4-pentanedionato-O,O')palladium(II)
- CAS No.
- 14024-61-4
- Chemical Name
- Bis(2,4-pentanedionato-O,O')palladium(II)
- Synonyms
- PALLADIUM(II) ACETYLACETONATE;PALLADIUM ACETYLACETONATE;BIS(ACETYLACETONATO)PALLADIUM(II);BIS(2,4-PENTANEDIONATO)PALLADIUM(II);ACETYLACETONE, PALLADIUM(II) DERIVATIVE;34.7%Pd;Umicore, 99%;Palladium acet;PALLADIUM-ACETYLACETONAT;Palladous acetylacetonate
- CBNumber
- CB4751427
- Molecular Formula
- C10H14O4Pd
- Formula Weight
- 304.64
- MOL File
- 14024-61-4.mol
Bis(2,4-pentanedionato-O,O')palladium(II) Property
- Melting point:
- 190 °C
- vapor pressure
- 0Pa at 25℃
- storage temp.
- Store below +30°C.
- solubility
- Soluble in benzene and chloroform.
- form
- Solution
- color
- Yellow to orange
- Specific Gravity
- 1.862
- Water Solubility
- INSOLUBLE
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- BRN
- 4136188
- InChI
- InChI=1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;
- InChIKey
- RJJXYEQOOACRKP-LNKPDPKZSA-M
- SMILES
- O([Pd]O/C(/C)=C\C(=O)C)/C(/C)=C\C(=O)C
- LogP
- 2.6 at 25℃
- NIST Chemistry Reference
- Bis(acetylacetonato)palladium(14024-61-4)
- EPA Substance Registry System
- Palladium, bis(2,4-pentanedionato-.kappa.O,.kappa.O')-, (SP-4-1)- (14024-61-4)
Safety
- Hazard Codes
- Xi,Xn
- Risk Statements
- 36-36/37/38-22
- Safety Statements
- 26-37/39
- RIDADR
- 3181
- WGK Germany
- 2
- TSCA
- Yes
- HS Code
- 28439090
N-Bromosuccinimide Price
- Product number
- 209015
- Product name
- Palladium(II) acetylacetonate
- Purity
- 99%
- Packaging
- 1g
- Price
- $102
- Updated
- 2024/03/01
- Product number
- 209015
- Product name
- Palladium(II) acetylacetonate
- Purity
- 99%
- Packaging
- 5g
- Price
- $410
- Updated
- 2024/03/01
- Product number
- 8.07103
- Product name
- Palladium(II) acetylacetonate
- Purity
- ≥98% (ICP)
- Packaging
- 5G
- Price
- $312.65
- Updated
- 2021/12/16
- Product number
- 8.07103
- Product name
- Palladium(II) acetylacetonate
- Purity
- ≥98% (ICP)
- Packaging
- 1g
- Price
- $77.51
- Updated
- 2021/12/16
- Product number
- B2018
- Product name
- Bis(2,4-pentanedionato)palladium(II)
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $187
- Updated
- 2024/03/01
Bis(2,4-pentanedionato-O,O')palladium(II) Chemical Properties,Usage,Production
Chemical Properties
yellow orange needles
Uses
Palladium(II) Acetylacetonate is an active anticancer agent. Exhibits growth inhibitory effect more than cisplatin in several cancer cells and treatment with Palladium(II) Acetylacetonate inhibits H460 cells. Palladium(II) Acetylacetonate is a catalyst for various organic transformations.
Uses
Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:
- Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).
- Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.
- As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
General Description
Palladium(II) acetylacetonate (Pd(acac)2) is a metal-organic complex. Sublimation of Pd(acac)2 has been investigated by thermogravimetry and XRD. The temperature range for the sublimation of Pd(acac)2, without undergoing thermal decomposition, was determined to be 100-160°C in the presence of inert gas helium.
Flammability and Explosibility
Highly flammable
Purification Methods
It can be recrystallised from *C6H6/pet ether and sublimes in vacuo. It is soluble in heptane, *C6H6 (1.2% at 20o, 2.2 at 40o), toluene (0.56% at 20o, 1.4% at 40o) and acetylacetone (1.2% at 20o, 0.05% at 40o). [West & Riley J Inorg Nucl Chem 5 295 1957/8, Fernelius & Bryant Inorg Synth V 105 1957, Beilstein 1 IV 3676.]
Bis(2,4-pentanedionato-O,O')palladium(II) Preparation Products And Raw materials
Raw materials
Preparation Products
Bis(2,4-pentanedionato-O,O')palladium(II) Suppliers
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View Lastest Price from Bis(2,4-pentanedionato-O,O')palladium(II) manufacturers
- Product
- Bis(2,4-pentanedionato-O,O')palladium(II) 14024-61-4
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 20ton
- Release date
- 2024-05-30
- Product
- Bis(2,4-pentanedionato-O,O')palladium(II) 14024-61-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2024-03-26
- Product
- Bis(2,4-pentanedionato-O,O")palladium(II) 14024-61-4
- Price
- US $15.00-10.00/KG
- Min. Order
- 1KG
- Purity
- 99%+ HPLC
- Supply Ability
- Monthly supply of 1 ton
- Release date
- 2021-07-11