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Ethyl caprylate

Product Name
Ethyl caprylate
CAS No.
106-32-1
Chemical Name
Ethyl caprylate
Synonyms
ETHYL OCTANOATE;OCTANOIC ACID ETHYL ESTER;Octanoic acid ethyl;Ethyl octoate;Ethyl carprylate;Ethyloctanoat;ETHYL OCTYLATE;Etheyl Octanoat;WC3035;WC 3035
CBNumber
CB4852670
Molecular Formula
C10H20O2
Formula Weight
172.26
MOL File
106-32-1.mol
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Ethyl caprylate Property

Melting point:
-48--47 °C (lit.)
Boiling point:
206-208 °C (lit.)
Density 
0.867 g/mL at 20 °C (lit.)
vapor pressure 
0.02 mm Hg ( 25 °C)
refractive index 
n20/D 1.417(lit.)
FEMA 
2449 | ETHYL OCTANOATE
Flash point:
167 °F
storage temp. 
Store below +30°C.
solubility 
ethanol: soluble1ml/4ml, clear, colorless (70% ethanol)
form 
Liquid
color 
Clear colorless
Odor
at 100.00 %. fruity wine waxy sweet apricot banana brandy pear
Odor Type
waxy
explosive limit
0.7%(V)
Water Solubility 
insoluble
Merck 
14,3778
JECFA Number
33
BRN 
1754470
LogP
4.47 at 22.7℃
CAS DataBase Reference
106-32-1(CAS DataBase Reference)
NIST Chemistry Reference
Octanoic acid, ethyl ester(106-32-1)
EPA Substance Registry System
Ethyl octanoate (106-32-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
RH0680000
Autoignition Temperature
325 °C
TSCA 
Yes
HS Code 
29159080
Toxicity
LD50 orally in rats: 25,960 mg/kg, P. M. Jenner et al., Food Cosmet. Toxicol. 2, 327 (1964)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
W244910
Product name
Ethyl octanoate
Purity
natural, ≥98%, FCC, FG
Packaging
1kg
Price
$266
Updated
2024/03/01
Sigma-Aldrich
Product number
W244910
Product name
Ethyl octanoate
Purity
natural, ≥98%, FCC, FG
Packaging
4kg
Price
$557
Updated
2024/03/01
Sigma-Aldrich
Product number
W244902
Product name
Ethyl octanoate
Purity
≥98%, FCC, FG
Packaging
1kg
Price
$68.9
Updated
2024/03/01
Sigma-Aldrich
Product number
W244902
Product name
Ethyl octanoate
Purity
≥98%, FCC, FG
Packaging
4kg
Price
$230
Updated
2024/03/01
Sigma-Aldrich
Product number
W244902
Product name
Ethyl octanoate
Purity
≥98%, FCC, FG
Packaging
20kg
Price
$631
Updated
2024/03/01
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Ethyl caprylate Chemical Properties,Usage,Production

Description

Ethyl caprylate (ethyl octanoate) is a kind of fatty acid ester formed from caprylic acid and ethanol. It is a kind of natural fruit flavoring agent. It is usually included in the alcohol beverage. Among the main flavoring components of None-flavor liquor, the absolute content of ethyl caprylate is not high but its flavoring contributions is higher than ethyl acetate, ethyl lactate, and ethyl butyrate, only lower than ethyl caproate. Only small amount of ethyl caprylate could produce obvious fruit aroma in Nong-flavor liquor. However, excessive content of ethyl caprylate would inhibit the performance of other flavoring components.

Chemical Properties

Ethyl Octanoate is a liquid with a fruity, floral odor. It occurs in many fruits and alcoholic beverages and is used in fruit flavors.

Chemical Properties

Ethyl octanoate has a pleasant, fruity, floral odor (wine–apricot note)

Chemical Properties

CLEAR COLOURLESS LIQUID

Occurrence

Reported found in apple, apricot, orange juice, grapefruit juice, guava, pineapple, cheddar cheese, other cheeses, butter, beer, cognac, rum, whiskey, cider, grape wines, cocoa, coconut meat, passion fruit, mango, pawpaw and mastic gum leaf oil.

Uses

Ethyl caprylate is a flavoring and fragrance agent.

Uses

Ethyl octanoate, found in Burgundy wine, was used to study its partition co-efficient in water in model wine using the headspace method.

Uses

manufacture of fruit ethers; constituent of enanthic, cocoic, and cognac ethers.

Preparation

Usually prepared by esterification of caprylic acid with ethyl alcohol and sulfuric acid as catalyst; also by alcoholysis of coconut oil in the presence of HCl.

Definition

ChEBI: A fatty acid ethyl ester resulting from the formal condensation of octanoic acid with ethanol.

Aroma threshold values

Detection: 5 to 92 ppb

Taste threshold values

Taste characteristics at 5 ppm: waxy, fatty, aldehydic, coconut, creamy and dairy-like.

Synthesis Reference(s)

Journal of the American Chemical Society, 89, p. 6804, 1967 DOI: 10.1021/ja01001a097
The Journal of Organic Chemistry, 42, p. 3209, 1977 DOI: 10.1021/jo00439a026

General Description

Ethyl octanoate is a powerful odourant found in mead (a traditional drink that contains alcohol).

Flammability and Explosibility

Not classified

Safety Profile

Mddly toxic by ingestion. A skin irritant. Combustible liquid. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

Carcinogenicity

Not listed by ACGIH, California Proposition 65, IARC, NTP, or OSHA.

Metabolism

Aliphatic esters including ethyl caprylate are thought to be readily hydrolysed to the corresponding alcohol and acid, which are then further metabolized (Fassett, 1963). Oral adminis tration of ethyl caprylate to rats produced a ketonuria twice as great as that from acetoacetate, indicating the formation of two fragments for the production of ketone bodies, and it was suggested that caprylic acid was probably broken down by a process involving multiple alternate oxidation (Deuel, Hallman, Butts & Murray, 1936).

References

Powers, John J. "HETEROGENEITY AND TEMPERATURE EFFECTS ON FLAVOR SENSING OF ETHYL CAPRYLATE." Journal of Food Science 42.1(2010):275-276.
Zhibin, L. I., and L. I. Jin. "Analysis of the Content of Ethyl Caprylate in Nong-flavor Liquor and Its Flavoring Contributions." Liquor-Making Science & Technology (2013).

Ethyl caprylate Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyl caprylate Suppliers

J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
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China
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94657
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76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
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future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
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Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30123
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24529
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81
Energy Chemical
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021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
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jiliang chemicals
Tel
21-62165282 15801962796;
Fax
021 61153784
Email
bidingchem@163.com
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China
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Beijing Isomersyn Technology CO;LTD
Tel
010-82954736 13391601435
Email
sales@isomersyn.com
Country
China
ProdList
3295
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Shandong Xiya Chemical Co., Ltd
Tel
4009903999 13355009207
Fax
0539-6365991
Email
3007715519@qq.com
Country
China
ProdList
18738
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57
Syntechem Co.,Ltd
Tel
Fax
E-Mail Inquiry
Email
info@syntechem.com
Country
China
ProdList
12984
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View Lastest Price from Ethyl caprylate manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD
Product
Ethyl Octanoate 106-32-1
Price
US $0.00/KG
Min. Order
25KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-14
Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Ethyl caprylate 106-32-1
Price
US $50.00/kg
Min. Order
1kg
Purity
99
Supply Ability
5000
Release date
2024-05-21
Shandong Deshang Chemical Co., Ltd.
Product
Ethyl caprylate 106-32-1
Price
US $8.00-5.00/kg
Min. Order
1kg
Purity
99.99%
Supply Ability
10 tons
Release date
2024-06-21

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