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3-Nitrobenzyl chloride

Product Name
3-Nitrobenzyl chloride
CAS No.
619-23-8
Chemical Name
3-Nitrobenzyl chloride
Synonyms
AKOS BBS-00004022;3-NITROBENZYL CHLORIDE;M-NITROBENZYL CHLORIDE;A-CHLORO-M-NITROTOLUENE;a-Chloro-3-nitrotoluene;à-chloro-3-nitrotoluene;α-chloro-3-nitrotoluene;α-Chloro-m-nitrotoluene;?-chloro-3-nitrotoluene;META-NITROBENZYLCHLORIDE
CBNumber
CB4853990
Molecular Formula
C7H6ClNO2
Formula Weight
171.58
MOL File
619-23-8.mol
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3-Nitrobenzyl chloride Property

Melting point:
43-47 °C(lit.)
Boiling point:
85-87 °C5 mm Hg(lit.)
Density 
1503
refractive index 
1.5577 (estimate)
Flash point:
>230 °F
solubility 
soluble in Methanol
form 
Crystalline Solid
color 
Light yellow to light brown
Water Solubility 
<0.1 g/100 mL at 22 ºC
BRN 
742794
CAS DataBase Reference
619-23-8(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-(chloromethyl)-3-nitro-(619-23-8)
EPA Substance Registry System
3-Nitrobenzyl chloride (619-23-8)
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Safety

Hazard Codes 
C
Risk Statements 
34-36
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
RTECS 
XS9090000
4.8-10-19-21
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29049090
Hazardous Substances Data
619-23-8(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P363Wash contaminated clothing before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
191167
Product name
3-Nitrobenzyl chloride
Purity
97%
Packaging
10g
Price
$80.1
Updated
2023/06/20
Sigma-Aldrich
Product number
191167
Product name
3-Nitrobenzyl chloride
Purity
97%
Packaging
50g
Price
$370
Updated
2023/06/20
TCI Chemical
Product number
C0709
Product name
3-Nitrobenzyl Chloride
Purity
>99.0%(GC)
Packaging
5g
Price
$57
Updated
2023/06/20
TCI Chemical
Product number
C0709
Product name
3-Nitrobenzyl Chloride
Purity
>99.0%(GC)
Packaging
25g
Price
$176
Updated
2023/06/20
Alfa Aesar
Product number
A16775
Product name
3-Nitrobenzyl chloride, 98%
Packaging
10g
Price
$42.4
Updated
2023/06/20
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3-Nitrobenzyl chloride Chemical Properties,Usage,Production

Chemical Properties

yellow to brown crystalline solid

Uses

3-Nitrobenzyl chloride was used in the synthesis of 8-chloropurine.

General Description

Yellow to brown solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

A halogenated aromatic nitro compound. Aromatic nitro compounds range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

Fire Hazard

Flash point data concerning 3-Nitrobenzyl chloride are not available, however, 3-Nitrobenzyl chloride is probably combustible.

Purification Methods

Crystallise the chloride from pet ether (b 90-120o). IRRITANT.[Beilstein 5 IV 855.]

3-Nitrobenzyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Nitrobenzyl chloride Suppliers

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