ChemicalBook > CAS DataBase List > Acryloyl chloride

Acryloyl chloride

Product Name
Acryloyl chloride
CAS No.
814-68-6
Chemical Name
Acryloyl chloride
Synonyms
prop-2-enoyl chloride;oyL;2-PROPENOYL CHLORIDE;acrylyl chloride;ACRYLIC ACID CHLORIDE;Propenoyl chloride;chloridkyselinyakrylove;Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole;propenoylchloride;ACRYLOYL CHLORIDE
CBNumber
CB4854427
Molecular Formula
C3H3ClO
Formula Weight
90.51
MOL File
814-68-6.mol
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Acryloyl chloride Property

Melting point:
76 °C(Solv: isopropyl ether (108-20-3))
Boiling point:
72-76 °C (lit.)
Density 
1.114 g/mL at 25 °C (lit.)
vapor density 
>1 (vs air)
vapor pressure 
1.93 psi ( 20 °C)
refractive index 
n20/D 1.435(lit.)
Flash point:
61 °F
storage temp. 
2-8°C
solubility 
Chloroform (Soluble), Methanol (Slightly)
form 
Oil
color 
Colourless to Pale Yellow
Water Solubility 
Miscible with water.
Sensitive 
Moisture & Light Sensitive
BRN 
635744
Exposure limits
ACGIH: TWA 5 mg/m3 (Skin)
NIOSH: TWA 5 mg/m3
Stability:
Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
InChIKey
HFBMWMNUJJDEQZ-UHFFFAOYSA-N
CAS DataBase Reference
814-68-6(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenoyl chloride(814-68-6)
EPA Substance Registry System
Acrylyl chloride (814-68-6)
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Safety

Hazard Codes 
F,T+
Risk Statements 
11-14-26-34
Safety Statements 
16-26-28-36/37/39-45-7/9
RIDADR 
UN 3383 6.1/PG 1
WGK Germany 
3
RTECS 
AT7350000
F 
8-10
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29161980
Hazardous Substances Data
814-68-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H290May be corrosive to metals

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H330Fatal if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
549797
Product name
Acryloyl chloride
Purity
97.0%, contains <210ppm MEHQ as stabilizer
Packaging
5g
Price
$76.2
Updated
2024/03/01
Sigma-Aldrich
Product number
549797
Product name
Acryloyl chloride
Purity
97.0%, contains <210ppm MEHQ as stabilizer
Packaging
500g
Price
$646
Updated
2024/03/01
Alfa Aesar
Product number
L10363
Product name
Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
Packaging
10g
Price
$40.5
Updated
2021/12/16
Alfa Aesar
Product number
L10363
Product name
Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
Packaging
50g
Price
$60.6
Updated
2021/12/16
Sigma-Aldrich
Product number
A24109
Product name
Acryloyl chloride
Purity
≥97%, contains ~400ppm phenothiazine as stabilizer
Packaging
5g
Price
$66.7
Updated
2024/03/01
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Acryloyl chloride Chemical Properties,Usage,Production

Chemical Properties

Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator.

Uses

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 72, 1950 DOI: 10.1021/ja01157a020

General Description

A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture.

Air & Water Reactions

Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid.

Reactivity Profile

Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Fire Hazard

When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water.

Potential Exposure

May be used as a monomer in preparation of specialty polymers or as a chemical intermediate

Shipping

UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required

Incompatibilities

Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals.

Acryloyl chloride Preparation Products And Raw materials

Raw materials

Copper(I) chloride

Preparation Products

N-Isopropylacrylamide N-ACRYLOXYSUCCINIMIDE N-NONYL ACRYLATE 1,4-Diacryloylpiperazine 1,4-BUTANEDIOL DIACRYLATE Atracurium besylate
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View Lastest Price from Acryloyl chloride manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
Acryloyl chloride 814-68-6
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10 mt
Release date
2024-11-21
Hebei Chuanghai Biotechnology Co,.LTD
Product
Acryloyl Chloride 814-68-6
Price
US $10.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
10 ton
Release date
2024-08-21
Hebei Kingfiner Technology Development Co.Ltd
Product
Acryloyl chloride 814-68-6
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
500000kg
Release date
2023-08-03

814-68-6, Acryloyl chlorideRelated Search:

Choline chloride Ammonium chloride Benzyl chloride Acrylamide Calcium chloride Mepiquat chloride Sodium chloride Polyvinyl chloride Tetramethyl Ibandronate methyl N-(3-methoxy-3-oxopropyl)-N-methyl-beta-alaninate Ibandronate sodium monohydrate Trisodium phosphate N-Methylpentylamine b-Alanine, N-methyl-N-pentyl- Phosphonic acid, disodium salt N-Methyl-N-pentyl-beta-alanine methyl ester Ibandronate Impurity 1(Ibandronate EP Impurity B) Pamidronic acid Acrylic Acid Chloride Propenoyl Chloride

  • chloridkyselinyakrylove
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  • Acryloyl chloride, 97%, stabilized with 400 ppm phenothiazine
  • Acryloyl chloride, 97%, stabilized with 400 ppm p-Hydroxyanisole
  • Acrylyl chloride manufacturer kf-wang(at)kf-chem.com
  • oyL
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  • acrylyl chloride
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  • ACRYLIC ACID CHLORIDE
  • ACRYLOYL CHLORIDE (STABILISED WITH PHENO
  • 2-PROPENOYL CHLORIDE
  • Chlorid kyseliny akrylove
  • Acryloyl Chloride (stabilized with Phenothiazine)&gt
  • Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole
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  • Acryloyl chloride ISO 9001：2015 REACH
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  • HYPERICUM PERFORATUM OIL 68917-49-7
  • Acryloyl chloride (6CI, 8CI)
  • Acryloyl chloride,99.5%
  • Acryloyl Chloride, stabilized with Phenothiazine), ≥ 95.0%
  • 814-68-6
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  • C3H3OCl
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  • ACID CHLORIDES
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  • 814-68-6