ChemicalBook > CAS DataBase List > Acryloyl chloride
Acryloyl chloride
- Product Name
- Acryloyl chloride
- CAS No.
- 814-68-6
- Chemical Name
- Acryloyl chloride
- Synonyms
- prop-2-enoyl chloride;oyL;2-PROPENOYL CHLORIDE;acrylyl chloride;ACRYLIC ACID CHLORIDE;Propenoyl chloride;chloridkyselinyakrylove;Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole;propenoylchloride;ACRYLOYL CHLORIDE
- CBNumber
- CB4854427
- Molecular Formula
- C3H3ClO
- Formula Weight
- 90.51
- MOL File
- 814-68-6.mol
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Acryloyl chloride Property
- Melting point:
- 76 °C(Solv: isopropyl ether (108-20-3))
- Boiling point:
- 72-76 °C (lit.)
- Density
- 1.114 g/mL at 25 °C (lit.)
- vapor density
- >1 (vs air)
- vapor pressure
- 1.93 psi ( 20 °C)
- refractive index
- n20/D 1.435(lit.)
- Flash point:
- 61 °F
- storage temp.
- 2-8°C
- solubility
- Chloroform (Soluble), Methanol (Slightly)
- form
- Oil
- color
- Colourless to Pale Yellow
- Water Solubility
- Miscible with water.
- Sensitive
- Moisture & Light Sensitive
- BRN
- 635744
- Exposure limits
- ACGIH: TWA 5 mg/m3 (Skin)
NIOSH: TWA 5 mg/m3 - Stability:
- Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
- InChIKey
- HFBMWMNUJJDEQZ-UHFFFAOYSA-N
- CAS DataBase Reference
- 814-68-6(CAS DataBase Reference)
- NIST Chemistry Reference
- 2-Propenoyl chloride(814-68-6)
- EPA Substance Registry System
- Acrylyl chloride (814-68-6)
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Safety
- Hazard Codes
- F,T+
- Risk Statements
- 11-14-26-34
- Safety Statements
- 16-26-28-36/37/39-45-7/9
- RIDADR
- UN 3383 6.1/PG 1
- WGK Germany
- 3
- RTECS
- AT7350000
- F
- 8-10
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29161980
- Hazardous Substances Data
- 814-68-6(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H290May be corrosive to metals
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
H330Fatal if inhaled
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 549797
- Product name
- Acryloyl chloride
- Purity
- 97.0%, contains <210ppm MEHQ as stabilizer
- Packaging
- 5g
- Price
- $76.2
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 549797
- Product name
- Acryloyl chloride
- Purity
- 97.0%, contains <210ppm MEHQ as stabilizer
- Packaging
- 500g
- Price
- $646
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- L10363
- Product name
- Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
- Packaging
- 10g
- Price
- $40.5
- Updated
- 2021/12/16
Alfa Aesar
- Product number
- L10363
- Product name
- Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
- Packaging
- 50g
- Price
- $60.6
- Updated
- 2021/12/16
Sigma-Aldrich
- Product number
- A24109
- Product name
- Acryloyl chloride
- Purity
- ≥97%, contains ~400ppm phenothiazine as stabilizer
- Packaging
- 5g
- Price
- $66.7
- Updated
- 2024/03/01
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Acryloyl chloride Chemical Properties,Usage,Production
Chemical Properties
Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator.
Uses
Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.
Synthesis Reference(s)
Journal of the American Chemical Society, 72, p. 72, 1950 DOI: 10.1021/ja01157a020
General Description
A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture.
Air & Water Reactions
Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid.
Reactivity Profile
Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Fire Hazard
When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water.
Potential Exposure
May be used as a monomer in preparation of specialty polymers or as a chemical intermediate
Shipping
UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required
Incompatibilities
Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals.
Acryloyl chloride Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Acryloyl chloride manufacturers
Ouhuang Engineering Materials (Hubei) Co., Ltd
- Product
- Acrylyl chloride 814-68-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99.91%
- Supply Ability
- 200000
- Release date
- 2024-04-19
Ouhuang Engineering Materials (Hubei) Co., Ltd
- Product
- Tritanol 814-68-6
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99.91%
- Supply Ability
- 200000
- Release date
- 2024-04-19
Henan Fengda Chemical Co., Ltd
- Product
- Acryloyl chloride 814-68-6
- Price
- US $100.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-26
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