HEXARHODIUM HEXADECACARBONYL

Product Name: HEXARHODIUM HEXADECACARBONYL
CAS No.: 28407-51-4
Chemical Name: HEXARHODIUM HEXADECACARBONYL
Synonyms: RHODIUM CARBONYL;rhodium(0) carbonyl;[Rh6(CO)12(μ3-CO)4];rhodium hexacarbonyl;Hexadecacarbonylhexa;Carbon Monoxide rhodiuM;HEXADECACARBONYLHEXARHODIUM;HEXARHODIUM HEXADECACARBONYL;HEXADECACARBONYLHEXARHODIUM (0);hexarhodium(0) hexadecacarbonyl
CBNumber: CB5101874
Molecular Formula: C16O16Rh6
Formula Weight: 1065.59
MOL File: 28407-51-4.mol

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HEXARHODIUM HEXADECACARBONYL Property

Melting point:: 238-242°C
Density: 2,87 g/cm³
solubility: Very sparingly soluble in chloroform, carbon tetrachloride and dichloromethane
form: crystal
Specific Gravity: 2.87
color: black
Sensitive: Air Sensitive
Exposure limits: ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 0.1 mg/m3
EPA Substance Registry System: Rhodium, tetra-.mu.3-carbonyldodecacarbonylhexa-, octahedro (28407-51-4)

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Safety

Hazard Codes: Xn
Risk Statements: 20/21/22
Safety Statements: 36/37
RIDADR: 1325
WGK Germany: 3
F: 10
TSCA: Yes
HazardClass: 6.1
PackingGroup: II

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 247650
Product name: Hexarhodium(0) hexadecacarbonyl
Purity: Rh 57-60 % (approx.)
Packaging: 1g
Price: $289.2
Updated: 2024/03/01

Alfa Aesar

Product number: B24185
Product name: Hexarhodium hexadecacarbonyl, 98%
Packaging: 0.1g
Price: $144
Updated: 2023/06/20

Alfa Aesar

Product number: B24185
Product name: Hexarhodium hexadecacarbonyl, 98%
Packaging: 0.5g
Price: $720
Updated: 2023/06/20

Strem Chemicals

Product number: 45-0820
Product name: Hexarhodium hexadecacarbonyl, min. 98%
Packaging: 250mg
Price: $278
Updated: 2024/03/01

Strem Chemicals

Product number: 45-0820
Product name: Hexarhodium hexadecacarbonyl, min. 98%
Packaging: 1g
Price: $828
Updated: 2024/03/01

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HEXARHODIUM HEXADECACARBONYL Chemical Properties,Usage,Production

Chemical Properties

black crystal(s); cluster structure; used as a catalyst [COT88] [ALD94] [ALF95]

Uses

Catalyst for hydrogenation of alkenes, hydroformylations ofalkenes; reducing agent for aldehydes, ketones, and nitro groups; catalyst for carbenoid reactions of diazo compounds

Preparation

Hexadecacarbonylhexarhodium could be prepared from Rhodium(III) Chloride or Pentacarbonyliron and RhCl3.3H2O.

reaction suitability

core: rhodium
reagent type: catalyst

Purification Methods

It slowly loses CO when heated in air, but may be regenerated by heating at 80-200o in the presence of CO at 200atmospheres pressure for 15hours, preferably in the presence of Cu. It forms black crystals which are insoluble in hexane. It has bands at 2073, 2026 and 1800cm-1 in the IR. [Hieber & Lagally Z Anorg Allgem Chem 251 96 1963, Corey & Dahl J Am Chem Soc 85 1202 1963, Doyle et al. Tetrahedron Lett 22 1783 1981.] POISONOUS.

References

1. Booth, B. L.; Else, M. J.; Fields, R.; Goldwhite, H.; Haszeldine, R. N. JOM 1968, 14, 417.
2. Lausarot, P. M.; Vaglio, G. A.: Valle, M. JOM 1981, 204, 249.

HEXARHODIUM HEXADECACARBONYL Preparation Products And Raw materials

Raw materials

Preparation Products

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HEXARHODIUM HEXADECACARBONYL Suppliers

Belgium 1 China 81 Denmark 1 Germany 4 India 3 Japan 2 Switzerland 2 The Netherlands 1 United Kingdom 5 United States 10 Global 110

Aladdin Scientific

Tel: +1-+1(833)-552-7181
Email: sales@aladdinsci.com
Country: United States
ProdList: 52924
Advantage: 58

Alfa Chemistry

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D.F. Goldsmith Chemical & Metal Corporation (DFG)

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MilliporeSigma (Sigma-Aldrich Corp.)

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ProdList: 5414
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Crescent Chemical Company

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ProdList: 1441
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Strem Chemicals, Inc.

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ProdList: 4910
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Riedel-de Haen AG

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Alfa Aesar

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HONEST JOY HOLDINGS LIMITED

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Aithaca Chemical Corp.

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ProdList: 1684
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View Lastest Price from HEXARHODIUM HEXADECACARBONYL manufacturers

Career Henan Chemical Co

Product: Carbon monooxide - rhodium (8:3) 28407-51-4
Price: US $1.00/g
Min. Order: 1g
Purity: Min98%HPLC
Supply Ability: g/kg/ton
Release date: 2020-01-09

28407-51-4, HEXARHODIUM HEXADECACARBONYLRelated Search:

YTTRIUM SCANDIUM Platinum dioxide HEXARHODIUM HEXADECACARBONYL Rhodium TETRARHODIUM DODECACARBONYL

HEXARHODIUM HEXADECACARBONYL

HEXADECACARBONYLHEXARHODIUM

HEXADECACARBONYLHEXARHODIUM (0)

RHODIUM CARBONYL

Rhodium carbonyl (Hexarhodium hexadecacarbonyl)

tetra-mu3-carbonyldodecacarbonyl-octahedro-hexarhodium

HEXARHODIUM(0) HEXADECACARBONYL, 57-60% RH

Hexarhodiumhexadecacarbonyl,min.98%

hexarhodium(0) hexadecacarbonyl

rhodium hexacarbonyl

rhodium(0) carbonyl

Hexarhodium hexadecacarbonyl,98%

Hexadecacarbonylhexa

Hexadecacarbonylhexarhodium, 98+%

Hexarhodium hexadecacarbonyl, min. 98%

Carbon Monoxide rhodiuM

Hexarhodium(0) hexadecacarbonyl Rh 57-60 % (approx.)

Carbon monooxide - rhodium (8:3)

[Rh6(CO)12(μ3-CO)4]

HEXARHODIUM HEXADECACARBONYL ISO 9001：2015 REACH

Di-μ-chlorobis[2-[(dimethylamino)methy]phenyl-C,N]

28407-51-4

Rh6CO16

C16O16Rh6

16CORh6

Catalysis and Inorganic Chemistry

metal carbonyl complexes