2-METHOXY-3-AMINO-4-PICOLINE
- Product Name
- 2-METHOXY-3-AMINO-4-PICOLINE
- CAS No.
- 76005-99-7
- Chemical Name
- 2-METHOXY-3-AMINO-4-PICOLINE
- Synonyms
- 2-METHOXY-3-AMINO-4-PICOLINE;2-Methoxy-4-Methylpyridin-3-aMine;2-Methoxy-4-methyl-3-pyridinamine;2-Methoxy-3-amino-4-methylpyridine;3-PyridinaMine, 2-Methoxy-4-Methyl-;2-Methoxy-4-methyl-pyridin-3-ylamine;2-METHOXY-3-AMINO-4-PICOLINE ISO 9001：2015 REACH
- CBNumber
- CB51076119
- Molecular Formula
- C7H10N2O
- Formula Weight
- 138.17
- MOL File
- 76005-99-7.mol
2-METHOXY-3-AMINO-4-PICOLINE Property
- Boiling point:
- 265℃
- Density
- 1.103
- Flash point:
- 114℃
- storage temp.
- Keep in dark place,Sealed in dry,Store in freezer, under -20°C
- pka
- 4.99±0.18(Predicted)
- Appearance
- Light brown to brown Solid
Safety
- HS Code
- 2933399990
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H317May cause an allergic skin reaction
H319Causes serious eye irritation
- Precautionary statements
-
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- M218958
- Product name
- 2-Methoxy-4-methylpyridin-3-amine
- Packaging
- 100mg
- Price
- $60
- Updated
- 2021/12/16
- Product number
- M218958
- Product name
- 2-Methoxy-4-methylpyridin-3-amine
- Packaging
- 500mg
- Price
- $175
- Updated
- 2021/12/16
- Product number
- FA55650
- Product name
- 3-Amino-2-methoxy-4-methylpyridine
- Packaging
- 500mg
- Price
- $200
- Updated
- 2021/12/16
- Product number
- FA55650
- Product name
- 3-Amino-2-methoxy-4-methylpyridine
- Packaging
- 100mg
- Price
- $90
- Updated
- 2021/12/16
- Product number
- FA55650
- Product name
- 3-Amino-2-methoxy-4-methylpyridine
- Packaging
- 250mg
- Price
- $150
- Updated
- 2021/12/16
2-METHOXY-3-AMINO-4-PICOLINE Chemical Properties,Usage,Production
Synthesis
160590-36-3
76005-99-7
General procedure for the synthesis of 2-methoxy-3-amino-4-methylpyridine from 2-methoxy-3-nitro-4-methylpyridine: 1. a mixture of 4-methyl-2-methoxy-3-nitropyridine (4.5 g, 26.8 mmol), NH4Cl (7.16 g, 133.9 mmol) and iron powder (7.5 g, 133.9 mmol) in ethanol (50 mL) was stirred at 25°C. 2. the mixture was slowly heated to 90 °C and stirred continuously at that temperature for 2 hours. 3. upon completion of the reaction, the reaction mixture was filtered through a diatomaceous earth plug and the diatomaceous earth plug was washed with ethanol (50 mL). 4. The filtrates were combined and evaporated to dryness. 5. The residue was diluted with water (50 mL) and extracted with EtOAc (100 mL). 6. The organic layer was dried over Na2SO4 and evaporated to dryness to afford 2-methoxy-3-amino-4-methylpyridine as a solid (3.5 g, 81% yield). Product characterization: 1H NMR (CDCl3, 400MHz) δ 7.50-7.49 (1H, d, J = 5.2Hz), 6.62-6.61 (1H, d, J = 5.2Hz), 3.97 (3H, s), 3.79-3.69 (2H, br s), 2.15 (3H, s).
References
[1] Patent: US2013/5743, 2013, A1. Location in patent: Page/Page column 12
[2] Patent: WO2013/4617, 2013, A1. Location in patent: Page/Page column 29
[3] Chemical and Pharmaceutical Bulletin, 2008, vol. 56, # 6, p. 775 - 780
2-METHOXY-3-AMINO-4-PICOLINE Preparation Products And Raw materials
Raw materials
Preparation Products
2-METHOXY-3-AMINO-4-PICOLINE Suppliers
- Tel
- 021-31261262/ 49 (0)17662837245
- Fax
- (0)21-33250524
- sales@novochemy.com
- Country
- Germany
- ProdList
- 6328
- Advantage
- 58
View Lastest Price from 2-METHOXY-3-AMINO-4-PICOLINE manufacturers
- Product
- 2-METHOXY-3-AMINO-4-PICOLINE 76005-99-7
- Price
- US $1.10/g
- Min. Order
- 1g
- Purity
- 99.00%
- Supply Ability
- 100 Tons min
- Release date
- 2021-08-31