ChemicalBook > CAS DataBase List > 1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI

1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI

Product Name: 1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI
CAS No.: 10034-20-5
Chemical Name: 1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI
Synonyms: NSC 82044;6-Tetra-O-acetyl-a-D-glucosamineHCI;1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI;1,3,4,4-Tetra-O-acetyl-a-D-glucosamine HCl;1,3,4,6-Tetra-O-acetyl-alpha-D-glucosamine HCl;1,3,4,6-Tetra-O-acetyl-2-aMino-2-deoxy-beta-D-gluc;1,3,4,6-Tetra-O-acetyl-β-D-glucosamine Hydrochloride;2-Amino-2-deoxy-β-D-glucopyranose 1,3,4,6-tetraacetate;1,3,4,6-Tetra-O-acetyl-beta-D-glucosamine hydrochloride;1,3,4,6-Tetra-O-acetyl-2-amino--D-glucopyranose, Hydrochloride
CBNumber: CB51231291
Molecular Formula: C14H21NO9.ClH
Formula Weight: 383.779
MOL File: 10034-20-5.mol

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1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI Property

Melting point:: 197-200°C
RTECS: LZ6574000
storage temp.: Inert atmosphere,2-8°C
solubility: Methanol (Slightly), Water (Slightly)
form: Powder
color: White to Pale Brown
optical activity: [α]/D 30.0±2.0°, c = 1 in H2O
Water Solubility: Soluble in water at 10mg/ml
InChI: InChI=1/C14H21NO9.ClH/c1-6(16)20-5-10-12(21-7(2)17)13(22-8(3)18)11(15)14(24-10)23-9(4)19;/h10-14H,5,15H2,1-4H3;1H/t10-,11-,12-,13-,14-;/s3
InChIKey: BQLUYAHMYOLHBX-GOLNYAHLNA-N
SMILES: [C@@H]1(OC(=O)C)[C@@H](COC(=O)C)O[C@@H](OC(=O)C)[C@H](N)[C@H]1OC(=O)C.Cl |&1:0,5,12,17,19,r|

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Safety

WGK Germany: 3
HS Code: 29329990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 728314
Product name: 1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-β-D-glucopyranose hydrochloride
Purity: ≥98% (HPLC)
Packaging: 1g
Price: $51.5
Updated: 2025/07/31

TCI Chemical

Product number: A3643
Product name: 1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-β-D-glucopyranose Hydrochloride
Packaging: 5G
Price: $159
Updated: 2025/07/31

TCI Chemical

Product number: A3643
Product name: 1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-β-D-glucopyranose Hydrochloride
Packaging: 25G
Price: $477
Updated: 2025/07/31

TRC

Product number: T237500
Product name: 1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-β-D-glucopyranose hydrochloride
Packaging: 2g
Price: $120
Updated: 2021/12/16

TRC

Product number: T237500
Product name: 1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-β-D-glucopyranose hydrochloride
Packaging: 5g
Price: $240
Updated: 2021/12/16

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1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI Chemical Properties,Usage,Production

Chemical Properties

White Solid

Uses

A potential metabolic inhibitor of cellular-membrane glycoconjugates.

Synthesis

7597-81-1

5432-46-2

Triester of (2S,3R,4R,5S,6R)-6-(acetyloxymethyl)-3-(((E)-4-methoxybenzylidene)amino)tetrahydro-2H-pyran-2,4,5-triacetate (4.0 g, 8.6 mmol) was used as a raw material and dissolved in preheated acetone (36 mL). Subsequently, 5 M HCl (2 mL) was slowly added to the solution and precipitation was observed. After cooling the reaction mixture to room temperature, ether (36 mL) was added and stirred continuously for 2 hours. The precipitate was collected by filtration, washed with ether and dried under reduced pressure to afford 1,3,4,6-tetra-O-acetyl-2-amino-2-deoxy-D-glucopyranose hydrochloride (2.9 g, 79%) as a white solid. The melting point of the product is 205°C (literature value: 231-233°C, ignition [49], melting point 235°C); specific optical rotation [α] 20D +36.6 (c 1.0, MeOH), literature value [49] +32 (H2O); infrared (IR) spectra (νmax 2939 cm?1 (broad peak, NH3Cl), 1751 cm?1 (C=O); 1H-NMR (DMSO-d6, 300 MHz) δ 1.95 (6H, s, CH3CO), 2.00 (3H, s, CH3CO), 2.14 (3H, s, CH3CO), 3.52 (1H, t, J = 9.7 Hz, H-2), 3.98 (2H, m, H-6, H-5), 4.15 (1H, dd, J = 12.3, 4.1 Hz, H-6), 4.87 (1H, t, J = 9.8 Hz, H-4), 5.28 (1H, t, J = 9.8 Hz, H-3), 5.84 (1H, d, J = 8.8 Hz, H-1), 8.26 (3H, s, NH3Cl).

References

[1] Journal of Organic Chemistry, 1999, vol. 64, # 16, p. 5926 - 5929
[2] Journal of the American Chemical Society, 2018, vol. 140, # 8, p. 3120 - 3127
[3] Carbohydrate Research, 2010, vol. 345, # 11, p. 1541 - 1547
[4] Advanced Synthesis and Catalysis, 2010, vol. 352, # 14-15, p. 2657 - 2662
[5] RSC Advances, 2014, vol. 4, # 12, p. 6239 - 6245

1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI manufacturers

Career Henan Chemical Co

Product: 1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI 10034-20-5
Price: US $8.66/KG
Min. Order: 1KG
Purity: 95.0%-99.0%
Supply Ability: 1kg-100kg
Release date: 2020-03-11

10034-20-5, 1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCIRelated Search:

ACETOBROMO-ALPHA-D-GLUCURONIC ACID METHYL ESTER 2,3,4,6-TETRA-O-ACETYL-ALPHA-D-GLUCOPYRANOSYL FLUORIDE 2,3,4,6-Tetraacetyl-D-glucose METHYL 4,6-O-BENZYLIDENE-ALPHA-D-GLUCOPYRANOSIDE 3,4,6-TRI-O-ACETYL-2-AZIDO-2-DEOXY-D-GALACTOSE 1,3,4,6-TETRA-O-ACETYL-2-AZIDO-2-DEOXY-BETA-D-GLUCOPYRANOSE 1-O-ACETYL-2,3,5-TRI-O-BENZOYL-D-RIBOFURANOSE 1-(2,2,2-Trifluoro-N-phenylethaniMidate)-D-glucopyranuronic Acid Methyl Ester 2,3,4-Triacetate 4-NITROPHENYL-BETA-D-GLUCURONIC ACID, SODIUM SALT L-GLUCOSE D-Glucosamine hydrochloride 1,3,4,6-TETRA-O-ACETYL-2-AMINO-2-DESOXY-BETA-D-GLUCOPYRANOSE HYDROCHLORIDE 1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI

1,3,4,6-Tetra-O-acetyl-a-D-glucosamineHCI

1,3,4,6-Tetra-O-acetyl-2-amino--D-glucopyranose, Hydrochloride

2-Amino-2-deoxy-1,3,4,6-tetra-O-acetyl--D-glucopyranose Hydrochloride

NSC 82044

1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-β-D-glucopyranose hydrochloride ,98%

1,3,4,6-Tetra-O-acetyl-beta-D-glucosamine hydrochloride

1,3,4,6-Tetra-O-acetyl-2-aMino-2-deoxy-beta-D-gluc

1,3,4,6-Tetra-o-acetyl-2-aMino-2-deoxy-beta-d-glucopyranose, HCl

b-D-Glucopyranose, 2-aMino-2-deoxy-, 1,3,4,6-tetraacetate, hydrochloride

1,3,4,6-Tetra-O-acetyl-2-aMino-2-deoxy-b-D-glucopyranose Hydrochloride

1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-beta-D-glucopyranose hydrochloride min. 99%

1,3,4,6-Tetra-O-acetyl-beta-D-glucosamine hydrochloride, beta-D-Glucosamine tetraacetate HCl, NSC 82044

(2S,3R,4R,5S,6R)-6-(Acetoxymethyl)-3-aminotetrahydro-2H-pyran-2,4,5-triyl triacetate hydrochloride

2-Amino-2-deoxy-β-D-glucopyranose 1,3,4,6-tetraacetate

1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-beta-D-glucopyranosehydrochloride98%

2-Amino-2-deoxy-1,3,4,6-tetra-O-acetyl-beta,D-glucopyranose hydrochloride

1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-beta-D-glucopyranose hydrochloride 98%

1,3,4,6-Tetra-O-acetyl-β-D-glucosamine Hydrochloride

1,3,4,6-Tetra-O-acetyl-2-amino-2-deoxy-β-D-glucopyranose Hydrochloride

β-D-Glucopyranose, 2-amino-2-deoxy-, 1,3,4,6-tetraacetate, hydrochloride (1:1)

1,3,4,4-Tetra-O-acetyl-a-D-glucosamine HCl

6-Tetra-O-acetyl-a-D-glucosamineHCI

2-amino-2-deoxy-β-D-glucopyranose 1,3,4,6-tetraacetate hydrochloride

1,3,4,6-Tetra-O-acetyl-alpha-D-glucosamine HCl

b-D-Glucopyranose,2-amino-2-deoxy-, 1,3,4,6-tetraacetate, hydrochloride (1:1)

1,3,4,6-Tetra-<i>O</i>-acetyl-2-amino-2-deoxy-β-<sc>D</sc>-glucopyranose hydrochloride

1,3,4,6-Tetra-O-acetyl-2-amino-2-desoxy-β-D-glucopyranose (hydrochloride)

1,3,4,6-Tetra-O-acetyl-2-amino-2-desoxy-∫-D-glucopyranose hydrochloride, CAS 10034-20-5

10034-20-5

Carbohydrates & Derivatives

Amines

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