2-BROMO-5-IODOANISOLE
- Product Name
- 2-BROMO-5-IODOANISOLE
- CAS No.
- 755027-18-0
- Chemical Name
- 2-BROMO-5-IODOANISOLE
- Synonyms
- 2-BROMO-5-IODOANISOLE;2-Bromo-5-iodoanisole 98%;2-bromo-5-iodophenyl ether;2-iodine-5-bromophenyl ether;2-BroMo-5-iodophenyl Methyl ether;Benzene, 1-broMo-4-iodo-2-Methoxy-;1-Bromo-4-iodo-2-methoxybenzene, 2-Bromo-5-iodophenyl methyl ether
- CBNumber
- CB5125368
- Molecular Formula
- C7H6BrIO
- Formula Weight
- 312.93
- MOL File
- 755027-18-0.mol
2-BROMO-5-IODOANISOLE Property
- Boiling point:
- 293.7±20.0 °C(Predicted)
- Density
- 2.062
- storage temp.
- Keep in dark place,Sealed in dry,2-8°C
- form
- crystalline needles
- color
- Faint yellow
Safety
- Hazard Codes
- Xi
- Hazard Note
- Irritant
- HS Code
- 2909309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
N-Bromosuccinimide Price
- Product number
- B688943
- Product name
- 1-Bromo-4-iodo-2-methoxybenzene
- Packaging
- 500mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- 062593
- Product name
- 2-Bromo-5-iodoanisole
- Packaging
- 250mg
- Price
- $9
- Updated
- 2021/12/16
- Product number
- 062593
- Product name
- 2-Bromo-5-iodoanisole
- Packaging
- 1g
- Price
- $10
- Updated
- 2021/12/16
- Product number
- J91545
- Product name
- 2-Bromo-5-iodoanisole
- Packaging
- 1g
- Price
- $10
- Updated
- 2021/12/16
- Product number
- OR9601
- Product name
- 2-Bromo-5-iodoanisole
- Purity
- 97%
- Packaging
- 1g
- Price
- $15
- Updated
- 2021/12/16
2-BROMO-5-IODOANISOLE Chemical Properties,Usage,Production
Synthesis
19056-40-7
755027-18-0
4-Bromo-3-methoxyaniline (102 mg, 0.50 mmol) was used as starting material and dissolved in concentrated hydrochloric acid (10 mL) at 0 °C. Subsequently, an aqueous solution of sodium nitrite (NaNO2, 45 mg, 0.65 mmol) (5 mL) was slowly added, the reaction temperature was maintained at 0 °C and the reaction was stirred for 1 hour. Next, an aqueous solution of potassium iodide (KI, 249 mg, 1.5 mmol) (5 mL) was added, and the reaction mixture was gradually warmed to room temperature and stirred overnight. After completion of the reaction, the product was extracted with ethyl acetate. The organic phase was washed sequentially with water and 10% sodium thiosulfate (Na2S2O3) solution, dried over anhydrous magnesium sulfate (MgSO4), filtered and concentrated to give 147 mg of 2-bromo-5-iodoanisole in 94% yield. The product was analyzed by mass spectrometry (ESI), m/e 332 (M + 20)+; nuclear magnetic resonance hydrogen spectrum (1H NMR, 300 MHz, DMSO-d6) δ 7.39 (d, J = 1.87 Hz, 1H), 7.34 (d, J = 8.11 Hz, 1H), 7.24 (dd, J = 8.11, 1.87 Hz, 1H), 3.86 (s 3H).
References
[1] European Journal of Organic Chemistry, 2018, vol. 2018, # 38, p. 5312 - 5322
[2] Patent: WO2004/76424, 2004, A1. Location in patent: Page 79
[3] Journal of the American Chemical Society, 2018,
[4] Patent: WO2007/37187, 2007, A1. Location in patent: Page/Page column 127-128
[5] Patent: WO2008/57208, 2008, A2. Location in patent: Page/Page column 50
2-BROMO-5-IODOANISOLE Preparation Products And Raw materials
Raw materials
Preparation Products
2-BROMO-5-IODOANISOLE Suppliers
- Tel
- --
- Fax
- --
- sales@ajchem.in
- Country
- India
- ProdList
- 6100
- Advantage
- 58
View Lastest Price from 2-BROMO-5-IODOANISOLE manufacturers
- Product
- 2-BROMO-5-IODOANISOLE 755027-18-0
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-11