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VANADIUM(IV) FLUORIDE

Product Name
VANADIUM(IV) FLUORIDE
CAS No.
10049-16-8
Chemical Name
VANADIUM(IV) FLUORIDE
Synonyms
VANADIUM FLUORIDE;VANADIUM(IV) FLUORIDE;VANADIUM TETRAFLUORIDE;Vanadium(IV)fluoride95%;Vanadium(IV) fluoride 95%;Vanadium(IV) fluoride,98%;Vanadium(IV) tetrafluoride;VanadiuM (IV) Fluoride, -100 Mesh;Vanadium fluoride (VF4)(7CI,8CI,9CI)
CBNumber
CB5128031
Molecular Formula
F4V
Formula Weight
126.94
MOL File
10049-16-8.mol
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VANADIUM(IV) FLUORIDE Property

Melting point:
325 °C (dec.)(lit.)
Density 
2.975 g/mL at 25 °C(lit.)
solubility 
very soluble in H2O
form 
Powder
Specific Gravity
3.15
color 
Yellow to brown
Water Solubility 
Soluble in water (blue color), acetone (deep green color), and glacial acetic acid (blue-green color)
Sensitive 
Moisture Sensitive
crystal system
Monoclinic
Space group
P21/n
Lattice constant
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.5380.5170.5349059.7900.1283
Exposure limits
ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3; Ceiling 0.05 mg/m3
CAS DataBase Reference
10049-16-8(CAS DataBase Reference)
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Safety

Hazard Codes 
T,Xi
Risk Statements 
23/24/25-34
Safety Statements 
22-26-36/37/39-45
RIDADR 
UN 3290 6.1/PG 2
WGK Germany 
3
Hazard Note 
Irritant
HazardClass 
8
PackingGroup 
II
HS Code 
2826199090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

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N-Bromosuccinimide Price

TRC
Product number
V963638
Product name
Vanadium(IV) fluoride
Packaging
250mg
Price
$45
Updated
2021/12/16
SynQuest Laboratories
Product number
M023-2-02
Product name
Vanadium(IV) fluoride
Purity
95%
Packaging
10g
Price
$35
Updated
2021/12/16
Apolloscientific
Product number
PC7980
Product name
Vanadium(IV) fluoride
Purity
95%
Packaging
100g
Price
$439
Updated
2021/12/16
SynQuest Laboratories
Product number
M023-2-02
Product name
Vanadium(IV) fluoride
Purity
95%
Packaging
25g
Price
$65
Updated
2021/12/16
SynQuest Laboratories
Product number
M023-2-02
Product name
Vanadium(IV) fluoride
Purity
95%
Packaging
100g
Price
$195
Updated
2021/12/16
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VANADIUM(IV) FLUORIDE Chemical Properties,Usage,Production

Chemical Properties

green to brown powder

Uses

Vanadium(IV) fluoride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.

Production Methods

Freshly distilled, Dry Ice-cooled VCl4 (40 g) is added to 130 g of similarly cooled anhydrous HF contained in a reactor. A copper reflux condenser charged with a cooling mixture is then attached to the vessel, and the reaction mixture is allowed to warm slowly to 0°C. The mixture is then boiled for several hours until no further HCl evolves. The reflux condenser is then replaced by a descending condenser, and the HF is distilled off. The VF4 remaining in the reactor is freed of any traces of HF by passing a dry stream of nitrogen at 50°C. The yield is 97%, based on VCl4. The product may be stored in sealed iron or copper containers.

VANADIUM(IV) FLUORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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VANADIUM(IV) FLUORIDE Suppliers

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10049-16-8, VANADIUM(IV) FLUORIDERelated Search:


  • VANADIUM FLUORIDE
  • VANADIUM(IV) FLUORIDE
  • VANADIUM TETRAFLUORIDE
  • Vanadium(IV) fluoride 95%
  • Vanadium(IV)fluoride95%
  • Vanadium(IV) tetrafluoride
  • Vanadium(IV) fluoride,98%
  • VanadiuM (IV) Fluoride, -100 Mesh
  • Vanadium fluoride (VF4)(7CI,8CI,9CI)
  • 10049-16-8
  • 4FV
  • VF4
  • F4V