VANADIUM(IV) FLUORIDE
- Product Name
- VANADIUM(IV) FLUORIDE
- CAS No.
- 10049-16-8
- Chemical Name
- VANADIUM(IV) FLUORIDE
- Synonyms
- VANADIUM FLUORIDE;VANADIUM(IV) FLUORIDE;VANADIUM TETRAFLUORIDE;Vanadium(IV)fluoride95%;Vanadium(IV) fluoride 95%;Vanadium(IV) fluoride,98%;Vanadium(IV) tetrafluoride;VanadiuM (IV) Fluoride, -100 Mesh;Vanadium fluoride (VF4)(7CI,8CI,9CI)
- CBNumber
- CB5128031
- Molecular Formula
- F4V
- Formula Weight
- 126.94
- MOL File
- 10049-16-8.mol
VANADIUM(IV) FLUORIDE Property
- Melting point:
- 325 °C (dec.)(lit.)
- Density
- 2.975 g/mL at 25 °C(lit.)
- solubility
- very soluble in H2O
- form
- Powder
- Specific Gravity
- 3.15
- color
- Yellow to brown
- Water Solubility
- Soluble in water (blue color), acetone (deep green color), and glacial acetic acid (blue-green color)
- Sensitive
- Moisture Sensitive
- crystal system
- Monoclinic
- Space group
- P21/n
- Lattice constant
a/nm b/nm c/nm α/o β/o γ/o V/nm3 0.538 0.517 0.534 90 59.7 90 0.1283 - Exposure limits
- ACGIH: TWA 2.5 mg/m3
NIOSH: IDLH 250 mg/m3; TWA 2.5 mg/m3; Ceiling 0.05 mg/m3 - CAS DataBase Reference
- 10049-16-8(CAS DataBase Reference)
Safety
- Hazard Codes
- T,Xi
- Risk Statements
- 23/24/25-34
- Safety Statements
- 22-26-36/37/39-45
- RIDADR
- UN 3290 6.1/PG 2
- WGK Germany
- 3
- Hazard Note
- Irritant
- HazardClass
- 8
- PackingGroup
- II
- HS Code
- 2826199090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P271Use only outdoors or in a well-ventilated area.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P312Call a POISON CENTER or doctor/physician if you feel unwell.
N-Bromosuccinimide Price
- Product number
- 011543
- Product name
- Vanadium(IV) fluoride
- Purity
- 95%
- Packaging
- 5g
- Price
- $48.65
- Updated
- 2024/03/01
- Product number
- 011543
- Product name
- Vanadium(IV) fluoride
- Purity
- 95%
- Packaging
- 25g
- Price
- $214.2
- Updated
- 2023/01/06
- Product number
- V963638
- Product name
- Vanadium(IV) fluoride
- Packaging
- 250mg
- Price
- $45
- Updated
- 2021/12/16
- Product number
- M023-2-02
- Product name
- Vanadium(IV) fluoride
- Purity
- 95%
- Packaging
- 10g
- Price
- $35
- Updated
- 2021/12/16
- Product number
- M023-2-02
- Product name
- Vanadium(IV) fluoride
- Purity
- 95%
- Packaging
- 25g
- Price
- $65
- Updated
- 2021/12/16
VANADIUM(IV) FLUORIDE Chemical Properties,Usage,Production
Chemical Properties
green to brown powder
Uses
Vanadium(IV) fluoride is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals.
Production Methods
Freshly distilled, Dry Ice-cooled VCl4 (40 g) is added to 130 g of similarly cooled anhydrous HF contained in a reactor. A copper reflux condenser charged with a cooling mixture is then attached to the vessel, and the reaction mixture is allowed to warm slowly to 0°C. The mixture is then boiled for several hours until no further HCl evolves. The reflux condenser is then replaced by a descending condenser, and the HF is distilled off. The VF4 remaining in the reactor is freed of any traces of HF by passing a dry stream of nitrogen at 50°C. The yield is 97%, based on VCl4. The product may be stored in sealed iron or copper containers.
VANADIUM(IV) FLUORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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