ZIRCONIUM IODIDE
- Product Name
- ZIRCONIUM IODIDE
- CAS No.
- 13986-26-0
- Chemical Name
- ZIRCONIUM IODIDE
- Synonyms
- ZrI4;ZIRCONIUM IODIDE;Einecs 237-780-9;ZIRCONIUM(IV) IODIDE;ZIRCONIUM TETRAIODIDE;zirconiumiodide(zri4);Zirconium iodide (ZrI4);Zirconium(IV) tetraiodide;zirconium(4+),tetraiodide;ZIRCONIUM(IV) IODIDE: 99.5%
- CBNumber
- CB5134410
- Molecular Formula
- I4Zr
- Formula Weight
- 598.84
- MOL File
- 13986-26-0.mol
ZIRCONIUM IODIDE Property
- Melting point:
- 499°C
- Boiling point:
- 431°C (estimate)
- Density
- 4.85
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- solubility
- very soluble in H2O
- form
- powder
- color
- Yellow
- Specific Gravity
- 4.914
- Water Solubility
- Insoluble in water.
- Sensitive
- Air & Moisture Sensitive
- Hydrolytic Sensitivity
- 7: reacts slowly with moisture/water
- Merck
- 14,10178
- Exposure limits
- ACGIH: TWA 5 mg/m3; STEL 10 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 - CAS DataBase Reference
- 13986-26-0(CAS DataBase Reference)
- EPA Substance Registry System
- Zirconium iodide (ZrI4) (13986-26-0)
Safety
- Hazard Codes
- C
- Risk Statements
- 34
- Safety Statements
- 22-26-27-36/37/39-45
- RIDADR
- UN 3260 8/PG 2
- WGK Germany
- 3
- TSCA
- No
- HazardClass
- 8
- PackingGroup
- III
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P260Do not breathe dust/fume/gas/mist/vapours/spray.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P363Wash contaminated clothing before reuse.
N-Bromosuccinimide Price
- Product number
- 017400
- Product name
- Zirconium(IV) iodide
- Purity
- 99%
- Packaging
- 25g
- Price
- $615
- Updated
- 2023/06/20
- Product number
- 93-4025
- Product name
- Zirconium(IV) iodide (99.5%-Zr)
- Packaging
- 1g
- Price
- $68
- Updated
- 2024/03/01
- Product number
- 93-4025
- Product name
- Zirconium(IV) iodide (99.5%-Zr)
- Packaging
- 5g
- Price
- $178
- Updated
- 2024/03/01
- Product number
- ING0007364
- Product name
- ZIRCONIUM(IV) IODIDE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $673.68
- Updated
- 2021/12/16
- Product number
- ING0007364
- Product name
- ZIRCONIUM(IV) IODIDE
- Purity
- 95.00%
- Packaging
- 5G
- Price
- $957.46
- Updated
- 2021/12/16
ZIRCONIUM IODIDE Chemical Properties,Usage,Production
Description
Zirconium(IV) iodide, ZrI4, is the most readily available iodide of zirconium. It is an orange-colored solid that degrades in the presence of water. The compound was once renowned as an intermediate in the purification of zirconium metal. This compound is volatile, subliming as intact tetrahedral ZrI4 molecules.
Chemical Properties
orange crystal(s); fumes heavily in air; cub, a=1.179nm [KIR84] [MER06]
Uses
Used in the van Arkel-de Boer refining process.
Preparation
It is prepared by the direct reaction of powdered zirconium metal and iodine. Pyrolysis of zirconium(IV) iodide gas by contact of hot wire was the first industrial process for the commercial production of pure ductile metallic zirconium.
Structure and conformation
Like most binary metal halides, it has a polymeric structure. The compound exists as a polymer consisting of octahedral Zr(IV) centers, each with a pair of terminal iodide ligands and four doubly bridging iodide ligands. The Zr-I distances are 2.692 (terminal) and 3.030 A? .
ZIRCONIUM IODIDE Preparation Products And Raw materials
Raw materials
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