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Titanium ethoxide

Product Name
Titanium ethoxide
CAS No.
3087-36-3
Chemical Name
Titanium ethoxide
Synonyms
TITANIUM(IV) ETHOXIDE;TITANIUM TETRAETHOXIDE;Tetraethoxy titanium;TETRAETHYL TITANATE;ETHYL ORTHOTITANATE;TETRAETHYL ORTHOTITANATE;TitaniuM tetraethanolate;VERTEC(TM) ET;ETHYL TITANATE;TITANIUM ETHOXIDE
CBNumber
CB5152902
Molecular Formula
C8H20O4Ti
Formula Weight
228.11
MOL File
3087-36-3.mol
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Titanium ethoxide Property

Melting point:
54°C
Boiling point:
150-152 °C10 mm Hg(lit.)
Density 
1.088 g/mL at 25 °C(lit.)
vapor pressure 
57.26hPa at 19.6℃
refractive index 
n20/D 1.505(lit.)
Flash point:
84 °F
storage temp. 
2-8°C
solubility 
Soluble in organic solvents.
form 
Liquid
Specific Gravity
1.107 (20℃)
color 
Pale yellow
Water Solubility 
reacts
Sensitive 
Moisture Sensitive
BRN 
3678992
Exposure limits
ACGIH: TWA 200 ppm; STEL 400 ppm
OSHA: TWA 400 ppm(980 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 400 ppm(980 mg/m3); STEL 500 ppm(1225 mg/m3)
Stability:
Stability Incompatible with strong oxidizing agents, strong acids. May decompose upon exposure to air or moisture.
InChIKey
JMXKSZRRTHPKDL-UHFFFAOYSA-N
LogP
-0.3 at 25℃
CAS DataBase Reference
3087-36-3(CAS DataBase Reference)
NIST Chemistry Reference
Ti(OEt)4(3087-36-3)
EPA Substance Registry System
Ethanol, titanium(4+) salt (3087-36-3)
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Safety

Hazard Codes 
Xi
Risk Statements 
10-36/37/38-67
Safety Statements 
26-37/39-16
RIDADR 
UN 1993 3/PG 3
WGK Germany 
3
F 
3-10-21
TSCA 
Yes
HazardClass 
4.1
PackingGroup 
III
HS Code 
29051900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H226Flammable liquid and vapour

H319Causes serious eye irritation

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.21083
Product name
Tetraethyl orthotitanate
Purity
for synthesis
Packaging
250ML
Price
$111
Updated
2024/03/01
Sigma-Aldrich
Product number
8.21083
Product name
Tetraethyl orthotitanate
Purity
for synthesis
Packaging
1L
Price
$237
Updated
2024/03/01
Sigma-Aldrich
Product number
244759
Product name
Titanium(IV) ethoxide
Purity
technical grade
Packaging
50g
Price
$92.3
Updated
2024/03/01
Sigma-Aldrich
Product number
244759
Product name
Titanium(IV) ethoxide
Purity
technical grade
Packaging
250g
Price
$329
Updated
2024/03/01
TCI Chemical
Product number
T0967
Product name
Tetraethyl Orthotitanate
Packaging
25mL
Price
$21
Updated
2024/03/01
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Titanium ethoxide Chemical Properties,Usage,Production

Chemical Properties

colourless liquid

Uses

Titanium(IV) ethoxide is used in organic synthesis and material science. It is involved in the synthesis of anti-perspirants and antifungal agents. Furthermore, it is used to prepare carbon films in association with silicon dioxide. It is also used as a precursor for the synthesis of Ti4+ ions titanium nanoparticles by various methods.

Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :

  • in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
  • spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
  • by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Uses

Titanium(IV) ethoxide can be used:

  • As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
  • As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
  • As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Application

Titanium(IV) ethoxide can be used:
As an activator and dehydrating agent for by condensation of (S)-(+)-p-toluenesulfinamide with aldehydes and ketones to form sulfinimines.
As a Ti4+ ion source to form complexes of titanium (IV) acrylate with methacrylic acid.
As a catalyst to synthesize esters of sterically hindered alcohols via transesterification reactions.

Flammability and Explosibility

Flammable

Materials Uses

Titanium ethoxide is used widely as a precursor for the synthesis of Ti4+ ions titania nanoparticles by various techniques such as :
in the sol-gel synthesis of free-standing ferroelectric lead zirconate titanate nanoparticles
spherical titania cores, produced either by hydrolysis of Ti(IV) ethoxide droplets in contact with water vapor or
by preadsorption of the titanium alkoxides into/onto the clay mineral platelets and their subsequent hydrolysis and calcination.

Titanium ethoxide Preparation Products And Raw materials

Raw materials

(S)-tert-Butyl 6-amino-2-((tert-butoxycarbonyl)amino)hexanoate hydrochloride Glass-lined reaction pot

Preparation Products

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Titanium ethoxide Suppliers

Belgium 1 China 183 Europe 1 France 1 Germany 6 India 9 Japan 6 Singapore 1 Switzerland 1 United Kingdom 4 United States 31 Global 244
Nanjing Runiver Technology Co.,Ltd.
Tel
0550-7041128 18014470519
Fax
025-52215598
Email
tcchem@tcchem.com
Country
China
ProdList
17
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55
Shanghai Guoyuan Chemical Co., Ltd.
Tel
0512-55170668 13913095008
Fax
0512-55170668
Email
shgyhg@139.com
Country
China
ProdList
585
Advantage
58
SHANGHAI BANGCHENG CHEMICAL Co.,Ltd.
Tel
021-69106960 13701823733
Fax
021-69106780
Email
13701823733@163.com
Country
China
ProdList
4775
Advantage
60
Jiaxing Deyi Chemical Co., Ltd.
Tel
86-0573-85866609 13325730825
Fax
0573-85866609
Email
945717149@qq.com
Country
China
ProdList
7936
Advantage
58
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
4006608290; 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40241
Advantage
62
Alfa Aesar
Tel
400-6106006
Fax
021-67582001/03/05
Email
saleschina@alfa-asia.com
Country
China
ProdList
30132
Advantage
84
TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
ProdList
24539
Advantage
81
Beijing dtftchem Technology Co., Ltd.
Tel
010-60275820 13031183356
Fax
010-60270825
Email
elainezt@sina.com
Country
China
ProdList
1392
Advantage
62
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44751
Advantage
61
Beijing Ouhe Technology Co., Ltd
Tel
010-82967028 13552068683
Fax
+86-10-82967029
Email
2355560935@qq.com
Country
China
ProdList
12426
Advantage
60
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View Lastest Price from Titanium ethoxide manufacturers

Speranza Chemical Co., Ltd.
Product
Titanium(IV) ethoxide,TiO2 33.2% 3087-36-3
Price
US $20.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
300 Tons/ year
Release date
2019-12-25
Shandong Luning Pharmaceutical Co., Ltd.
Product
Titanium(IV) ethoxide 3087-36-3
Price
US $15.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
6000KG
Release date
2020-11-09
Hebei Yanxi Chemical Co., Ltd.
Product
Titanium ethoxide 3087-36-3
Price
US $30.00-1.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-09-15

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