3-azabicyclo[3.1.0]hexane
- Product Name
- 3-azabicyclo[3.1.0]hexane
- CAS No.
- 285-59-6
- Chemical Name
- 3-azabicyclo[3.1.0]hexane
- Synonyms
- UKRORGSYN-BB BBV-265866;3-azabicyclo[3.1.0]hexane;3-Azabicyclo[3.1.0]hexane (8CI, 9CI, ACI)
- CBNumber
- CB51562340
- Molecular Formula
- C5H9N
- Formula Weight
- 83.13
- MOL File
- 285-59-6.mol
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H320Causes eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P330Rinse mouth.
N-Bromosuccinimide Price
- Product number
- A965770
- Product name
- 3-Azabicyclo[3.1.0]hexane
- Packaging
- 50mg
- Price
- $130
- Updated
- 2021/12/16
- Product number
- A965770
- Product name
- 3-Azabicyclo[3.1.0]hexane
- Packaging
- 100mg
- Price
- $200
- Updated
- 2021/12/16
- Product number
- CHM0110640
- Product name
- 3-AZABICYCLO[3.1.0]HEXANE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $1216.37
- Updated
- 2021/12/16
- Product number
- 123669
- Product name
- 3-Azabicyclo[3.1.0]hexane
- Purity
- 95+%
- Packaging
- 1g
- Price
- $1552
- Updated
- 2021/12/16
- Product number
- CHM0110640
- Product name
- 3-AZABICYCLO[3.1.0]HEXANE
- Purity
- 95.00%
- Packaging
- 2.5G
- Price
- $1906.96
- Updated
- 2021/12/16
3-azabicyclo[3.1.0]hexane Chemical Properties,Usage,Production
Uses
3-Azabicyclo[3.1.0]hexane is a key structural feature found in a wide range of biologically active natural products, drugs, and agrochemicals.
Synthesis
3-azabicyclo[3.1.0]hexane synthesis: 1-Chlorocyclopropyl p-tolyl sulfoxides with an N,N-disubstituted aminomethyl group on the cyclopropane ring were prepared from dichloromethyl p-tolyl sulfoxide, α,β-unsaturated carboxylic acid esters, primary amines, and alkyl halides. Treatment of the sulfoxides with i-PrMgCl generated cyclopropylmagnesium carbenoids, which were inserted into an intramolecular C–H bond adjacent to a nitrogen atom to give 3-azabicyclo[3.1.0]hexane in yields of up to 94%.
3-azabicyclo[3.1.0]hexane Preparation Products And Raw materials
Raw materials
Preparation Products
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