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CITRACONIC ACID DIMETHYL ESTER

Product Name
CITRACONIC ACID DIMETHYL ESTER
CAS No.
617-54-9
Chemical Name
CITRACONIC ACID DIMETHYL ESTER
Synonyms
C05126;DIMETHYL CITRACONATE;dimethylmethylmaleate;Dimethyl methyl maleate;Citraconate de dimethyle;Dimethyl Citraconate >dimethyl 2-methylmaleate;(2Z)-Dimethyl 2-methylmaleate;methylmaleicacid,dimethylester;CITRACONIC ACID DIMETHYL ESTER
CBNumber
CB5179806
Molecular Formula
C7H10O4
Formula Weight
158.15
MOL File
617-54-9.mol
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CITRACONIC ACID DIMETHYL ESTER Property

Boiling point:
211 °C
Density 
1,11 g/cm3
refractive index 
1.4460-1.4490
storage temp. 
Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Oil
color 
Clear Colourless
LogP
0.849 (est)
EPA Substance Registry System
2-Butenedioic acid, 2-methyl-, dimethyl ester, (2Z)- (617-54-9)
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36
RTECS 
GE6700000
HS Code 
2917198090
Toxicity
Both the acute oral LD50 value in rats and the acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1974).
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
C0364
Product name
Dimethyl Citraconate
Purity
>99.0%(GC)
Packaging
5g
Price
$85
Updated
2024/03/01
TCI Chemical
Product number
C0364
Product name
Dimethyl Citraconate
Purity
>99.0%(GC)
Packaging
25g
Price
$224
Updated
2024/03/01
TRC
Product number
D471950
Product name
Dimethyl Citraconate
Packaging
100mg
Price
$150
Updated
2021/12/16
AK Scientific
Product number
J57352
Product name
Citraconicaciddimethylester
Packaging
1g
Price
$29
Updated
2021/12/16
AK Scientific
Product number
J57352
Product name
Citraconicaciddimethylester
Packaging
5g
Price
$84
Updated
2021/12/16
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CITRACONIC ACID DIMETHYL ESTER Chemical Properties,Usage,Production

Occurrence

Has apparently not been reported to occur in nature.

Uses

Dimethyl Citraconate is a useful synthetic intermediate. It has been used in the synthesis of natural products chaetomellic acid A anhydride and 1,7(Z)- nonadecadiene-2,3-dicarboxylic acid. It is also used to prepare acyclic alkanes by reduction using homogeneous catalysts or biocatalysts.

Preparation

By the reaction of methanol with citraconic anhydride in the presence of a catalyst.

Synthesis Reference(s)

Journal of the American Chemical Society, 94, p. 9269, 1972 DOI: 10.1021/ja00781a071

CITRACONIC ACID DIMETHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

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CITRACONIC ACID DIMETHYL ESTER Suppliers

Americas 1 China 53 Europe 1 Germany 2 India 2 Japan 1 United Kingdom 2 United States 6 USA 1 Global 69
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
52925
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58
Penta International Corporation
Tel
--
Fax
--
Email
lisaa@pentamfg.com
Country
United States
ProdList
5042
Advantage
58
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
AccuStandard Inc
Tel
--
Fax
--
Email
info@bester.nl
Country
United States
ProdList
5300
Advantage
76
Penta Manufacturing Company
Tel
--
Fax
--
Email
sales@pentamfg.com
Country
United States
ProdList
5076
Advantage
65
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47

617-54-9, CITRACONIC ACID DIMETHYL ESTERRelated Search:

Dimethyl sulfate CITRACONIC ACID DIMETHYL ESTER Citraconic acid TETRAETHYL ETHYLENETETRACARBOXYLATE 2-HYDROXY-5-OXO-2,5-DIHYDRO-FURAN-3,4-DICARBOXYLIC ACID DIMETHYL ESTER DIETHYL DICYANOFUMARATE, 97 TRIALLYL ACONITATE TRIETHYL ACONITATE TRANS-ACONITIC ACID TRIMETHYL ESTER ETHYL 7-HYDROXYCOUMARIN-4-CARBOXYLATE TETRAMETHYL (1Z,3Z)-1-{[4-(ETHOXYCARBONYL)-1,2,3-THIADIAZOL-5-YL]AMINO}BUTA-1,3-DIENE-1,2,3,4-TETRACARBOXYLATE TRIETHYL 1,1,2-ETHYLENETRICARBOXYLATE RARECHEM AL BI 1458 3-HYDROXY-2-OXO-5,6,7,8-TETRAHYDRO-2H-PYRANO[3,2-B]PYRIDINE-4-CARBOXYLIC ACID ETHYL ESTER RARECHEM AL BF 1458 1-Propene-1,2,3-tricarboxylic acid, trihexyl ester 2-(TERT-BUTYL) 1,1-DIETHYL 1,1,2-ETHYLENETRICARBOXYLATE (1Z,3Z)-TETRAMETHYL 1-(4-CARBAMOYL-1,2,3-THIADIAZOL-5-YLAMINO)BUTA-1,3-DIENE-1,2,3,4-TETRACARBOXYLATE

  • 2-Butenedioic acid, 2-methyl-, dimethyl ester (Z)-
  • 2-methyl-,dimethylester,(z)-2-butenedioicaci
  • 2-Methyl-but-2-enedioic acid dimethyl ester, Z
  • cis-2-methyl-2-butenedioicacid,dimethylester
  • cis-2-methyl-but-2-enoicaciddimethylester
  • Dimethyl (2Z)-2-methyl-2-butenedioate
  • Dimethyl methyl maleate
  • dimethylmethylmaleate
  • Maleic acid, methyl-, dimethyl ester
  • Methylmaleic acid, dimethyl ester
  • methylmaleicacid,dimethylester
  • DIMETHYL CITRACONATE
  • CITRACONIC ACID DIMETHYL ESTER
  • 2-Butenedioic acid, 2-methyl-, dimethyl ester, (2Z)-
  • (Z)-2-Methyl-2-butenedioic acid dimethyl ester
  • Dimethyl cis-1-propene-1,2-dicarboxylate
  • C05126
  • Citraconate de dimethyle
  • Dimethyl Citraconate &gt
  • Dimethyl Citraconate@1000 μg/mL in Ethanol
  • 2-Butenedioic acid, 2-methyl-, 1,4-dimethyl ester, (2Z)-
  • dimethyl 2-methylmaleate
  • (2Z)-Dimethyl 2-methylmaleate
  • 617-54-9　CITRACONIC ACID DIMETHYL ESTER
  • (Z)-Citraconic acid-dimethyl ester
  • 617-54-9
  • C7H10O4C7H10O4