ChemicalBook > CAS DataBase List > (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
Reaction- Product Name
- (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- CAS No.
- 380230-02-4
- Chemical Name
- (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
- Synonyms
- 3,4-a']dinapht...;(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;]dinaphthalen-4-yl)bis(1-phenylethyl)amine;1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR);(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;(S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo
- CBNumber
- CB5190531
- Molecular Formula
- C36H30NO2P
- Formula Weight
- 539.6
- MOL File
- 380230-02-4.mol
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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Property
- Melting point:
- 88-89 °C
- alpha
- +13.1° (c 1.01, CHCl3)
- Boiling point:
- 710.7±63.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- Powder
- pka
- -0.57±0.20(Predicted)
- color
- off-white
- Sensitive
- moisture sensitive
- InChIKey
- LKZPDRCMCSBQFN-UIOOFZCWSA-N
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Safety
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36/37/39
- WGK Germany
- 3
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 665290
- Product name
- (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
- Purity
- 97%
- Packaging
- 100mg
- Price
- $84.3
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 665290
- Product name
- (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
- Purity
- 97%
- Packaging
- 2g
- Price
- $636
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1521
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
- Packaging
- 100mg
- Price
- $94
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-1521
- Product name
- (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
- Packaging
- 500mg
- Price
- $367
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 665290
- Product name
- (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
- Purity
- 97%
- Packaging
- 500mg
- Price
- $240.6
- Updated
- 2024/03/01
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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Chemical Properties,Usage,Production
Reaction
- A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
- Iridium-catalyzed regioselective and enantioselective allylation of enamines.
- Iridium-catalyzed asymmetric allylation of KSAc.
Uses
The product may be used as a ligand in:
- Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
- Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
- Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Preparation Products And Raw materials
Raw materials
Preparation Products
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380230-02-4, (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)Related Search:
(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
(R)-MONOPHOS
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)