ChemicalBook > CAS DataBase List > (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

Reaction

Product Name: (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
CAS No.: 380230-02-4
Chemical Name: (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
Synonyms: 3,4-a']dinapht...;(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;]dinaphthalen-4-yl)bis(1-phenylethyl)amine;1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR);(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;(S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a’3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,95%
CBNumber: CB5190531
Molecular Formula: C36H30NO2P
Formula Weight: 539.6
MOL File: 380230-02-4.mol

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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Property

Melting point:: 88-89 °C
alpha: +13.1° (c 1.01, CHCl3)
Boiling point:: 710.7±63.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: -0.57±0.20(Predicted)
form: Powder
color: off-white
Sensitive: moisture sensitive
InChIKey: LKZPDRCMCSBQFN-UIOOFZCWSA-N
SMILES: O1C2=CC=C3C(=C2C2=C4C(C=CC=C4)=CC=C2OP1N([C@H](C1=CC=CC=C1)C)[C@H](C1=CC=CC=C1)C)C=CC=C3

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Safety

Risk Statements: 36/37/38
Safety Statements: 26-36/37/39
WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 665290
Product name: (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity: 97%
Packaging: 100mg
Price: $60.83
Updated: 2025/07/31

Sigma-Aldrich

Product number: 665290
Product name: (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity: 97%
Packaging: 2g
Price: $1640
Updated: 2025/07/31

Strem Chemicals

Product number: 15-1521
Product name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
Packaging: 100mg
Price: $94
Updated: 2024/03/01

Strem Chemicals

Product number: 15-1521
Product name: (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
Packaging: 500mg
Price: $367
Updated: 2024/03/01

Sigma-Aldrich

Product number: 665290
Product name: (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity: 97%
Packaging: 500mg
Price: $413
Updated: 2025/07/31

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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Chemical Properties,Usage,Production

Reaction

A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
Iridium-catalyzed regioselective and enantioselective allylation of enamines.
Iridium-catalyzed asymmetric allylation of KSAc.

Uses

The product may be used as a ligand in:

Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Suppliers

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380230-02-4, (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)Related Search:

(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE

(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1S)-1-PHENYLETHYL]AMINE

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%

S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95%

3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%

3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine

(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE

3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95%

N,N-Bis((S)-1-phenylethyl)dinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

N,N-Bis[(1S)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)aMine 97%

3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,95%

(S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo

]dinaphthalen-4-yl)bis(1-phenylethyl)amine

]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D

1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1S)-1-phenylethyl]-

3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,97%

3,4-a']dinapht...

3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.

N,N-Bis[(1S)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%

3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct

(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine

(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a′]dinaphthalen-4-yl)bis(1-phenylethyl)amine, CAS 380230-02-4

380230-02-4

C36H30NO2P

Privileged Ligands

DSM MonoPhos Phosphoramidites

Asymmetric Synthesis

Chiral Catalysts, Ligands, and Reagents

Chiral Phosphine

CPN