Reaction
ChemicalBook > CAS DataBase List > (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

Reaction
Product Name
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
CAS No.
380230-02-4
Chemical Name
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
Synonyms
3,4-a']dinapht...;(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;]dinaphthalen-4-yl)bis(1-phenylethyl)amine;1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR);(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;(S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo
CBNumber
CB5190531
Molecular Formula
C36H30NO2P
Formula Weight
539.6
MOL File
380230-02-4.mol
More
Less

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Property

Melting point:
88-89 °C
alpha 
+13.1° (c 1.01, CHCl3)
Boiling point:
710.7±63.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
pka
-0.57±0.20(Predicted)
color 
off-white
Sensitive 
moisture sensitive
InChIKey
LKZPDRCMCSBQFN-UIOOFZCWSA-N
More
Less

Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
More
Less

Hazard and Precautionary Statements (GHS)

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
665290
Product name
(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity
97%
Packaging
100mg
Price
$84.3
Updated
2024/03/01
Sigma-Aldrich
Product number
665290
Product name
(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity
97%
Packaging
2g
Price
$636
Updated
2024/03/01
Strem Chemicals
Product number
15-1521
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
Packaging
100mg
Price
$94
Updated
2024/03/01
Strem Chemicals
Product number
15-1521
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
Packaging
500mg
Price
$367
Updated
2024/03/01
Sigma-Aldrich
Product number
665290
Product name
(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity
97%
Packaging
500mg
Price
$240.6
Updated
2024/03/01
More
Less

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Chemical Properties,Usage,Production

Reaction

  1. A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
  2. Iridium-catalyzed regioselective and enantioselective allylation of enamines.
  3. Iridium-catalyzed asymmetric allylation of KSAc. 

Uses

The product may be used as a ligand in:

  • Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
  • Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
  • Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Suppliers

China 43 Germany 1 Switzerland 1 Ukraine 1 United Kingdom 1 United States 9 Global 56
LaaJoo
Tel
021-60702684 18516024827
Email
huang.jiayi@sinocompound.com
Country
China
ProdList
2603
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
96815
Advantage
76
Energy Chemical
Tel
021-021-58432009 400-005-6266
Fax
021-58436166
Email
sales8178@energy-chemical.com
Country
China
ProdList
44689
Advantage
61
China DongFan Chemical Co.,LTD
Tel
86-0571-85151182
Fax
86-0571-85151182
Country
China
ProdList
5691
Advantage
66
Nanjin Cynthia chemicals Technology Co.,Ltd
Tel
0550-5618439 15951861180
Fax
0550-5610690
Email
cynthiachem@163.com
Country
China
ProdList
335
Advantage
62
Tianjin Derchemist Science & Technology Co., Ltd.
Tel
22-58627059 13920586291
Fax
022-58620305
Email
zdcomcon@126.com
Country
China
ProdList
3461
Advantage
50
Shanghai Jian Chao Chemical Technology Co., Ltd.
Tel
18017383231 18017383231
Fax
qq：2817624287
Email
lyh_antaeus@163.com
Country
China
ProdList
9347
Advantage
55
Shanghai Incat Chemtech Co.,Ltd.
Tel
021-57603038 13601791340
Fax
021-57603057
Email
307593986@qq.com
Country
China
ProdList
475
Advantage
58
Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Chengdu HuaXia Chemical Reagent Co. Ltd
Tel
400-1166-196 13458535857
Fax
QQ：800101999
Email
cdhxsj@163.com
Country
China
ProdList
13350
Advantage
58
Sigma-Aldrich
Tel
021-61415566 800-8193336
Email
orderCN@merckgroup.com
Country
China
ProdList
51456
Advantage
80
Shanghai Chiral bio-compound co., Ltd.
Tel
021-5068 3667/17749785980/1029026415; 17749785980
Fax
021-50683667
Email
1029026415@qq.com
Country
China
ProdList
3013
Advantage
58
ATK CHEMICAL COMPANY LIMITED
Tel
021-51619050 13301662590
Fax
+86-21-51619052
Email
mandy@atkchemical.com
Country
China
ProdList
8025
Advantage
55
Shanghai SuperLan Chemcial Technique Centre
Tel
021-2022843681 15618226720
Fax
+86-21-51601218
Email
lucy@atkchemical.com
Country
China
ProdList
9204
Advantage
58
Amadis Chemical Company Limited
Tel
571-89925085
Fax
0086-571-89925065
Email
sales@amadischem.com
Country
China
ProdList
131957
Advantage
58
Shandong Ono Chemical Co., Ltd.
Tel
0539-6362799 20）
Fax
0539-6362799（To 20）
Country
China
ProdList
10007
Advantage
58
Aikon International Limited
Tel
025-66113011 18112977050
Fax
02557626880
Email
sales01@aikonchem.com
Country
China
ProdList
16027
Advantage
58
3A Chemicals
Tel
400-668-9898
Fax
010-51582189
Email
service@3achem.com
Country
China
ProdList
20557
Advantage
58
Shanghai Anyinuo Biomedical Technology Co., Ltd.
Tel
021-34625901
Email
420970979@qq.com
Country
China
ProdList
5877
Advantage
58
Shenzhen Polymeri Biochemical Technology Co., Ltd.
Tel
+86-400-002-6226 +86-13028896684;
Email
sales@rrkchem.com
Country
China
ProdList
57412
Advantage
58
Hefei TNJ Chemical Industry Co.,Ltd.
Tel
+86-0551-65418684 +8618949823763
Fax
0086-551-65418684
Email
sales@tnjchem.com
Country
China
ProdList
25356
Advantage
58
Dayang Chem (Hangzhou) Co.,Ltd.
Tel
571-88938639 +8617705817739
Fax
+86-571-88938652，+86-571- 88492614
Email
info@dycnchem.com
Country
China
ProdList
52849
Advantage
58
Henan Weituxi Chemical Technology Co., Ltd.
Tel
0371-63284658 18135795563
Fax
QQ:2885349392
Email
2885349392@qq.com
Country
China
ProdList
10057
Advantage
58
Henan Huawen Chemical Co., Ltd
Tel
0370-0370-2059268 17550075363
Fax
QQ:2712427897
Email
1124977392@qq.com
Country
China
ProdList
2283
Advantage
58
Shanghai Kaiwei Chemical Technology Co., Ltd.
Tel
021-58461859 15821823057
Email
service@aiviche.com
Country
China
ProdList
49312
Advantage
58
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.
Tel
021-51816796-820 13611835272
Fax
021-5161 3951
Email
sales2@sunwaypharm.com
Country
China
ProdList
44458
Advantage
58
Beijing Jin Ming Biotechnology Co., Ltd.
Tel
010-60605840 15801484223;
Email
psaitong@jm-bio.com
Country
China
ProdList
29774
Advantage
58
Shanghai Haohong Pharmaceutical Co., Ltd.
Tel
400-8210725 4008210725
Email
malulu@leyan.com
Country
China
ProdList
40037
Advantage
58
Bide Pharmatech Ltd.
Tel
400-1647117 13681763483
Email
product02@bidepharm.com
Country
China
ProdList
62163
Advantage
58
Bide Pharmatech Ltd.
Tel
400-6005915
Email
sales@picasso-e.com
Country
China
ProdList
39653
Advantage
58
Jiaxing Zhejia Biotechnology Co., LTD
Tel
0573-85609002
Email
zhejia01@163.com
Country
China
ProdList
8870
Advantage
58
Shanghai Maclean Biochemical Technology Co., LTD
Tel
021-50706066 15221275939
Email
shenlinxing@macklin.cn
Country
China
ProdList
29794
Advantage
58
Shanghai Yingxin laboratory equipment Co., Ltd
Tel
021-021-59178156 15300768757
Email
359382369@qq.com
Country
China
ProdList
10674
Advantage
58
Yantai Sheng Kai Lun Biological Products Co. , Ltd.
Tel
3119594100
Email
mark@sklnchem.cn
Country
China
ProdList
14477
Advantage
58
Beijing Solarbio Science & Tecnology Co., Ltd.
Tel
010-50973130 17801761073
Email
Gsiyu@solarbio.com
Country
China
ProdList
50464
Advantage
58
https://hanhongsci.com/
Tel
021-54306202 18917919676
Email
info@hanhongsci.com
Country
China
ProdList
29977
Advantage
58
Henan Fangding Technology Co., LTD
Tel
15670369782
Email
15670369782@163.com
Country
China
ProdList
10051
Advantage
58
Shandong Binchen Chemical Co.，Ltd
Tel
18351216136 18338758121;18351216281
Email
3846935277@qq.com
Country
China
ProdList
926
Advantage
58
Shaoxin Catsyn Co., Ltd.
Tel
+undefined-0575-82040869 +86-0575-82040869;
Email
sales@catsyn.com
Country
China
ProdList
6114
Advantage
58
GIHI CHEMICALS CO.,LIMITED
Tel
+8618058761490
Email
info@gihichemicals.com
Country
China
ProdList
49979
Advantage
58
PT CHEM GROUP LIMITED
Tel
Email
peter68@ptchemgroup.com
Country
China
ProdList
35425
Advantage
58
Shanghai Hao Zhun Biological Technology Co., Ltd.
Tel
--
Fax
--
Email
info@zzsrm.com
Country
CHINA
ProdList
6650
Advantage
58
Shanghai Sujia Biomedical Technology Co., Ltd.
Tel
--
Fax
--
Email
lilan505@126.com
Country
CHINA
ProdList
260
Advantage
58

380230-02-4, (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)Related Search:

(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

  • (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE
  • (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1S)-1-PHENYLETHYL]AMINE
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
  • (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
  • S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95%
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine
  • (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95%
  • N,N-Bis((S)-1-phenylethyl)dinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • N,N-Bis[(1S)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)aMine 97%
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,95%
  • (S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo
  • ]dinaphthalen-4-yl)bis(1-phenylethyl)amine
  • ]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D
  • 1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1S)-1-phenylethyl]-
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,97%
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
  • 3,4-a']dinapht...
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.
  • N,N-Bis[(1S)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
  • 380230-02-4
  • C36H30NO2P
  • Privileged Ligands
  • DSM MonoPhos Phosphoramidites
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Chiral Phosphine
  • CPN