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ChemicalBook > CAS DataBase List > (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

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Product Name
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
CAS No.
380230-02-4
Chemical Name
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
Synonyms
3,4-a']dinapht...;(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;]dinaphthalen-4-yl)bis(1-phenylethyl)amine;1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR);(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;(S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo
CBNumber
CB5190531
Molecular Formula
C36H30NO2P
Formula Weight
539.6
MOL File
380230-02-4.mol
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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Property

Melting point:
88-89 °C
alpha 
+13.1° (c 1.01, CHCl3)
Boiling point:
710.7±63.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
Powder
pka
-0.57±0.20(Predicted)
color 
off-white
Sensitive 
moisture sensitive
InChIKey
LKZPDRCMCSBQFN-UIOOFZCWSA-N
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Safety

Risk Statements 
36/37/38
Safety Statements 
26-36/37/39
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
665290
Product name
(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity
97%
Packaging
100mg
Price
$84.3
Updated
2024/03/01
Sigma-Aldrich
Product number
665290
Product name
(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity
97%
Packaging
2g
Price
$636
Updated
2024/03/01
Strem Chemicals
Product number
15-1521
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
Packaging
100mg
Price
$94
Updated
2024/03/01
Strem Chemicals
Product number
15-1521
Product name
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
Packaging
500mg
Price
$367
Updated
2024/03/01
Sigma-Aldrich
Product number
665290
Product name
(S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine
Purity
97%
Packaging
500mg
Price
$240.6
Updated
2024/03/01
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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Chemical Properties,Usage,Production

Reaction

  1. A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
  2. Iridium-catalyzed regioselective and enantioselective allylation of enamines.
  3. Iridium-catalyzed asymmetric allylation of KSAc. 

Uses

The product may be used as a ligand in:

  • Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
  • Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
  • Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Preparation Products And Raw materials

Raw materials

Preparation Products

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(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Suppliers

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380230-02-4, (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)Related Search:

(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ (+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

  • (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE
  • (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1S)-1-PHENYLETHYL]AMINE
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
  • (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
  • S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95%
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95%
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine
  • (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95%
  • N,N-Bis((S)-1-phenylethyl)dinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • N,N-Bis[(1S)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)aMine 97%
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,95%
  • (S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo
  • ]dinaphthalen-4-yl)bis(1-phenylethyl)amine
  • ]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D
  • 1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1S)-1-phenylethyl]-
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,97%
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D
  • (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
  • 3,4-a']dinapht...
  • 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.
  • N,N-Bis[(1S)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • 380230-02-4
  • C36H30NO2P
  • Privileged Ligands
  • DSM MonoPhos Phosphoramidites
  • Asymmetric Synthesis
  • Chiral Catalysts, Ligands, and Reagents
  • Chiral Phosphine
  • CPN