N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][

Reaction

Product Name: N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
CAS No.: 376355-58-7
Chemical Name: N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
Synonyms: N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][;Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine;N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-;N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%;BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite
CBNumber: CB4497141
Molecular Formula: C28H26NO2P
Formula Weight: 439.49
MOL File: 376355-58-7.mol

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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Property

Melting point:: 99-102 °C
Boiling point:: 578.4±53.0 °C(Predicted)
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
pka: -0.31±0.20(Predicted)
form: Powder
color: white
optical activity: [α]/D -250±10°, c = 1 in toluene
Sensitive: moisture sensitive

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 07033
Product name: N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
Purity: ≥99.0%
Packaging: 100MG
Price: $94.3
Updated: 2022/05/15

Strem Chemicals

Product number: 15-0519
Product name: N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
Packaging: 100mg
Price: $117
Updated: 2024/03/01

Strem Chemicals

Product number: 15-0519
Product name: N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
Packaging: 500mg
Price: $470
Updated: 2024/03/01

American Custom Chemicals Corporation

Product number: CCH0004775
Product name: N,N-BIS-((S)-1-PHENYLETHYL)DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN-6-AMINE
Purity: 95.00%
Packaging: 100MG
Price: $730.68
Updated: 2021/12/16

American Custom Chemicals Corporation

Product number: CCH0004775
Product name: N,N-BIS-((S)-1-PHENYLETHYL)DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN-6-AMINE
Purity: 95.00%
Packaging: 1G
Price: $1379.7
Updated: 2021/12/16

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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Chemical Properties,Usage,Production

Reaction

Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic substituted allylic halides to form branched chiral products from diverse Grignard reagents.
Ligand for the copper catalyzed, highly enantioselective conjugate addition of diethylzinc to eneones and nitro olefins.
Ligand for the nickel catalyzed, highly enantioselective hydrovinylation of alkenes.
Ligand for the rhodium catalyzed, highly enantioselective hydroformylation of vinylarenes.
Ligand for gold catalyzed asymmetric Intramolecular hydroamination of allenes

Uses

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:

In the iridium catalyzed allylic arylation.
To prepare a copper complex (Cu₂X₂L₃), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt₂.

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Preparation Products And Raw materials

Raw materials

Preparation Products

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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Suppliers

China 29 Switzerland 1 United States 3 Global 33

J & K SCIENTIFIC LTD.

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Sigma-Aldrich

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Amadis Chemical Company Limited

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LaaJoo

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376355-58-7, N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][Related Search:

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][

BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite

N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine

N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine

1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite

Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite

Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%

376355-58-7

phosphine-amine ligand

Chiral Phosphine

CPN