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ChemicalBook > CAS DataBase List > N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][

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Product Name
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
CAS No.
376355-58-7
Chemical Name
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
Synonyms
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][;Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine;N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-;N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%;BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite
CBNumber
CB4497141
Molecular Formula
C28H26NO2P
Formula Weight
439.49
MOL File
376355-58-7.mol
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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Property

Melting point:
99-102 °C
Boiling point:
578.4±53.0 °C(Predicted)
storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
pka
-0.31±0.20(Predicted)
form 
Powder
color 
white
optical activity
[α]/D -250±10°, c = 1 in toluene
Sensitive 
moisture sensitive
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Safety

WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
07033
Product name
N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
Purity
≥99.0%
Packaging
100MG
Price
$94.3
Updated
2022/05/15
Strem Chemicals
Product number
15-0519
Product name
N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
Packaging
100mg
Price
$117
Updated
2024/03/01
Strem Chemicals
Product number
15-0519
Product name
N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
Packaging
500mg
Price
$470
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CCH0004775
Product name
N,N-BIS-((S)-1-PHENYLETHYL)DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN-6-AMINE
Purity
95.00%
Packaging
100MG
Price
$730.68
Updated
2021/12/16
American Custom Chemicals Corporation
Product number
CCH0004775
Product name
N,N-BIS-((S)-1-PHENYLETHYL)DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN-6-AMINE
Purity
95.00%
Packaging
1G
Price
$1379.7
Updated
2021/12/16
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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Chemical Properties,Usage,Production

Reaction

  1. Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic substituted allylic halides to form branched chiral products from diverse Grignard reagents.
  2. Ligand for the copper catalyzed, highly enantioselective conjugate addition of diethylzinc to eneones and nitro olefins.
  3. Ligand for the nickel catalyzed, highly enantioselective hydrovinylation of alkenes.
  4. Ligand for the rhodium catalyzed, highly enantioselective hydroformylation of vinylarenes.
  5. Ligand for gold catalyzed asymmetric Intramolecular hydroamination of allenes

Uses

N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:

  • In the iridium catalyzed allylic arylation.
  • To prepare a copper complex (Cu2X2L3), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt2.

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Preparation Products And Raw materials

Raw materials

Preparation Products

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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Suppliers

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376355-58-7, N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][Related Search:

N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

  • N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine
  • N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
  • BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite
  • N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
  • N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
  • 1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite
  • Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite
  • Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-
  • N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%
  • 376355-58-7
  • phosphine-amine ligand
  • Chiral Phosphine
  • CPN