ChemicalBook > CAS DataBase List > N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
Reaction- Product Name
- N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
- CAS No.
- 376355-58-7
- Chemical Name
- N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
- Synonyms
- N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][;Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;1,1'-Biphenyl-2,2'-diyl bis((1S)-1-phenylethyl)phosphoramidite;N,N-bis[(1R)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine;N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine;Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1S)-1-phenylethyl]-;N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%;BIPOL-A1(S), (S,S)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(S)-1-phenylethyl]phosphoramidite
- CBNumber
- CB4497141
- Molecular Formula
- C28H26NO2P
- Formula Weight
- 439.49
- MOL File
- 376355-58-7.mol
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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Property
- Melting point:
- 99-102 °C
- Boiling point:
- 578.4±53.0 °C(Predicted)
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- pka
- -0.31±0.20(Predicted)
- form
- Powder
- color
- white
- optical activity
- [α]/D -250±10°, c = 1 in toluene
- Sensitive
- moisture sensitive
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Safety
- WGK Germany
- 3
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 07033
- Product name
- N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
- Purity
- ≥99.0%
- Packaging
- 100MG
- Price
- $94.3
- Updated
- 2022/05/15
Strem Chemicals
- Product number
- 15-0519
- Product name
- N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
- Packaging
- 100mg
- Price
- $117
- Updated
- 2024/03/01
Strem Chemicals
- Product number
- 15-0519
- Product name
- N,N-Bis[(1S)-(-)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine
- Packaging
- 500mg
- Price
- $470
- Updated
- 2024/03/01
American Custom Chemicals Corporation
- Product number
- CCH0004775
- Product name
- N,N-BIS-((S)-1-PHENYLETHYL)DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN-6-AMINE
- Purity
- 95.00%
- Packaging
- 100MG
- Price
- $730.68
- Updated
- 2021/12/16
American Custom Chemicals Corporation
- Product number
- CCH0004775
- Product name
- N,N-BIS-((S)-1-PHENYLETHYL)DIBENZO[D,F][1,3,2]DIOXAPHOSPHEPIN-6-AMINE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $1379.7
- Updated
- 2021/12/16
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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Chemical Properties,Usage,Production
Reaction
- Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic substituted allylic halides to form branched chiral products from diverse Grignard reagents.
- Ligand for the copper catalyzed, highly enantioselective conjugate addition of diethylzinc to eneones and nitro olefins.
- Ligand for the nickel catalyzed, highly enantioselective hydrovinylation of alkenes.
- Ligand for the rhodium catalyzed, highly enantioselective hydroformylation of vinylarenes.
- Ligand for gold catalyzed asymmetric Intramolecular hydroamination of allenes
Uses
N,N-Bis-((S)-1-phenylethyl)dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
- In the iridium catalyzed allylic arylation.
- To prepare a copper complex (Cu2X2L3), which is used to detect the transmetalation intermediates in asymmetric addition reactions using ZnEt2.
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Preparation Products And Raw materials
Raw materials
Preparation Products
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N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][ Suppliers
376355-58-7, N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][Related Search:
N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
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